Synthesis of Nano-Praseodymium Oxide for Cataluminescence Sensing of Acetophenone in Exhaled Breath
Abstract
:1. Introduction
2. Results and Discussion
2.1. Characterization
2.2. Selectivity of the CTL Sensor Based on Nano-Pr6O11
2.3. Optimization of Working Temperature
2.4. Optimization of Air Flow Rate
2.5. Optimization of Detecting Wavelength
2.6. CTL Response Profile and Analytical Characteristics
2.7. Sample Analysis
3. Experimental Section
3.1. Materials and Instrumentation
3.2. Synthesis of Praseodymium Oxide Nanoparticles
3.3. Procedure for Sensing
4. Conclusions
Author Contributions
Funding
Conflicts of Interest
References
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Principle | Sensing Materials | Linear Range (ppm) | LOD (ppm) | References |
---|---|---|---|---|
CTL | Nano-Pr6O11 | 2.8–50 | 0.7 | Present work |
Electrochemistry | 1-Octyl, 3-methylimidazolium tetrafluoroborate | 5–80 | 2.0 | [47] |
Quartz microbalance | Macrocyclic oligolactams | 5–40 | 2.0 | [48] |
Sample No. | Spiked Concentration (mg/m3) | Measured Concentration (mg/m3) | Recovery (%) | RSD (%) |
---|---|---|---|---|
1 | 20.0 | 21.9 ± 0.9 | 109.5 | 4.0 |
2 | 25.0 | 26.7 ± 0.9 | 106.7 | 3.2 |
3 | 30.0 | 33.9 ± 1.3 | 113.1 | 3.8 |
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Zhang, Q.-C.; Yan, W.-L.; Jiang, L.; Zheng, Y.-G.; Wang, J.-X.; Zhang, R.-K. Synthesis of Nano-Praseodymium Oxide for Cataluminescence Sensing of Acetophenone in Exhaled Breath. Molecules 2019, 24, 4275. https://doi.org/10.3390/molecules24234275
Zhang Q-C, Yan W-L, Jiang L, Zheng Y-G, Wang J-X, Zhang R-K. Synthesis of Nano-Praseodymium Oxide for Cataluminescence Sensing of Acetophenone in Exhaled Breath. Molecules. 2019; 24(23):4275. https://doi.org/10.3390/molecules24234275
Chicago/Turabian StyleZhang, Qian-Chun, Wu-Li Yan, Li Jiang, Yu-Guo Zheng, Jing-Xin Wang, and Run-Kun Zhang. 2019. "Synthesis of Nano-Praseodymium Oxide for Cataluminescence Sensing of Acetophenone in Exhaled Breath" Molecules 24, no. 23: 4275. https://doi.org/10.3390/molecules24234275