Next Article in Journal
A Secure Image Encryption Scheme Based on a New Hyperchaotic System and 2D Compressed Sensing
Previous Article in Journal
Enhanced Coexistence of Quantum Key Distribution and Classical Communication over Hollow-Core and Multi-Core Fibers
 
 
Font Type:
Arial Georgia Verdana
Font Size:
Aa Aa Aa
Line Spacing:
Column Width:
Background:
Article

Impact of Quantum Non-Locality and Electronic Non-Ideality on the Shannon Entropy for Atomic States in Dense Plasma

by
Askhat T. Nuraly
1,
Madina M. Seisembayeva
1,2,3,
Karlygash N. Dzhumagulova
1,2,3,* and
Erik O. Shalenov
1,*
1
Department of General Physics, Satbayev University, Almaty 050013, Kazakhstan
2
Institute of Experimental and Theoretical Physics, Al-Farabi Kazakh National University, Almaty 050040, Kazakhstan
3
Department of Plasma Physics, Nanotechnology and Computer Physics, Al-Farabi Kazakh National University, Almaty 050040, Kazakhstan
*
Authors to whom correspondence should be addressed.
Entropy 2024, 26(7), 602; https://doi.org/10.3390/e26070602
Submission received: 4 June 2024 / Revised: 26 June 2024 / Accepted: 8 July 2024 / Published: 16 July 2024
(This article belongs to the Section Statistical Physics)

Abstract

:
The influence of the collective and quantum effects on the Shannon information entropy for atomic states in dense nonideal plasma was investigated. The interaction potential, which takes into account the effect of quantum non-locality as well as electronic correlations, was used to solve the Schrödinger equation for the hydrogen atom. It is shown that taking into account ionic screening leads to an increase in entropy, while taking into account only electronic screening does not lead to significant changes.

1. Introduction

Dense non-ideal plasma appears in various astrophysical objects, such as the interiors of giant planets and White Dwarfs, as well as in laboratory conditions. High-energy-density studies have now received significant development due to the emergence of new high-tech and expensive devices, such as relativistic ion synchrotron accelerators, high-power lasers, intense charged particle beams, high-current Z-pinches, explosive and electroexplosive generators of powerful shock waves, and others. Temperature and density of dense non-ideal plasma are considered in the ranges 1 0 4 1 0 6   K and 1 0 21 1 0 25   c m 3 , respectively.
At present, in the physics of dense non-ideal plasmas, the study of the influence of collective and quantum effects, such as screening, degeneracy, quantum non-locality, etc., on the properties of plasma is becoming increasingly relevant [1,2,3,4,5,6,7,8,9,10,11,12,13,14,15,16,17,18,19,20,21,22,23,24,25,26]. The results obtained in these studies are of crucial importance for expanding our knowledge of the physical processes in plasmas under extreme conditions, such as in the cores of stars, in experiments with laser plasmas, and in inertial thermonuclear fusion facilities [27].
In this paper, we investigate the influence of collective and quantum effects on the Shannon entropy of atomic states in quantum hydrogen plasma. Hydrogen plasma is one of the simplest and at the same time most important models for studying plasma systems. This is due to its wide applicability, ranging from astrophysical objects such as stars to laboratory setups used to study controlled thermonuclear fusion. Shannon entropy is a fundamental concept of information theory, introduced by Claude Shannon in 1948 to quantitatively describe the uncertainty in data transmission systems. The concept of Shannon entropy provides a unique tool for analyzing the complexity and orderliness of plasma states. In particular, visualizing entropy in spatial form allows one to clearly represent and quantify the degree of uncertainty and information content in the dynamics of plasma systems.
The work [28] considered the application of information entropy to the analysis of instabilities and turbulence in plasma. The study proposed methods for the quantitative assessment of chaos and order in plasma systems. L.C. Souza et al. [29] used Shannon entropy to study anomalous transport and chaotic processes in plasma. J.A. Krommes [30] applied the concept of information entropy to the modeling and analysis of structural changes in plasma, focusing on transitions between different regimes of the plasma state. G. Livadiotis [31] considered the use of Shannon entropy to analyze time series and spatial data obtained in plasma experiments, which revealed patterns and predicted the behavior of plasma structures. D. Rastovic [32] investigated the application of entropy in the context of thermonuclear fusion, proposing methods for improving the diagnostics and control of plasma in tokamak- and stellarator-type devices. These studies show that Shannon entropy is a powerful tool for analyzing and understanding complex processes in plasma.
Y.-D. Jung and M.-J. Lee [33,34,35] extensively studied Shannon entropy in the context of astrophysical plasma. In refs. [33,34], the effect of screening on the entropy of information states of atoms in strongly coupled plasma was analyzed. The studies showed that the change in the entropy of atomic states is more significant for excited states compared to the ground state and that the localization of screening has a greater effect on atoms with a higher charge number. In ref. [35], the influence of nonequilibrium effects on the Shannon entropy of atomic states in astrophysical Lorentz plasma was investigated. The study covered the calculation of the Shannon entropy for the ground and excited states of a hydrogen atom under astrophysical plasma conditions, taking into account the parameters of the spectral index, effective screening lengths, and plasma parameters, including radial and angular components. As a result of the study, it was found that the nonequilibrium nature of the Lorentz plasma suppresses the entropy changes in both the ground state and the excited states. It was also found that changes in entropy in excited states are more significant compared to the ground state. The effect of the magnetic quantum number on changes in entropy turned out to be insignificant, which is explained by the invariance of the angular parts of the Shannon entropy under the influence of the nonequilibrium nature and screening of the plasma.
The structure of the presented work is as follows: Section 2 describes the electron–ion interaction model for the calculation of the Schrödinger equation. The methodology of the calculation of the Shannon entropy is presented in Section 3. The fourth section presents the results obtained. Conclusions are given in Section 5.

