2.2. Tsallis Statistics
Boltzmann–Gibbs (BG) statistics work perfectly for classical systems with short-range forces and relatively simple dynamics in equilibrium. Tsallis proposed a generalization of the BG statistics [
35,
36,
37,
38]. In the new frame, entropy is not an extensive property.
Tsallis statistics have been successfully applied to complex systems. For them, the formalism of nonextensive statistical mechanics is a helpful concept that incorporates correlations between subsystems. A more general Boltzmann factor is introduced, which depends on an entropic index
and which, for
q = 1, reduces to the ordinary Boltzmann–Gibbs statistics [
35].
In conventional BG statistics, we use the entropy from information theory, i.e.,
, where
is the probability associated with an event and
is the total number of possible (microscopic) configurations. Tsallis postulates that, in nonextensive systems, the entropy is
where
is any real number. From Equation (1), one can obtain the BG statistics with
, and we can also obtain the additive property to entropy for a system with two probabilistically independent subsystems
and
(i.e., if
) [
37], such as quarks and gluons inside a hadron as
where, in contrast with
, which is additive, entropy
is non-additive for
. This non-additivity will make it extensive for various classes of systems [
38].
Several types of generalized stochastic dynamics have been studied, for which Tsallis statistics can be proved rigorously. Physical applications include high-energy physics [
39], 2D and 3D turbulence [
40,
41,
42,
43], the statistics of cosmic rays [
44,
45], and many other phenomena [
36].
2.3. Description of a Simple Hadron Model
In the MIT bag model, quarks are treated as free particles confined inside a finite region of space. The system’s stability is maintained by an external, constant pressure applied to the bag’s surface. Confinement arises from the equilibrium between the internal pressure
exerted by the quarks and gluons and the bag pressure
. This parameter,
, is a key phenomenological quantity in the model, encapsulating the nonperturbative effects of Quantum Chromodynamics (QCD), thus making it central to understanding the dynamics of confinement. The relationship between bag pressure
and radius
is:
where
is the number of quarks. The bag model pressure has dimensions of energy divided by volume. In natural units where
,
has dimensions of mass. We use natural units throughout the derivations, and we express
in MeV and
in femtometers (fm) and GeV
−1.
We shall consider only bags with static, spherical boundaries and quark, antiquark, and gluon systems with no interaction, with an equal number of quarks and antiquarks. At high temperatures (where quarks and gluons have large momentum), the gluons behave like an ultra-relativistic Bose gas. The pressure arising from the gluons is detailed in [
46,
47]; the gluon pressure is therefore given by:
where
is the system’s temperature. In natural units and considering the degeneracy due to gluons
(where the factor of 8 is due to generators of the SU(3) group of gluons, and the factor of 2 is due to spin orientation), we have the gluon pressure:
On the other hand, we have the creation–annihilation processes between quarks and antiquarks, and from this we treat the system as a mixed gas. Although quarks and antiquarks undergo creation–annihilation processes, we do not consider the particles and remnants of these processes, and we obtain a relation between the number of quarks and antiquarks (their difference) and their chemical potentials,
. Additionally, we assume that momentum is large enough compared to rest mass to let
. Thus, the quark pressure of the system is given by
Since the quark degeneracy factor is
(where the factor of 2 is due to flavor number as we consider only up and down quarks; the factor of 3 is due to color charge, and the factor of 2 is due to spin orientation), the quark pressure becomes
From Equation (3), the entropy for a hadron with quarks, antiquarks, and gluons (in natural units) is:
Equation (8) is a special case in which we consider that the quark and gluon entropy is BG entropy, but the combined quark–gluon entropy is not of the BG type; this is because we are considering that particles of the same type do not self-interact, that is, quarks and antiquarks do not self-interact between them, and gluons do not interact between them, but gluons and quarks (and antiquarks) do interact between them as a first approximation. Thus,
and
correspond to this case of no self-interaction. We can rewrite Equation (8) as
where
stands for quark and antiquark BG entropy, and
is the gluon BG entropy. From [
48], we have that (in the ultra-relativistic fermion/boson gas regime for each), the quark and gluon entropies are, respectively
where
is the bag volume. From Equations (9) and (10), the Tsallis entropy is:
Using the Maxwell relation
, the Tsallis pressure is:
where
is an integration constant. Since, for
, the standard total pressure must be recovered, and the integration constant is:
Substituting (12) into (11), the non-additive total pressure for the quark–gluon system is:
By using the Maxwell relation
, we can obtain an expression for the system’s internal energy. From this last relation, we have two expressions:
where
is the Helmholtz energy using Tsallis statistics. From (14), the Helmholtz energy is:
where
is an integration constant that only depends on
. However, we can assume that the integration constant is zero, given the free choice of the zero-point energy.
