Mechanism and Performance Analysis of Nanoparticle-Polymer Fluid for Enhanced Oil Recovery: A Review
Abstract
:1. Introduction
2. Polymer Flooding Mechanism and Influencing Factors
2.1. Common Polymers in Oil Displacement
2.2. Influence of Salinity
2.3. Influence of Temperature
2.4. PH
2.5. Self-Factors of Polymer
3. Nanoparticles Commonly Used in Oil Displacement
3.1. Nanoparticles of Metal Oxide
3.2. Non-Metallic Oxide Nanoparticles
4. Nanoparticle Reinforced Polymer
4.1. Quantum Size Effect and Chemical Bonding between Nanoparticles and Polymers
4.2. Improvement of Polymer Properties by Nanoparticles
4.2.1. Improvement of Viscosity
4.2.2. Stability of Shear Property
4.2.3. Thermal Stability and Salt Tolerance
4.3. Advantages of Nano Polymer Fluids
5. EOR Mechanism of Nanoparticle-Polymer Fluid
5.1. IFT
5.2. Wettability
5.3. Stability Analysis
6. Current Challenges
7. Future Prospects
8. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Nanoparticle and Concentration (wt%) | Polymer and Concentration (ppm) | Porous Media | IFT (mN/m) | Contact Angle (°) | Oil Recovery (%OOIP) | Ref. | |||
---|---|---|---|---|---|---|---|---|---|
P | With NPs | P | With NPs | P | NPF | ||||
SiO2 0.5 | HPAM 800 | Sandstone | - | - | - | - | 26.32 | 35.0 | [96] |
SiO2 0.1–0.5 | PAM 1000 | Glass micromodel | - | - | - | - | 50.6 | 61.8 | [72] |
SiO2 0.1–0.5 | PAM 2000 | Glass micromodel | - | - | - | - | 55.0 | 65.0 | [72] |
SiO2 0.1–0.5 | PAM 3000 | Glass micromodel | - | - | - | - | 58.0 | 68.0 | [72] |
SiO2 1.0 | PAM 1000 | Sandstone | 18.03 | 10.22 | - | - | 58.1 | 62.2 | [97] |
SiO2 0.1 | Xanthan gum 5000 | Sandstone | 17.8 | 10.75 | 72.7 | 22.8 | 14.5 | 16.3 | [6] |
SiO2 0.3 | Xanthan gum 5000 | Sandstone | 17.8 | 8.67 | 66.5 | - | - | - | [6] |
SiO2 0.5 | xanthan gum 5000 | Sandstone | 17.8 | 8.54 | 50.4 | 18.84 | 14.5 | 20.8 | [6] |
SiO2 0.1 | HPAM 2000 | Sandstone | 21.8 | 11.5 | 100.3 | 78.6 | 54.7 | 60.81 | [98] |
Al2O3 0.1 | HPAM 2000 | Sandstone | 21.8 | 9.3 | 100.3 | 60.6 | 54.7 | 65.3 | [98] |
Surface Modified Clay | HPAM 2000 | carbonate | - | - | - | - | 25.0 | 34.0 | [99] |
SiO2 0.2 | Guar gum 4000 | Sandstone | - | - | - | 115.0 | 23.02 | 35.97 | [100] |
Nanoparticle | Polymer | Preparation Method | Contact Angle (°) | IFT (mN/m) | Rock | Recovery Factor OOIP (%) | Ref. | ||
---|---|---|---|---|---|---|---|---|---|
Water | NPF | Water | NPF | ||||||
Bare silica nanoparticles | PDMAEMA homopolymer | Surface grafted | - | - | 39.5 | 19.0 | - | - | [119] |
SiO2 | DMAEMA polymer | Coated | 75.9 | 62.2 | 27.0 | 14.0 | Sandstone | 9.9 | [120] |
Fe3O4 | Anionic polymer | Coated | 160.0 | 114.0 | 11.23 | 7.92 | Carbonate rock | 16.2–17.1 | [4] |
SiO2/Al2O3 | Methacrylate | Coated | 143.3 | 48.75 | 10.3 | 6.5 | Sandstone | 6.0 | [121] |