2. Effective Potential of Electron–Ion Interaction

One of the main points in the study of phenomena in quantum plasma is the choice of an adequate model of particle interaction, taking into account various effects and features in this system. In ref. [26], the effective potential, which takes into account the effects of the quantum non-locality and electronic non-ideality, was presented. In this work, we use this electron–ion interaction potential (see Equation (6) from ref. [26]):
Φ e i ( r ) = Z e 2 r ( 1 + k i 2 λ e e 2 ) 2 4 k D 2 λ e e 2 1 λ e e 2 B 2 exp ( B r ) 1 λ e e 2 A 2 exp ( A r )
Here, A 2 = 1 + k i 2 λ e e 2 + ( 1 + k i 2 λ e e 2 ) 2 4 k D 2 λ e e 2 2 λ e e 2 , B 2 = 1 + k i 2 λ e e 2 ( 1 + k i 2 λ e e 2 ) 2 4 k D 2 λ e e 2 2 λ e e 2 , λ e e 2 = a ~ 2 / a ~ 0 1 k Y 2 γ ,   a ~ 0 = 2 π e 2 k Y 2 , a ~ 2 = 2 I 3 / 2 ( η ) 36 m e n θ 3 2 I 1 / 2 2 ( η ) , k D 2 = k s 2 + k i 2 = r D 2 ,   k s 2 = k Y 2 1 k Y 2 γ ,   k i 2 = 4 π n i Z i 2 e 2 k B T i is the inverse ionic Debye length, Z i is the charge number of ions, parameter γ = 1 4 π e 2 2 n e f X C n e , T e n e 2 takes into account the impact of electronic exchange correlations, f X C n e , T e describes the exchange correlation part of the electronic free energy density from the quantum Monte Carlo simulations [26,36], k Y 2 = 1 2 k T F 2 θ 1 / 2 I 1 / 2 ( η ) is the inverse electron screening length that interpolates between Debye and Thomas–Fermi expansions [26], k T F = 3 ω p v F = 4 k F π a B , ω p = 4 π n e e 2 m e is the plasma electronic frequency, and v F = k F m e is the Fermi speed. Parameter θ = k B T e E F characterizes the electron degeneracy; here, T e is the electron temperature, E F = 2 k F 2 2 m e is the Fermi energy, k F = 3 π 2 n e 1 / 3 is the Fermi wave vector, is the reduced Planck constant, and n e and m e are the electron density and mass, respectively. In the work [26], the Schrödinger equation was solved on the basis of this model. As a result, wave functions and values of energy levels were obtained. In ref. [26], it was shown that if one takes k i = 0 in Equation (1), then the results of calculations of the energies of the ground and first excited levels of the hydrogen atom in plasma practically coincide with the data obtained by Z.-B. Chen et al. [37] based on the potential of Stanton and Murillo [38]. The potential of Stanton and Murillo takes into account only electron screening. A detailed description of the potential (1) with k i 0 is given in ref. [26].
The radial Schrödinger equation for a hydrogen atom in dense plasma would be given by
2 m e d 2 d r 2 l ( l + 1 ) r 2 + Φ e i ( r ) P n l ( r ) = E n l P n l ( r ) ,
where P n l ( r ) is the radial wave function for the nlth shell, E n l is the energy level, Φ e i ( r ) is the corresponding electron–ion interaction potential, and r is the radius of the electron orbit. We used potential (1) as the interaction potential. Solving the Schrödinger equation based on interaction potentials in dense plasma is very difficult. Therefore, we used the variational method to calculate the bound states and wave functions of the hydrogen atom.
Using the variational method, we selected the trial wave functions as follows:
P n l ( r ) = r R n l ( r ) = 2 Z n α 3 n l 1 ! 2 n ( n + l ) ! 3 e ρ 2 ρ l L n + l 2 l + 1 ( ρ ) ,
where ρ = 2 Z n α r , α is the variational parameter, α a z for k D 0 & λ e e 0 , a z = a 0 / Z , a 0 is the Bohr radius, and k D 0 & λ e e 0 indicates a plasma-free situation. L n + l 2 l + 1 ( ρ ) is the generalized Laguerre polynomials. The formula for the Laguerre polynomials was as follows:
L n + l 2 l + 1 ( ρ ) = i = 0 n l 1 1 i + 1 n + l ! 2 ( n l i 1 ) ( 2 l + i + 1 ) ! i ! ρ i .
The trial functions for the ground state 1s and the excited states 2s, 2p of the hydrogen atom were as follows:
P 1 s ( r ) = 2 α 3 / 2 r e r / α , P 2 s ( r ) = 1 2 α 3 / 2 r 1 r 2 α e r / 2 α , P 3 s ( r ) = 2 3 3 α 3 / 2 r 1 2 r 3 α + 2 r 2 27 α 2 e r / 3 α , P 2 p ( r ) = 1 2 6 α 5 r 2 e r / 2 α , P 3 p ( r ) = 4 2 9 3 α 5 r 2 1 r 6 α e r / 3 α .
The dependence of E n l ( α ) was found through the trial functions:
E n l ( α ) = 2 2 m 0 d P n l ( r ) d r 2 + l ( l + 1 ) r 2 + 2 m 2 Φ e i ( r ) P n l 2 ( r ) d r .
The minima of this function gave the energy levels, and by substituting the values of α m i n into the trial functions, the radial wave functions were determined.
In present work, we recalculated the Schrödinger equation on the basis of the Shalenov–Nuraly–Dzhumagulova potential (1) at k i       0 (the SNDP-A case) and potential Shalenov–Nuraly–Dzhumagulova (1) at k i       0 (SNDP-B case) in order to investigate the Shannon entropy of the system under study.

