Degradation Kinetics of Anthocyanins from European Cranberrybush (Viburnum opulus L.) Fruit Extracts. Effects of Temperature, pH and Storage Solvent
Abstract
:1. Introduction
2. Results and Discussion
2.1. Total Anthocyanins Content
2.2. Degradation Kinetics of Anthocyanins during Storage
pH | Temp. (°C) | Solvent | k × 103 (h−1) a | t1/2 (h) |
---|---|---|---|---|
3 | 2 | Water | 0.6 (0.9503) | 1,155 |
3 | 37 | Water | 6.4 (0.9740) | 108.28 |
3 | 75 | Water | 46.1 (0.9971) | 15.03 |
7 | 2 | Water | 2.8 (0.9680) | 247.5 |
7 | 37 | Water | 30.5 (0.9944) | 22.72 |
7 | 75 | Water | 348.8 (0.9762) | 1.98 |
3 | 2 | Ethanol/Water | 1.3 (0.9575) | 533.07 |
3 | 37 | Ethanol/Water | 13.6 (0.9602) | 50.95 |
3 | 75 | Ethanol/Water | 53.9 (0.9948) | 12.86 |
7 | 2 | Ethanol/Water | 2.5 (0.9298) | 277.2 |
7 | 37 | Ethanol/Water | 38.5 (0.9867) | 18.0 |
7 | 75 | Ethanol/Water | 189.3 (0.9824) | 3.66 |
pH | Solvent | Ea (kJ/mol)a | Ko (h−1) | Q10 | |
---|---|---|---|---|---|
2-37 °C | 37-75 °C | ||||
3 | Water | 47.39 (0.9886) | 5.94 × 105 | 1.018 | 1.681 |
7 | 52.47 (0.9975) | 2.43 × 107 | 1.978 | 1.898 | |
3 | Ethanol/Water | 40.79 (0.9890) | 8.08 × 104 | 1.956 | 1.436 |
7 | 47.34 (0.9999) | 2.84 × 106 | 2.184 | 1.52 |
3. Experimental
3.1. Plant Material
3.2. Chemicals and Reagents
3.3. Preparation of Ethanolic and Aqueous Anthocyanin Extracts
3.4. Determination of Anthocyanin Content
3.5. Degradation Studies
pH | Temp. (°C) | Solvent | Total storage time (h) |
---|---|---|---|
3 | 2 | Water | 167 |
3 | 37 | Water | 48 |
3 | 75 | Water | 72 |
7 | 2 | Water | 167 |
7 | 37 | Water | 14 |
7 | 75 | Water | 12 |
3 | 2 | Ethanol/Water | 167 |
3 | 37 | Ethanol/Water | 145 |
3 | 75 | Ethanol/Water | 72 |
7 | 2 | Ethanol/Water | 145 |
7 | 37 | Ethanol/Water | 97 |
7 | 75 | Ethanol/Water | 14 |
3.6. Data Analysis
4. Conclusions
Acknowledgements
- Sample Availability: Samples of the extracts are available from the authors.
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Moldovan, B.; David, L.; Chişbora, C.; Cimpoiu, C. Degradation Kinetics of Anthocyanins from European Cranberrybush (Viburnum opulus L.) Fruit Extracts. Effects of Temperature, pH and Storage Solvent. Molecules 2012, 17, 11655-11666. https://doi.org/10.3390/molecules171011655
Moldovan B, David L, Chişbora C, Cimpoiu C. Degradation Kinetics of Anthocyanins from European Cranberrybush (Viburnum opulus L.) Fruit Extracts. Effects of Temperature, pH and Storage Solvent. Molecules. 2012; 17(10):11655-11666. https://doi.org/10.3390/molecules171011655
Chicago/Turabian StyleMoldovan, Bianca, Luminiţa David, Cristian Chişbora, and Claudia Cimpoiu. 2012. "Degradation Kinetics of Anthocyanins from European Cranberrybush (Viburnum opulus L.) Fruit Extracts. Effects of Temperature, pH and Storage Solvent" Molecules 17, no. 10: 11655-11666. https://doi.org/10.3390/molecules171011655