Anionic Water Cluster Polymers [(H2O)18(OH)2]n2n− Is Stabilized by Bis(2,2′-bipyridine) Cupric Chloride [Cu(bipy)2Cl]−
Abstract
:1. Introduction
2. Results
3. Discussion
4. Materials and Methods
5. Conclusions
Supplementary Materials
Acknowledgments
Author Contributions
Conflicts of Interest
References
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Sample Availability: Samples of the compound [CuCl(bipy)2]2[(OH)2(H2O)8]∙3H2O are available from the authors. |
Length | Angle | ||
---|---|---|---|
O1w–O2w | 2.740(1) | O2w…O1w…O1wA | 115.28 |
O1w–O7w | 2.948(1) | O2w…O1w…O7w | 130.28 |
O1w–C(11) a | 3.372(1) | O1wA…O1w…O7w | 113.35 |
O1w–C(12) a | 3.361(1) | O1w…O2w…O3w | 113.25 |
C(1)–O3w a | 3.348(1) | O1w…O2w…O6wB | 119.13 |
C(1)–O2w a | 3.386(1) | O3w…O2w…O6wB | 125.39 |
Cl(2)–O5w a | 3.454(1) | O3wA…O3w…O6wC | 111.78 |
C(12)–O2w a | 3.396(2) | O3wA…O3w…O2w | 111.75 |
C(18)–O7w b | 3.264(1) | O6w…O3w…O2w | 114.28 |
O2w–O3w | 2.934 | O6wD…O4w…O6wE | 78.77 |
O2w–C(2) a | 3.386(1) | O6wD…O4w…O7w | 166.87 |
O3w–O6w c | 2.625(1) | O6wE…O4w…O7wA | 166.87 |
O5w-O6w b | 3.176 | O6wE…O4w…O7w | 90.53 |
Ring (i) → Ring (j)/C | Distance between the (i,j) Ring Centroids (Å) | Dihedral Angle (i,j) (Deg) | Distance of Centroid (i) from Ring (j) (Å) |
---|---|---|---|
R1 → R5 i | 3.813 | 2.55 | 3.268 |
R1 → R6 ii | 4.254 | 56.05 | 0.567 |
R1 → R7 iii | 4.287 | 28.65 | 4.175 |
R2 → R5 iv | 3.813 | 2.55 | 3.268 |
R2 → R6 iii | 4.254 | 56.05 | 0.567 |
R2 → R7 ii | 4.287 | 28.65 | 4.175 |
R3 → R6 iii | 4.016 | 28.02 | 3.982 |
R4 → R6 ii | 4.016 | 28.02 | 3.982 |
R5 → R6 i | 3.730 | 1.96 | 3.266 |
R7 → R5 iii | 4.088 | 26.36 | 3.597 |
R7 → R8 i | 3.783 | 0.43 | 3.431 |
C4 → R1 i | 3.251 | 3.334 | |
C4 → R2 v | 3.251 | 3.334 |
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Liu, E.; Jian, F. Anionic Water Cluster Polymers [(H2O)18(OH)2]n2n− Is Stabilized by Bis(2,2′-bipyridine) Cupric Chloride [Cu(bipy)2Cl]−. Molecules 2018, 23, 195. https://doi.org/10.3390/molecules23010195
Liu E, Jian F. Anionic Water Cluster Polymers [(H2O)18(OH)2]n2n− Is Stabilized by Bis(2,2′-bipyridine) Cupric Chloride [Cu(bipy)2Cl]−. Molecules. 2018; 23(1):195. https://doi.org/10.3390/molecules23010195
Chicago/Turabian StyleLiu, E, and Fangfang Jian. 2018. "Anionic Water Cluster Polymers [(H2O)18(OH)2]n2n− Is Stabilized by Bis(2,2′-bipyridine) Cupric Chloride [Cu(bipy)2Cl]−" Molecules 23, no. 1: 195. https://doi.org/10.3390/molecules23010195