3. Methodology

It was shown that the Shannon entropy associated with the atomic density distribution ρ ( r ) = | ψ ( r ) | 2 in the position space is defined as
S ρ = ρ ( r ) ln ρ ( r ) d r 3 = | ψ ( r ) | 2 ln | ψ ( r ) | 2 d r 3 ,
where ψ ( r ) is the atomic wave function in the position space r . In one-electron systems with the wave function
ψ ( r ) = R n l ( r ) Y l m ( Ω ) , the Shannon entropy S ρ would be decomposed into the radial and angular parts [39]:
S ρ = S ( R n l ) + S ( Y l m ) ,
where S ( R n l ) is the radial part of the Shannon entropy with the radial wave function R n l :
S ( R n l ) = | R n l | 2 ln | R n l | 2 r 2 d r ,
S ( Y l m ) is the angular part of the Shannon entropy with the spherical harmonics Y l m ( Ω ) :
S ( Y l m ) = | Y l m ( Ω ) | 2 ln | Y l m ( Ω ) | 2 d Ω ,
and d Ω = ( s i n θ d θ d φ ) is the differential solid angle in spherical coordinates.

4. Results and Discussions

The results calculated from the atomic density distribution of the hydrogen atom in the ground state (1s) in Figure 1a and Figure 2a and the excited state (2p) in Figure 1b and Figure 2b are given. The atomic density distributions were determined for different temperatures at a fixed plasma concentration in Figure 1 and different concentrations at a fixed plasma temperature in Figure 2. What can be observed from these figures is that as the temperature decreased and the concentration increased, the atomic density distribution decreased and spread out in space owing to less nuclear attraction felt due to screening by free electrons and quantum nonlocality. Conversely, as the temperature increased and the concentration decreased, the results approached the values of the atomic density distribution determined based on the Coulomb potential.
The results of calculations of the Shannon information entropy (7) are presented in this section. Figure 3, Figure 4, Figure 5 and Figure 6 show the changes in the Shannon information entropy ( Δ S = S ρ p l a s m a S ρ f r e e ). S ρ p l a s m a corresponds to the calculations of the Shannon information entropy (7) using potential (1) (the SNDP-B case). S ρ f r e e presents data obtained on the basis of the Coulomb potential for the isolated atom. One can see from Figure 3, Figure 4, Figure 5 and Figure 6 that the entropy changes fell with an increase in the temperature and rose with an increase in the electron numerical density. Figure 3 and Figure 4 show the changes in Shannon information entropy ( Δ S ) as functions of the electron numerical density for the 1s state (Figure 3) and 2p state (Figure 4). The changes in Shannon information entropy as functions of the temperature are presented on Figure 5 (1s state) and Figure 6 (2p state). Also, one can see that the entropy change in excited states was more prominent than that in the ground state. This fact was mentioned in refs. [4,33,34,35,40,41].
Figure 7 and Figure 8 represent the surface plots of the entropy changes Δ S 1 s and Δ S 2 p , respectively, as a function of the temperature and electron numerical densities. These figures show that the influence of screening effects, quantum non-locality, and electronic correlations for the entropy changes Δ S 1 s and Δ S 2 p in the dense cold plasmas was more pronounced than in the rarefied hot plasmas.
Table 1 and Table 2 present the general behavior of the absolute change in Shannon entropies for hydrogen plasma Δ S 1 s (Table 1) and Δ S 2 p (Table 2) of an atom immersed in plasma compared to a free atom, i.e., S = S p l a s m a S f r e e . The calculations were performed for four values of the temperature at four values of electron number densities. We performed the calculations and present the results based on the following models: with the Debye–Huckel potential (DHP), with the Shalenov–Nuraly–Dzhumagulova potential (1) at k i       0 (SNDP-A), and, finally, with the Shalenov–Nurala–Dzhumagulova potential (1) at k i       0 ; (SNDP-B). The results corresponding to n e = 1 0 22   c m 3 were compared with the data of ref. [35], where the DHP was used.
As one can see, our DHP data were in good agreement with those obtained in ref. [35]. The results for SNDP-1 were slightly less than for DHP but the results for SNDP-B were approximately twice as large as the other results. This means that taking into account ionic screening leads to an increase in entropy, while taking into account only electronic screening does not lead to significant changes.
The results for the radial Shannon entropy S ( R n l ) (see Equation (9)) for hydrogen plasma for quantum numbers n 3 and l = 0,1 are presented in Table 3. The variation of the radial Shannon entropy with respect to n and l for free hydrogen was previously discussed by Jiao et al. [39] and Yanez et al. [42]. Here, it can be seen that our calculations for the isolated atom case (without plasma) were in excellent agreement with the data obtained in [39]. When we took into account the plasma effects based on potential (1) (the SNDP-B case), the results showed the same conclusions that we made based on Figure 1, Figure 2, Figure 3 and Figure 4.

