Comparison of the Nucleation Kinetics Obtained from the Cumulative Distributions of the Metastable Zone Width and Induction Time Data
Abstract
:1. Introduction
2. Theoretical Derivations
3. Results and Discussions
4. Conclusions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
Sample Availability
Nomenclature
Notation | |
pre-exponential nucleation factor | |
cooling rate | |
initial concentration of solute molecules | |
equilibrium concentration of solute molecules | |
nucleation rate | |
Boltzmann constant | |
molar mass | |
Avogadro number | |
gas constant | |
supersaturation ratio, | |
temperature | |
initial saturated temperature for the initial saturated solute concentration | |
temperature at the MSZW limit at | |
time | |
induction time | |
time at the MSZW limit | |
solution volume | |
volume of the solute molecule | |
Greek letters | |
interfacial energy (J/m2) | |
crystal density (kg/m3) | |
MSZW (K). |
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INA | 2.96 | 3499 | 0.975 | 3.60 | 6600 |
BP | 0.86 | 4588 | 0.961 | 1.15 | 2752 |
DCD | 3.24 | 86 | 0.988 | 2.77 | 58 |
SA in ACN | 1.62 | 63 | 0.935 | 1.71 | 285 |
SA in EtAc | 2.26 | 140 | 0.866 | 2.03 | 144 |
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Shiau, L.-D. Comparison of the Nucleation Kinetics Obtained from the Cumulative Distributions of the Metastable Zone Width and Induction Time Data. Molecules 2022, 27, 3007. https://doi.org/10.3390/molecules27093007
Shiau L-D. Comparison of the Nucleation Kinetics Obtained from the Cumulative Distributions of the Metastable Zone Width and Induction Time Data. Molecules. 2022; 27(9):3007. https://doi.org/10.3390/molecules27093007
Chicago/Turabian StyleShiau, Lie-Ding. 2022. "Comparison of the Nucleation Kinetics Obtained from the Cumulative Distributions of the Metastable Zone Width and Induction Time Data" Molecules 27, no. 9: 3007. https://doi.org/10.3390/molecules27093007