The internal energy of the hadron is given by
which matches with the energy of the quarks (as an ultra-relativistic Fermi gas) and gluons (as an ultra-relativistic Bose gas) when
:
2.4. Volume and Temperature Dependence on the Bag Radius
In [
49], an expression is derived for temperature as a function of the radius of a hypothetical “bag,” representing a quark–gluon plasma system in this work. The system has specified values of
and
, with a zero-chemical potential, and the mass of the nucleons approximates the total energy. Under these assumptions, the authors propose a formula for temperature:
In Equation (19), is the radius from the proton’s center, measured in femtometers (fm), and in GeV. When the radius of a proton is less than 0.6 fm, the temperature approaches 170 MeV, which is close to the critical temperature at which the hadron deconfines.
It is worth mentioning that the temperature Equation (19) is derived from experimental data on energies measured at distinct radii within the proton. However, there exists a minimum radius at which the bag can remain stable. Additionally, the bag’s volume can be expressed as a function of its radius:
2.5. Hadron Mass in the MIT Bag Model
The MIT bag model provides a framework for estimating the masses and other properties of hadrons by modeling them as a spherical bag [
34]. The mass formula is given by:
and
We will use this expression to estimate radii in tetraquarks and pentaquarks. In (20), the first term represents the kinetic energy of all quarks within the bag of radius
, and
is the frequency of the lowest mode. The second term corresponds to the volume energy. The third term accounts for the zero-point energy, and
denotes the short-range interactions between quarks. Also,
represents the number of quarks or antiquarks. In (21),
is the mass of a quark of flavor
, i.e., the light non-strange quarks (u,d), the strange quark (s), the charm quark (c), or the bottom quark (b). The dimensionless parameter
is related to the bag radius by a transcendental eigenequation:
The interaction energy consists of two additional terms: . is the spin-binding energy that arises from the short-range chromoelectric interaction between quarks and antiquarks. This energy becomes significant only when both quarks involved are massive and move non-relativistically.
represents the chromomagnetic interaction energy arising from the perturbative gluon exchange between quarks
and
. It is defined as
where
are the Gell-Mann matrices,
are the Pauli matrices, and
is the chromomagnetic parameter given by
where
is the running strong coupling,
is the reduced magnetic moment without electric charge, and
is a rational function of
and
, given explicitly in [
34,
50].
2.6. Tsallis Parameter Fitting Method
Hadrons were grouped according to their spin to determine the parameter . This classification is justified because, in the MIT bag model, the chromomagnetic interaction (resulting from the perturbative exchange of gluons between quarks) depends on the flavor, spin, and color wave functions. Therefore, the fits were performed to preserve this physical dependence while respecting this structure.
The value of was obtained using Equation (17). For each hadronic group, the experimental values of mass and radius (charge radius for light hadrons or MIT radius for exotic states) were used, and a least-squares fit was performed to determine the value of that best reproduces the experimental masses. We use experimentally extracted radii for the light hadron masses to test our ideas against observed values. When considering radii derived from the MIT model for light hadrons as well, we found no significant changes in the overall description. The uncertainty associated with each value was estimated from the covariance matrix of the fit. These uncertainties, as well as those associated with the experimental or MIT radius, were propagated to compute the errors in the theoretical masses, which are reported in the corresponding tables and figures.
In summary, the contributions to entropy and pressure from quarks and gluons within the bag model were calculated. These quantities were then transformed into their non-additive forms using Tsallis statistics. The Helmholtz free energy and total internal energy of the quark–gluon system were subsequently computed (cf. Equations (16) and (17)). Temperature and volume were expressed as functions of the parameters , , and . The chemical potential was determined for each hadronic group. Subsequently, the parameter r was calculated for exotic hadrons (tetraquarks and pentaquarks) by solving Equation (21) (the mass expression discussed in the previous section) for . Finally, the corresponding values of the non-extensivity parameter were obtained through data fitting, and the hadron masses were computed using the modified energy expression given in Equation (26).
It is important to emphasize that, when , the Tsallis formalism reduces to the standard Boltzmann–Gibbs statistics, and Equation (17) recovers the usual internal energy of an ideal ultra-relativistic quark–gluon gas, equivalent to the standard MIT bag model. Deviations from reflect nonextensive statistical behaviors that may capture additional correlations, collective effects, or long-range interactions among quarks and gluons inside the hadron.