5. Conclusions

In this paper, we investigated the effect of quantum non-locality as well as electronic correlations on the variation of the Shannon entropy for atomic states in dense plasmas. The results obtained were verified by comparison with data obtained by other authors for isolated atoms and atoms immersed in plasma at certain values of plasma parameters. In all cases, excellent agreement was noted.
The influence of temperature and electron density on the Shannon information entropy of atomic states in dense plasma was studied. It was concluded that quantum non-locality and electronic correlations are crucial for accurately describing entropy and atomic state distribution in dense plasmas. Therefore, Shannon atomic entropy can provide information about atomic states and plasma parameters, such as density and temperature. It would be useful in plasma diagnostics, as Shannon atomic entropy measures the transmission of quantum information [43] during atomic collisions and radiation processes depending on plasma conditions. These findings are significant for understanding dense plasmas in astrophysical objects and high-energy-density laboratory conditions, providing insights for controlled thermonuclear fusion, laser–plasma experiments, and the study of stellar interiors.

Author Contributions

Conceptualization, E.O.S. and K.N.D.; methodology, A.T.N. and E.O.S.; formal analysis, A.T.N. and M.M.S.; investigation, A.T.N. and M.M.S.; writing—original draft preparation, E.O.S. and K.N.D.; writing—review and editing, E.O.S. and K.N.D.; visualization, A.T.N. and M.M.S.; supervision, E.O.S. and K.N.D.; project administration, E.O.S. All authors have read and agreed to the published version of the manuscript.

Funding

The authors acknowledge support from the Committee of Science of the Ministry of Science and Higher Education of the Republic of Kazakhstan under grant no. AP19679049.

Institutional Review Board Statement

Not applicable.

Data Availability Statement

The data that support the findings of this study are available from the corresponding author upon reasonable request.

Conflicts of Interest

The authors declare no conflicts of interest.