Surface modified SiO2 (AANP) | Xanthan gum | Radical polymerization method | - | - | 31.5 | 25.1 | - | 18.5 | [122] |
TiO2 | Xanthan gum | Homogeneous miscible | 148.0 | 28.0 | 24.5 | 10.8 | Natural rock | 25.0 | [123] |
ZnO/SiO2 | Xanthan gum | Coated | 132.6 | 34.1 | 19.68 | 9.45 | Carbonate rock | 19.3 | [1] |
SiO2 | Guar gum | Homogeneous miscible | 115.0 | 73.0 | - | - | Sandstone | 44.28 | [100] |
Nano | Cellulose | Surface grafted | 101.8 | 56.8 | - | - | Carbonate rock | 6.0 | [124] |
Janus GO | Cellulose nanocrystals | Radical polymerization method | 166.0 | 37.0 | 20.2 | 14.4 | Edwards White | 22.96 | [125] |
CuO/TiO2 | PAM | - | 151.0 | 14.7 | 28.0 | 15.0 | Carbonate rock | - | [2] |
ZnO | PAM | Homogeneous miscible | 145.86 | 83.6 | 29.18 | 5.52 | Carbonate rock | 26.34 | [126] |
Aminated SiO2 (M-SiO2) | PAM | Radical polymerization method | - | - | - | - | - | 17.5 | [127] |
Surface modified SiO2 (C-SiO2) | PAM/PEI | Radical polymerization method | - | - | - | - | - | - | [128] |
Al2O3 | HPAM | Radical polymerization method | 111.8 | 25.1 | - | - | Sandstone | 37.6 | [5] |
SiO2 | HPAM | Radical polymerization method | 111.8 | 31.0 | - | - | Sandstone | 33.0 | [5] |
aminated SiO2 | HPAM | Homogeneous miscible | - | - | 24.0 | 14.0 | - | 17.3 | [116] |
Dispersible nano-SiO2 | HPAM | Homogeneous miscible | 141.8 | - | - | - | Quartz sand | 10.54 | [129] |
Aminated GO | HPAM | Radical polymerization method | - | - | - | - | - | - | [130] |
Bisfunctionalized GO | HPAM | Radical polymerization method | - | - | - | - | - | 21.5 | [131] |
Particle Wettability | Contact Angle Range (°) | Characteristics of Surface Unsaturated Bonds |
---|---|---|
Strong hydrophilic particles | 0 | Metal bond, ionic bond |
Weakly hydrophilic particles | 0–40 | Surface ionic bond or covalent bond |
Hydrophobic particle | 40–90 | Molecular bonds are dominant, and local regions are strong bonds |
Strongly hydrophobic particles | 90 | Intermolecular bonding force |
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Sun, Y.; Zhang, W.; Li, J.; Han, R.; Lu, C. Mechanism and Performance Analysis of Nanoparticle-Polymer Fluid for Enhanced Oil Recovery: A Review. Molecules 2023, 28, 4331. https://doi.org/10.3390/molecules28114331
Sun Y, Zhang W, Li J, Han R, Lu C. Mechanism and Performance Analysis of Nanoparticle-Polymer Fluid for Enhanced Oil Recovery: A Review. Molecules. 2023; 28(11):4331. https://doi.org/10.3390/molecules28114331
Chicago/Turabian StyleSun, Yuanxiu, Weijie Zhang, Jie Li, Ruifang Han, and Chenghui Lu. 2023. "Mechanism and Performance Analysis of Nanoparticle-Polymer Fluid for Enhanced Oil Recovery: A Review" Molecules 28, no. 11: 4331. https://doi.org/10.3390/molecules28114331