A 3-D Metal-Organic Framework Constructed with Manganese(ΙΙ), 4,4'-Oxybis(benzoic acid) and 2,2'-Biphenyl: Synthesis, Crystal Structure and Photoelectric Property Characterization
Abstract
:1. Introduction
2. Results and Discussion
2.1. Crystal Structure Descriptions
2.2. Fluorescence Emission Properties
2.3. Electrochemical Properties
3. Experimental
3.1. Materials and Instrumentation
3.2. Synthesis of (3-D) Coordination Framework 1
3.3. X-ray Structure Determination
Empirical formula | C62H40Mn3N4O15 |
---|---|
Temperature (K) | 1245.80 |
Wavelength (Å) | 296(2) |
Crystal system | 0.71073 |
space group | Monoclinic |
a (Å) | C2/c |
b (Å) | 14.230(4) |
c (Å) | 17.019(2) |
α (°) | 25.805(3) |
β (°) | 90 |
γ (°) | 92.932(2) |
V (Å3) | 90 |
Z | 6241.5(9) |
Dc (Mg/m3) | 4 |
µ (mm−1) | 1.326 |
F (000) | 0.664 |
Crystal size (mm) | 2540 |
θ range | 0.35 × 0.34 × 0.32 |
Reflections collected | 1.87–25.00 |
Independent reflections | 5493 |
Completeness to θ = 25.00 | 5493 [R(int) = 0.0012] |
Absorption correction | 0.999 |
Max. and min. transmission | Multi-scan |
Data/restraints/parameters | 0.8156 and 0.8008 |
Goodness-of-fit on F | 5493/0/381 |
R indices [I > 2σ(I)] | 1.07 |
R indices (all data) | R1 = 0.0288, wR2 = 0.0732 |
Mn(1)-O(8) 2.0740(13) | O(1)#3-Mn(2)-O(5)#2 93.51(5) |
---|---|
Mn(1)-O(2)#1 2.0820(13) | O(5)-Mn(2)-O(5)#2 180.0 |
Mn(1)-O(4) 2.1794(13) | O(4)-Mn(1)-N(2) 90.99(6) |
Mn(1)-N(1) 2.2612(15) | N(1)-Mn(1)-N(2) 71.66(6) |
Mn(1)-N(2) 2.2625(17) | O(8)-Mn(1)-O(5) 93.82(5) |
Mn(1)-O(5) 2.4032(12) | O(2)#1-Mn(1)-O(5) 105.45(5) |
Mn(2)-O(7) 2.1782(12) | O(4)-Mn(1)-O(5) 56.89(4) |
Mn(2)-O(7)#2 2.1782(12) | N(1)-Mn(1)-O(5) 148.94(5) |
Mn(2)-O(1)#1 2.1801(12) | N(2)-Mn(1)-O(5) 91.70(6) |
Mn(2)-O(1)#3 2.1801(12) | O(7)-Mn(2)-O(7)#2 180.00(6) |
Mn(2)-O(5)#2.2451(12) | O(7)-Mn(2)-O(1)#1 90.51(5) |
Mn(2)-O(5)#2 2.2451(12) | O(7)#2-Mn(2)-O(1)#1 89.49(5) |
O(1)-Mn(2)#4 2.1801(12) | O(7)-Mn(2)-O(1)#3 89.49(5) |
O(2)-Mn(1)#5 2.0821(13) | O(7)#2-Mn(2)-O(1)#3 90.51(5) |
O(8)-Mn(1)-O(2)#1 92.42(6) | O(1)#1-Mn(2)-O(1)#3 180.0 |
O(8)-Mn(1)-O(4) 150.68(5) | O(7)-Mn(2)-O(5) 87.41(5) |
O(2)#1-Mn(1)-O(4) 96.77(6) | O(7)#2-Mn(2)-O(5) 92.59(5) |
O(8)-Mn(1)-N(1) 111.11(6) | O(1)#1-Mn(2)-O(5) 93.51(5) |
O(2)#1-Mn(1)-N(1) 92.13(5) | O(1)#3-Mn(2)-O(5) 86.49(5) |
O(4)-Mn(1)-N(1) 96.35(5) | O(7)-Mn(2)-O(5)#2 92.59(5) |
O(8)-Mn(1)-N(2) 88.19(6) | O(7)#2-Mn(2)-O(5)#2 87.41(5) |
O(2)#1-Mn(1)-N(2) 162.76(6) | O(1)#1-Mn(2)-O(5)#2 86.49(5) |
4. Conclusions
Supplementary Materials
Acknowledgments
References
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Diao, K.-S.; Li, L.; Ding, Y.-Q.; Lei, F.-H. A 3-D Metal-Organic Framework Constructed with Manganese(ΙΙ), 4,4'-Oxybis(benzoic acid) and 2,2'-Biphenyl: Synthesis, Crystal Structure and Photoelectric Property Characterization. Molecules 2012, 17, 11103-11112. https://doi.org/10.3390/molecules170911103
Diao K-S, Li L, Ding Y-Q, Lei F-H. A 3-D Metal-Organic Framework Constructed with Manganese(ΙΙ), 4,4'-Oxybis(benzoic acid) and 2,2'-Biphenyl: Synthesis, Crystal Structure and Photoelectric Property Characterization. Molecules. 2012; 17(9):11103-11112. https://doi.org/10.3390/molecules170911103
Chicago/Turabian StyleDiao, Kai-Sheng, Long Li, Yu-Qiu Ding, and Fu-Hou Lei. 2012. "A 3-D Metal-Organic Framework Constructed with Manganese(ΙΙ), 4,4'-Oxybis(benzoic acid) and 2,2'-Biphenyl: Synthesis, Crystal Structure and Photoelectric Property Characterization" Molecules 17, no. 9: 11103-11112. https://doi.org/10.3390/molecules170911103