References

  1. He, Y.Y.; Zhou, Z.L.; Jiao, L.G.; Liu, A.; Montgomery, H.E.; Ho, Y.K. Hyperpolarizabilities of Hydrogenlike Atoms in Debye and Dense Quantum Plasmas. Phys. Rev. E 2023, 107, 045201. [Google Scholar] [CrossRef] [PubMed]
  2. Li, X.N.; Zhang, Y.Z.; Jiao, L.G.; Wang, Y.C.; Montgomery, H.E.; Ho, Y.K.; Fritzsche, S. Geometric Properties of the Ground State of H- and He in Dense Quantum Plasmas. Eur. Phys. J. D 2023, 77, 59. [Google Scholar] [CrossRef]
  3. Hu, H.; Li, L.; Chen, Z.; Chen, W.; Liu, X.; Li, P. Shielding Effect of Quantum Plasma. Phys. Plasmas 2019, 26, 032123. [Google Scholar] [CrossRef]
  4. Verma, N.; Joshi, R. Shannon Entropy for Hydrogen Atom in Debye and Quantum Plasma Environment. Phys. Plasmas 2023, 30, 063905. [Google Scholar] [CrossRef]
  5. Colonna, G.; Laricchiuta, A. Thermodynamic and Transport Properties of Equilibrium Debye Plasmas. Entropy 2020, 22, 237. [Google Scholar] [CrossRef] [PubMed]
  6. Karmakar, A.; Ghoshal, A. Scattering in Non-Ideal Classical Plasmas: Scattering Length and Zero-Energy Resonances. Phys. Plasmas 2019, 26, 102114. [Google Scholar] [CrossRef]
  7. Lumb Talwar, S.; Lumb, S.; Sen, K.D.; Prasad, V. Non-Ideal Classical Plasma: Laser Pulse Effects and Dynamic Dipole Polarizabilities. J. Phys. B At. Mol. Opt. Phys. 2023, 56, 145001. [Google Scholar] [CrossRef]
  8. Das, B.; Ghoshal, A. Scattering of Slow Electron from Hydrogen Atom in Non-Ideal Classical Plasmas: Zero-Energy Resonances. Phys. Plasmas 2021, 28, 042106. [Google Scholar] [CrossRef]
  9. Chen, C.; Zhao, G.P.; Qi, Y.Y.; Liu, L.; Chen, Z.B.; Wang, J.G. Total, State-Selective, and Angular-Differential Cross Sections for Electron Capture in He2++H Collisions in Warm Dense Plasmas. Phys. Plasmas 2022, 29, 062110. [Google Scholar] [CrossRef]
  10. Shalenov, E.O.; Dzhumagulova, K.N.; Ramazanov, T.S.; Reinholz, H.; Ropke, G. Influence of Dynamic Screening on the Conductivity of Hydrogen Plasma Including Electron–Electron Collisions. Contrib. Plasma Phys. 2019, 59, e201900024. [Google Scholar] [CrossRef]
  11. Shalenov, E.O.; Dzhumagulova, K.N.; Ramazanov, T.S.; Ropke, G.; Reinholz, H. Dynamical Conductivity of the Dense Semiclassical Plasmas on the Basis of the Effective Potential. Phys. Plasmas 2018, 25, 082706. [Google Scholar] [CrossRef]
  12. Shalenov, E.O.; Rosmej, S.; Reinholz, H.; Ropke, G.; Dzhumagulova, K.N.; Ramazanov, T.S. Optical Reflectivity Based on the Effective Interaction Potentials of Xenon Plasma. Contrib. Plasma Phys. 2017, 57, 486. [Google Scholar] [CrossRef]
  13. Dzhumagulova, K.N.; Shalenov, E.O.; Ramazanov, T.S. Elastic Scattering of Low Energy Electrons in Partially Ionized Dense Semiclassical Plasma. Phys. Plasmas 2015, 22, 082120. [Google Scholar] [CrossRef]
  14. Jumagulov, M.N.; Seisembayeva, M.M.; Shalenov, E.O.; Kossymkyzy, Z.; Ramazanov, T.S.; Dzhumagulova, K.N. Electron Runaway in a Dense Semiclassical Plasma. High Energy Density Phys. 2020, 36, 100832. [Google Scholar] [CrossRef]
  15. Shalenov, E.O.; Seisembayeva, M.M.; Dzhumagulova, K.N.; Ramazanov, T.S. Effect of Dynamic Screening on the Electron Capture Process in Nonideal Plasma. J. Phys. Conf. Ser. 2019, 1385, 012031. [Google Scholar] [CrossRef]
  16. Shalenov, E.O.; Seisembayeva, M.M.; Dzhumagulova, K.N.; Ramazanov, T.S. Kinetic Ionization and Recombination Coefficients in the Dense Semiclassical Plasmas on the Basis of the Effective Interaction Potential. J. Phys. Conf. Ser. 2019, 1400, 077035. [Google Scholar] [CrossRef]
  17. Ma, K.; Chen, C.; Chu, Y.; Jiao, Z.; Chen, Z.B. Theoretical Calculations on the Relativistic Corrections and Photoionization Cross Sections for Hydrogenlike Ions in Finite Temperature Dense Plasmas. Few-Body Syst. 2022, 63, 6. [Google Scholar] [CrossRef]
  18. Chen, Z.B.; Zhao, G.P.; Qi, Y.Y. Theoretical Studies of the Spectral Characteristics and Electron Impact Dynamics of Ti XXI Placed in the Hot Dense Regimes. J. Electron Spectrosc. Relat. Phenom. 2023, 262, 147283. [Google Scholar] [CrossRef]
