2D Leaf-Like Structured ZIF-L Embedded Electrochemically Reduced Graphene Oxide Composite as an Electrochemical Sensing Platform for Sensitively Detecting Benomyl
Abstract
:1. Introduction
2. Results and Discussion
2.1. Structural Characterization
2.2. Electrochemical Characterization
2.3. Electrochemical Behavior of BM
2.4. Optimization of Analytical Parameters
2.4.1. Impact of the GO@ZIF-L Volume
2.4.2. Impact of Accumulation Time
2.4.3. Impact of Buffer Solution pH
2.5. Electrocatalytic Mechanism
2.6. Determination of BM
2.7. Repeatability, Reproducibility, Stability, and Anti-Interference
2.8. Real Sample Analysis
3. Materials and Methods
3.1. Materials and Reagents
3.2. Apparatuses
3.3. Preparation of GO@ZIF-L
3.4. Preparation of Modified Electrodes
3.5. Preparation of Practical Samples
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
Sample Availability
References
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Method | Detection Limit (nM) | Linear Range (μM) | Reference |
---|---|---|---|
Bare GCE | 82.66 | 0.27–5.17 | [42] |
OV-17 silicon a/CPE b | 237.66 | 0.34–13.77 | [43] |
NiFe2O4 c/MWCNTs/GCE | 24.8 | 0.09–9.98 | [8] |
Nano d-CuxO-MWCNTs-COOH /GCE | 3.0 | 0.01–10.00 | [9] |
ERGO@ZIF-L/GCE | 3.0 | 0.009–10.00 | This work |
Sample | Added (μM) | Found (μM) | Recovery (%) | RSD (%) |
---|---|---|---|---|
Tomato | 0.00 | 0.00 | - | - |
0.50 | 0.97 ± 0.01 | 97.00 | 1.57 | |
3.00 | 2.86 ± 0.22 | 95.33 | 3.78 | |
5.00 | 5.11 ± 0.64 | 104.8 | 2.76 | |
10.00 | 10.18 ± 0.43 | 103.6 | 4.34 |
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Shi, M.; Peng, G.; Xue, S.; Xu, J.; Gao, Y.; Liu, S.; Duan, X.; Lu, L. 2D Leaf-Like Structured ZIF-L Embedded Electrochemically Reduced Graphene Oxide Composite as an Electrochemical Sensing Platform for Sensitively Detecting Benomyl. Molecules 2022, 27, 6857. https://doi.org/10.3390/molecules27206857
Shi M, Peng G, Xue S, Xu J, Gao Y, Liu S, Duan X, Lu L. 2D Leaf-Like Structured ZIF-L Embedded Electrochemically Reduced Graphene Oxide Composite as an Electrochemical Sensing Platform for Sensitively Detecting Benomyl. Molecules. 2022; 27(20):6857. https://doi.org/10.3390/molecules27206857
Chicago/Turabian StyleShi, Min, Guanwei Peng, Shuya Xue, Jingkun Xu, Yansha Gao, Shuwu Liu, Xuemin Duan, and Limin Lu. 2022. "2D Leaf-Like Structured ZIF-L Embedded Electrochemically Reduced Graphene Oxide Composite as an Electrochemical Sensing Platform for Sensitively Detecting Benomyl" Molecules 27, no. 20: 6857. https://doi.org/10.3390/molecules27206857