Wet-Chemically Prepared Porphyrin Layers on Rutile TiO2(110)
Abstract
:1. Introduction
2. Results and Discussion
2.1. Preparation of the TiO2(110) Crystals
2.2. Porphyrin Deposition
2.3. Porphyrin Metalation
3. Experimental Details
3.1. Wet-Chemically Prepared Crystals
3.2. Ultrahigh-Vacuum-Prepared Crystals
3.3. Chemicals
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
Sample Availability
References
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TiO2(110) | MCTPP + TiO2(110) | |||
---|---|---|---|---|
Before Cleaning | Wet-Chemically Cleaned | 1.3 ML MCTPP | 1.0 ML MCTPP | |
Wet-Chemically Prepared | UHV Prepared | |||
Ti | 16.04% | 24.72% | 14.16% | 17.05% |
O | 55.88% | 55.21% | 36.90% | 39.25% |
C | 23.85% | 19.66% | 44.64% | 37.89% |
N | 1.20% | 0.17% | 3.98% | 4.06% |
Zn | 0.12% | <0.03% | <0.05% | <0.02% |
Cu | 0.82% | <0.02% | <0.04% | <0.02% |
Ca | 0.58% | <0.01% | <0.20% | <0.40% |
S | 0.33% | <0.05% | <0.01% | <0.20% |
P | 0.57% | <0.06% | <0.01% | <0.30% |
Si | 0.61% | <0.08% | <0.01% | <0.80% |
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Wechsler, D.; Fernández, C.C.; Köbl, J.; Augustin, L.-M.; Stumm, C.; Jux, N.; Steinrück, H.-P.; Williams, F.J.; Lytken, O. Wet-Chemically Prepared Porphyrin Layers on Rutile TiO2(110). Molecules 2021, 26, 2871. https://doi.org/10.3390/molecules26102871
Wechsler D, Fernández CC, Köbl J, Augustin L-M, Stumm C, Jux N, Steinrück H-P, Williams FJ, Lytken O. Wet-Chemically Prepared Porphyrin Layers on Rutile TiO2(110). Molecules. 2021; 26(10):2871. https://doi.org/10.3390/molecules26102871
Chicago/Turabian StyleWechsler, Daniel, Cynthia Carolina Fernández, Julia Köbl, Lisa-Marie Augustin, Corinna Stumm, Norbert Jux, Hans-Peter Steinrück, Federico José Williams, and Ole Lytken. 2021. "Wet-Chemically Prepared Porphyrin Layers on Rutile TiO2(110)" Molecules 26, no. 10: 2871. https://doi.org/10.3390/molecules26102871
APA StyleWechsler, D., Fernández, C. C., Köbl, J., Augustin, L. -M., Stumm, C., Jux, N., Steinrück, H. -P., Williams, F. J., & Lytken, O. (2021). Wet-Chemically Prepared Porphyrin Layers on Rutile TiO2(110). Molecules, 26(10), 2871. https://doi.org/10.3390/molecules26102871