  19. Roozehdar Mogaddam, R.; Sepehri Javan, N.; Javidan, K.; Mohammadzadeh, H. Entanglement Fidelity Ratio for Elastic Collisions in Non-Ideal Two-Temperature Dense Plasma. Phys. Scr. 2020, 95, 115601. [Google Scholar] [CrossRef]
  20. Mahdavi, M.; Akbarian, H. Calculation of Effective Potential of Hulthen Interaction for a Nonideal Dense Plasma Using Dielectric Response Method. Chin. J. Phys. 2022, 77, 1237. [Google Scholar] [CrossRef]
  21. Parpia, F.A.; Fischer, C.F. Generalized Coulomb Screening in Dense Plasmas: A Numerical Approach. Phys. Rev. A 2023, 107, 012702. [Google Scholar] [CrossRef]
  22. Sharma, A.; Agrawal, M.; Vyas, M.; Sen, K.D.; Montgomery, H.E.; Ho, Y.K. Thermodynamic Properties and Information-Theoretic Measures for Hydrogenic Atoms in Quantum Plasmas. Phys. Rev. A 2022, 106, 022802. [Google Scholar] [CrossRef]
  23. Yadav, A.; Mishra, S.P. Positional and Momentum Shannon Entropies of Hydrogenic Atoms in Weakly Coupled Debye Plasmas. Entropy 2023, 25, 260. [Google Scholar] [CrossRef]
  24. Dzhumagulova, K.N.; Shalenov, E.O.; Tashkenbayev, Y.A.; Ramazanov, T.S. Study of the Electron-Atom Collisions in Dense Semiclassical Plasma of Noble Gases. J. Plasma Phys. 2022, 88, 905880001. [Google Scholar] [CrossRef]
  25. Dzhumagulova, K.N.; Shalenov, E.O.; Tashkenbayev, Y.A.; Ramazanov, T.S. Electron-Atom Interactions in Dense Semiclassical Helium Plasma. Phys. Plasmas 2022, 29, 102705. [Google Scholar] [CrossRef]
  26. Shalenov, E.O.; Nuraly, A.T.; Dzhumagulova, K.N. Bound States of the Hydrogen Atom in High-Density Plasmas. Contrib. Plasma Phys. 2022, 62, e202200017. [Google Scholar] [CrossRef]
  27. Zeng, J.; Jiang, X.; Cheng, G.; Wu, J.; Yuan, J. Electron Localization Induced Increase in the Electron Impact Excitation Cross Sections and Rate Coefficients of Ions Embedded in a Dense Plasma. Results Phys. 2024, 58, 107522. [Google Scholar] [CrossRef]
  28. Zhdankin, V. Generalized Entropy Production in Collisionless Plasma Flows and Turbulence. Physical Review. X 2022, 12, 031011. [Google Scholar] [CrossRef]
  29. Souza, L.C.; Sales, M.R.; Mugnaine, M.; Szezech, J.D.; Caldas, I.L.; Viana, R.L. Chaotic Escape of Impurities and Sticky Orbits in Toroidal Plasmas. Phys. Rev. E 2024, 109, 015202. [Google Scholar] [CrossRef]
  30. Krommes, J.A. Fundamental Statistical Descriptions of Plasma Turbulence in Magnetic Fields. Phys. Rep. 2002, 360, 1–352. [Google Scholar] [CrossRef]
  31. Livadiotis, G. Derivation of the Entropic Formula for the Statistical Mechanics of Space Plasmas. Nonlinear Process. Geophys. 2018, 25, 77–88. [Google Scholar] [CrossRef]
  32. Rastovic, D. Applications of Artificial Intelligence and Multi-Variable Control of Chaos on Tokamak Equilibriums. In Glow Discharges and Tokamaks; Murphy, S.A., Ed.; Nova Science Publishers: New York, NY, USA, 2011; Chapter 10; pp. 407–418. ISBN 978-1-61668-352-8. [Google Scholar]
  33. Lee, M.-J.; Jung, Y.-D. Characteristics of Shannon’s Information Entropy of Atomic States in Strongly Coupled Plasma. Entropy 2020, 22, 881. [Google Scholar] [CrossRef] [PubMed]
  34. Jung, Y.-D.; Lee, M.-J. Atomic Shannon entropy in astrophysical nonthermal plasmas. Presented at the XXIX International Conference on Neutrino Physics and Astrophysics, Online conference, June 2020. Available online: https://indico.fnal.gov/event/19348/contributions/186622/ (accessed on 22 June 2020).
  35. Lee, M.; Jung, Y. Astronomical Data of Atomic Shannon Entropies in Astrophysical Lorentzian Plasmas. Astrophys. J. 2019, 871, 111. [Google Scholar] [CrossRef]
  36. Groth, S.; Dornheim, T.; Sjostrom, T.; Malone, F.D.; Foulkes, W.M.C.; Bonitz, M. Ab Initio Exchange-Correlation Free Energy of the Uniform Electron Gas at Warm Dense Matter Conditions. Phys. Rev. Lett. 2017, 119, 135001. [Google Scholar] [CrossRef] [PubMed]
  37. Chen, Z.-B.; Qi, Y.-Y.; Sun, H.-Y.; Zhao, G.-P.; Liu, P.-F. Systematic Investigations of Level Delocalization and Spectroscopy of Hydrogen Atom Subjected to a Plasma Environment Using Various Statically Screened Potentials. Phys. Plasmas 2020, 27, 072105. [Google Scholar] [CrossRef]
