A van der Waals Model of Solvation Thermodynamics
Abstract
:1. Introduction
2. A van der Waals Binary Solution
3. Solvation Thermodynamics
4. Some Calculations
5. Conclusions
Author Contributions
Funding
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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σ1 Å | v1 cm3 mol−1 | αP,1·103 K−1 | b1 Å3 | ΔGc kJ mol−1 | ΔHc kJ mol−1 | ΔSc J K−1mol−1 | ΔSx J K−1mol−1 | ΔHc/T J K−1mol−1 | |
---|---|---|---|---|---|---|---|---|---|
water | 2.80 | 18.07 | 0.257 | 18.0 | 13.0 | 2.3 | −35.9 | −43.6 | 7.7 |
methanol | 3.83 | 40.73 | 1.189 | 46.0 | 8.8 | 8.5 | −1.0 | −29.5 | 28.5 |
ethanol | 4.44 | 58.68 | 1.089 | 71.6 | 8.3 | 8.4 | 0.4 | −27.8 | 28.2 |
CCl4 | 5.37 | 97.09 | 1.226 | 126.7 | 7.6 | 9.7 | 7.0 | −25.5 | 32.5 |
n-hexane | 5.92 | 131.62 | 1.390 | 169.7 | 6.5 | 8.8 | 7.7 | −21.8 | 29.5 |
n-decane | 7.08 | 195.94 | 1.020 | 290.3 | 9.2 | 16.5 | 24.4 | −30.9 | 55.3 |
c-hexane | 5.63 | 108.75 | 1.214 | 146.0 | 7.9 | 10.9 | 10.1 | −26.5 | 36.6 |
benzene | 5.26 | 89.40 | 1.240 | 119.1 | 8.5 | 12.0 | 11.7 | −28.5 | 40.2 |
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Tortorella, A.; Graziano, G. A van der Waals Model of Solvation Thermodynamics. Entropy 2024, 26, 714. https://doi.org/10.3390/e26080714
Tortorella A, Graziano G. A van der Waals Model of Solvation Thermodynamics. Entropy. 2024; 26(8):714. https://doi.org/10.3390/e26080714
Chicago/Turabian StyleTortorella, Attila, and Giuseppe Graziano. 2024. "A van der Waals Model of Solvation Thermodynamics" Entropy 26, no. 8: 714. https://doi.org/10.3390/e26080714