New Acridone- and (Thio)Xanthone-Derived 1,1-Donor–Acceptor-Substituted Alkenes: pH-Dependent Fluorescence and Unusual Photooxygenation Properties
Abstract
:1. Introduction
2. Results
2.1. Synthesis of Donor–Acceptor Alkenes
2.2. Fluorescence and UV–VIS Absorption Properties
2.3. Photooxygenation of the Geminal Acceptor–Donor Systems
3. Materials and Methods
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Compound | TFA | λabsmax (nm) | Absorption Coefficient ελ (L/mol·cm) | λex (nm) | λemmax (nm) | Quantum Yield ΦF |
---|---|---|---|---|---|---|
7 | − | 378 | 9370 | 360 | 398 | 0.008 |
+ | 366 | 11,580 | 366 | 511 | 0.310 | |
8 | − | 417 | 12,540 | 360 | 410/432 | 0.035 |
+ | 362 | 22,890 | 362 | 476/495 | 0.886 | |
10 | − | 329 | 13,520 | 329 | − | − |
+ | 329 | 12,040 | 329 | − | − |
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Lippold, T.; Neudörfl, J.M.; Griesbeck, A. New Acridone- and (Thio)Xanthone-Derived 1,1-Donor–Acceptor-Substituted Alkenes: pH-Dependent Fluorescence and Unusual Photooxygenation Properties. Molecules 2021, 26, 3305. https://doi.org/10.3390/molecules26113305
Lippold T, Neudörfl JM, Griesbeck A. New Acridone- and (Thio)Xanthone-Derived 1,1-Donor–Acceptor-Substituted Alkenes: pH-Dependent Fluorescence and Unusual Photooxygenation Properties. Molecules. 2021; 26(11):3305. https://doi.org/10.3390/molecules26113305
Chicago/Turabian StyleLippold, Tim, Jörg M. Neudörfl, and Axel Griesbeck. 2021. "New Acridone- and (Thio)Xanthone-Derived 1,1-Donor–Acceptor-Substituted Alkenes: pH-Dependent Fluorescence and Unusual Photooxygenation Properties" Molecules 26, no. 11: 3305. https://doi.org/10.3390/molecules26113305
APA StyleLippold, T., Neudörfl, J. M., & Griesbeck, A. (2021). New Acridone- and (Thio)Xanthone-Derived 1,1-Donor–Acceptor-Substituted Alkenes: pH-Dependent Fluorescence and Unusual Photooxygenation Properties. Molecules, 26(11), 3305. https://doi.org/10.3390/molecules26113305