  38. Stanton, L.G.; Murillo, M.S. Unified Description of Linear Screening in Dense Plasmas. Phys. Rev. E 2015, 91, 033104. [Google Scholar] [CrossRef]
  39. Jiao, L.G.; Zan, L.R.; Zhang, Y.Z.; Ho, Y.K. Benchmark Values of Shannon Entropy for Spherically Confined Hydrogen Atom. Int. J. Quantum Chem. 2017, 117, 13. [Google Scholar] [CrossRef]
  40. Lin, C.-H.; Ho, Y. Quantum Entanglement and Shannon Information Entropy for the Doubly Excited Resonance State in Positronium Negative Ion. Atoms 2015, 3, 422–432. [Google Scholar] [CrossRef]
  41. Zan, L.R.; Jiao, L.G.; Ma, J.; Ho, Y.K. Information-Theoretic Measures of Hydrogen-Like Ions in Weakly Coupled Debye Plasmas. Phys. Plasmas 2017, 24, 122101. [Google Scholar] [CrossRef]
  42. Yanez, R.J.; Van Assche, W.; Dehesa, J.S. Position and Momentum Information Entropies of the D-Dimensional Harmonic Oscillator and Hydrogen Atom. Phys. Rev. A 1994, 50, 3065–3079. [Google Scholar] [CrossRef]
  43. Mishima, K.; Hayashi, M.; Lin, S. Entanglement in Scattering Processes. Phys. Lett. A 2004, 333, 371. [Google Scholar] [CrossRef]
Figure 1. Atomic density distribution of the hydrogen atom in the ground state (a), n e = 10 24   c m 3 , and excited state (b), n e = 10 23   c m 3 .
Figure 1. Atomic density distribution of the hydrogen atom in the ground state (a), n e = 10 24   c m 3 , and excited state (b), n e = 10 23   c m 3 .
Entropy 26 00602 g001
Figure 2. Atomic density distribution of the hydrogen atom in the ground state (a) and excited state (b), T = 40 eV.
Figure 2. Atomic density distribution of the hydrogen atom in the ground state (a) and excited state (b), T = 40 eV.
Entropy 26 00602 g002
Figure 3. Entropy changes Δ S 1 s plotted as functions of the electron numerical density at different temperatures.
Figure 3. Entropy changes Δ S 1 s plotted as functions of the electron numerical density at different temperatures.
Entropy 26 00602 g003
Figure 4. Entropy changes Δ S 2 p plotted as functions of the electron numerical density at different temperatures.
Figure 4. Entropy changes Δ S 2 p plotted as functions of the electron numerical density at different temperatures.
Entropy 26 00602 g004
Figure 5. Entropy changes Δ S 1 s plotted as a function of the temperature at different electron numerical densities.
Figure 5. Entropy changes Δ S 1 s plotted as a function of the temperature at different electron numerical densities.
Entropy 26 00602 g005
Figure 6. Entropy changes Δ S 2 p plotted as a function of the temperature at different electron numerical densities.
Figure 6. Entropy changes Δ S 2 p plotted as a function of the temperature at different electron numerical densities.
Entropy 26 00602 g006
Figure 7. The surface plots of the entropy changes Δ S 1 s as a function of the temperature and electron numerical densities.
Figure 7. The surface plots of the entropy changes Δ S 1 s as a function of the temperature and electron numerical densities.
Entropy 26 00602 g007
Figure 8. The surface plots of the entropy changes Δ S 2 p as a function of the temperature and electron numerical densities.
Figure 8. The surface plots of the entropy changes Δ S 2 p as a function of the temperature and electron numerical densities.
Entropy 26 00602 g008
Table 1. Shannon entropy changes Δ S 1 s for hydrogen plasma compared with the results of ref. [35]. DHP: present work with Debye–Huckel potential ( λ e e = 0 , k i   = 0 ); SNDP-A: present work with Shalenov–Nuraly–Dzhumagulov potential (1),   k i   = 0 ; SNDP-B: present work with Shalenov–Nuraly–Dzhumagulov potential (1), k i     0 .
Table 1. Shannon entropy changes Δ S 1 s for hydrogen plasma compared with the results of ref. [35]. DHP: present work with Debye–Huckel potential ( λ e e = 0 , k i   = 0 ); SNDP-A: present work with Shalenov–Nuraly–Dzhumagulov potential (1),   k i   = 0 ; SNDP-B: present work with Shalenov–Nuraly–Dzhumagulov potential (1), k i     0 .
T , [ e V ] Model l g ( n e , [ c m 3 ] )
21222324
50.5DHP0.0021560.019815 0.019826 a0.1554260.830312
SNDP-A0.0020510.0187730.1457970.773562
SNDP-B0.0041340.0366850.265969-
202DHP0.0005500.005263 0.005272 b0.0461960.325082
SNDP-A0.0005420.0051860.0454460.318487
SNDP-B0.0010830.0101800.0852250.545540
454.5DHP0.0002460.002389 0.002393 c0.0218430.170048
SNDP-A0.0002440.0023730.0216870.168575
SNDP-B0.0004880.0046790.0413580.297958
808DHP0.0001390.001358 0.001361 d0.0126870.104340
SNDP-A0.0001380.0013530.0126360.103853
SNDP-B0.0002760.0026750.0243410.187644
a Ref. [35], r D = 10 a B ; b ref. [35], r D = 20 a B ; c ref. [35], r D = 30 a B ; d ref. [35], r D = 40 a B .
Table 2. Shannon entropy changes Δ S 2 p for hydrogen plasma compared with the results of ref. [35]. DHP: present work with Debye–Huckel potential ( λ e e = 0 , k i   = 0 ) ; SNDP-A: present work with Shalenov–Nuraly–Dzhumagulova potential (1),   k i   = 0 ; SNDP-B: present work with Shalenov–Nuraly–Dzhumagulova potential (1), k i     0 .
Table 2. Shannon entropy changes Δ S 2 p for hydrogen plasma compared with the results of ref. [35]. DHP: present work with Debye–Huckel potential ( λ e e = 0 , k i   = 0 ) ; SNDP-A: present work with Shalenov–Nuraly–Dzhumagulova potential (1),   k i   = 0 ; SNDP-B: present work with Shalenov–Nuraly–Dzhumagulova potential (1), k i     0 .
T , [ e V ] Model l g ( n e , [ c m 3 ] )
20212223
50.5DHP0.0028790.0265890.213152 0.213257 a-
SNDP-A0.0028660.0264570.211904-
SNDP-B0.0056550.0506430.378147-
202DHP0.0007330.0070400.062325 0.062422 b0.453349
SNDP-A0.0007320.0070320.0622430.452619
SNDP-B0.0014550.0137320.116375-
454.5DHP0.0003280.0031920.029345 0.029395 c0.232816
SNDP-A0.0003280.0031900.0293280.232663
SNDP-B0.0006520.0062770.0559170.412632
808DHP0.0001850.0018140.017010 0.017040 d0.141772
SNDP-A0.0001850.0018130.0170040.141723
SNDP-B0.0003680.0035820.0327710.257123
a Ref. [35], r D = 10 a B ; b ref. [35], r D = 20 a B ; c ref. [35], r D = 30 a B ; d ref. [35], r D = 40 a B .
Table 3. Radial Shannon entropy S ρ for hydrogen plasma for quantum numbers n 3 and l = 0,1 . PFJ: plasma-free, Jiao et al. [39]; PFPW: plasma-free, present work.
Table 3. Radial Shannon entropy S ρ for hydrogen plasma for quantum numbers n 3 and l = 0,1 . PFJ: plasma-free, Jiao et al. [39]; PFPW: plasma-free, present work.
Plasma Type l g ( n e , c m 3 ) 1s2s3s2p3p
PFJ-1.613715.579917.895465.165827.70677
PFPW-1.613715.579997.895965.165897.70723
T = 20 eV 191.613815.581657.904015.167287.71472
201.614755.596277.969785.179617.77645
211.623535.714498.406445.282638.19733
T = 10 eV 191.613915.583357.912085.168697.72225
201.615715.611238.032775.192357.83611
211.631995.821208.737115.378148.52553
T = 5 eV 191.614105.586627.927415.171427.73658
201.617465.638898.142615.215997.94099
211.646785.99741-5.53953-
Disclaimer/Publisher’s Note: The statements, opinions and data contained in all publications are solely those of the individual author(s) and contributor(s) and not of MDPI and/or the editor(s). MDPI and/or the editor(s) disclaim responsibility for any injury to people or property resulting from any ideas, methods, instructions or products referred to in the content.

Share and Cite

MDPI and ACS Style

Nuraly, A.T.; Seisembayeva, M.M.; Dzhumagulova, K.N.; Shalenov, E.O. Impact of Quantum Non-Locality and Electronic Non-Ideality on the Shannon Entropy for Atomic States in Dense Plasma. Entropy 2024, 26, 602. https://doi.org/10.3390/e26070602

AMA Style

Nuraly AT, Seisembayeva MM, Dzhumagulova KN, Shalenov EO. Impact of Quantum Non-Locality and Electronic Non-Ideality on the Shannon Entropy for Atomic States in Dense Plasma. Entropy. 2024; 26(7):602. https://doi.org/10.3390/e26070602

Chicago/Turabian Style

Nuraly, Askhat T., Madina M. Seisembayeva, Karlygash N. Dzhumagulova, and Erik O. Shalenov. 2024. "Impact of Quantum Non-Locality and Electronic Non-Ideality on the Shannon Entropy for Atomic States in Dense Plasma" Entropy 26, no. 7: 602. https://doi.org/10.3390/e26070602

Note that from the first issue of 2016, this journal uses article numbers instead of page numbers. See further details here.

Article Metrics

Back to TopTop