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Article

Theoretical Analysis of Superior Photodegradation of Methylene Blue by Cerium Oxide/Reduced Graphene Oxide vs. Graphene

by
Nguyen Hoang Hao
1,
Phung Thi Lan
2,
Nguyen Ngoc Ha
2,
Le Minh Cam
2,3 and
Nguyen Thi Thu Ha
2,*
1
College of Education, Vinh University, 182 Le Duan, Vinh 460000, Vietnam
2
Faculty of Chemistry, Hanoi National University of Education, 136 Xuan Thuy, Cau Giay, Hanoi 100000, Vietnam
3
Faculty of Pharmacy, Thanh Do University, QL32, Kim Chung, Hoai Duc, Hanoi 100000, Vietnam
*
Author to whom correspondence should be addressed.
Molecules 2024, 29(16), 3821; https://doi.org/10.3390/molecules29163821
Submission received: 14 July 2024 / Revised: 5 August 2024 / Accepted: 8 August 2024 / Published: 12 August 2024
(This article belongs to the Topic Advances in Computational Materials Sciences)
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Abstract

:
Density functional theory and a semi-empirical quantum chemical approach were used to evaluate the photocatalytic efficiency of ceria (CeO2) combined with reduced graphene oxide (rGO) and graphene (GP) for degrading methylene blue (MB). Two main aspects were examined: the adsorption ability of rGO and GP for MB, and the separation of photogenerated electrons and holes in CeO2/rGO and CeO2/GP. Our results, based on calculations of the adsorption energy, population analysis, bond strength index, and reduced density gradient, show favorable energetics for MB adsorption on both rGO and GP surfaces. The process is driven by weak, non-covalent interactions, with rGO showing better MB adsorption. A detailed analysis involving parameters like fractional occupation density, the centroid distance between molecular orbitals, and the Lewis acid index of the catalysts highlights the effective charge separation in CeO2/rGO compared to CeO2/GP. These findings are crucial for understanding photocatalytic degradation mechanisms of organic dyes and developing efficient photocatalysts.

Graphical Abstract

1. Introduction

Dye pollutants stand out as persistent and problematic contaminants in water bodies within the context of environmental issues [1]. Photocatalysis, which uses catalysts and light to degrade dyes into harmless compounds, offers a promising solution for sustainable dye treatment and has emerged as an effective method for addressing this problem [2].
Among the variety of photocatalytic materials, ceria (cerium oxide, CeO2) is considered one of the most promising for dye treatment due to its high efficiency, non-toxicity, photochemical stability, affordability, and its excellent ability to switch between Ce3+ and Ce4+ states, thereby enhancing catalytic efficiency in various reactions. However, ceria catalysts also exhibit limitations that hinder their practical applications. One significant drawback is their typically small specific surface area, which can limit photocatalytic efficiency. More critically, ceria suffers from a high rate of electron–hole recombination, a major challenge in photocatalysis, as this recombination reduces the number of charge carriers available for the photocatalytic reaction. A potential solution to this problem involves combining ceria with materials that have large specific surface areas and can rapidly conduct electrons, thereby reducing the recombination of photogenerated electrons and holes (e* and h+). Examples of such materials include reduced graphene oxide (rGO) and graphene (GP) [3,4,5]. The large surface area of GP and rGO provides ample active sites for the adsorption of dye molecules, thereby enhancing the efficiency of the photocatalytic process through increased catalyst–dye contact [6,7]. Furthermore, the excellent electron transport properties of graphene-based materials facilitate efficient electron transfer, leading to the generation of reactive oxygen species crucial for organic compound degradation under light irradiation [3,8].
It is noteworthy that the number of research projects on CeO2/rGO significantly exceeds those on CeO2/GP. Besides the fact that rGO is easier to synthesize than GP, structural differences—particularly the presence of oxygen-containing functional groups and distinct electronic properties between rGO and GP—may also account for the differences in their ability to adsorb organic dyes and the optical properties of rGO-based photocatalysts compared to GP-based photocatalysts [9,10]. The photocatalytic degradation of organic dyes is a complicated process comprising numerous stages, with the initial step involving the adsorption of dye molecules onto the surface of the photocatalyst. The photocatalytic efficiency of CeO2/rGO and CeO2/GP can be directly impacted by the dye adsorption capacity. The surface of rGO has demonstrated a greater affinity for adsorbing cationic dyes compared to anionic dyes [11]. In a study conducted by Mayara et al., utilizing a combination of multi-scale simulations and experiments, the authors demonstrated that the adsorption of methylene blue (MB) onto graphene oxide flakes is primarily of a physical nature and dependent on the functional groups on the surface [12]. In addition to the surface area and the presence of oxygen-containing functional groups, the existence of π-π and electrostatic interactions further enhances the adsorption capacity of rGO for cationic dyes like MB [13,14,15]. The adsorption capacity of MB on rGO has been documented to reach values in the range of 2000 mg/g [16], whereas the adsorption capacity of MB on GP typically amounts to approximately 200 mg/g [17], indicating the superior adsorption capacity of rGO over GP for MB.
In this study, we utilized computational chemistry methods to delve into the molecular-level reasons behind the superior photocatalytic performance of CeO2/rGO over CeO2/GP. Our focus was on two key aspects: (i) understanding how MB sticks to rGO and GP, shedding light on the forces driving the adsorption process; and (ii) elucidating the differences in electronic structure between CeO2/rGO and CeO2/GP. These findings aim to provide a clear and thorough comparison of the photocatalytic abilities of CeO2/rGO and CeO2/GP.

2. Results and Discussions

2.1. Adsorption Behavior of Graphene and Reduced Graphene Oxide toward Methylene Blue

A graphene model is constructed as a flat carbon layer containing 214 atoms, where the boundary carbon atoms are saturated with hydrogen atoms, corresponding to the formula C214H40 (Figure 1a). The mass fraction of carbon in this model is 98.5%, consistent with experimental analyses of the chemical composition of GP [18,19]. It should be noted that, in reality, oxygen always constitutes a small proportion of the chemical composition of GP. However, for ideal modeling purposes, we employ a completely oxygen-free GP model.
The reduced graphene oxide (rGO) model was derived from the GP model by adding the epoxide functional groups, resulting in the general formula C214H40O15 (Figure 1b). The mass fractions of carbon, hydrogen, and oxygen were 90.2%, 1.40%, and 8.43%, respectively, aligning with experimental studies [19]. Although the functional groups on the surface of rGO can be quite diverse, previous studies have demonstrated that epoxides are unique among oxygen-containing functional groups in their ability to tune the band gap. In contrast, other oxygen-containing groups are less effective: hydroxyls do not alter the band gap, and carbonyl and carboxyl groups disrupt the hexagonal carbon-ring structure of rGO [20,21].
The adsorption of MB on GP and rGO was evaluated by calculating adsorption energy values (Eads) and conducting a detailed population analysis. This analysis encompassed charge transfer (q), Wiberg bond orders (BOs), molecular orbital interactions, and various other non-covalent interactions.
The adsorption energy is calculated using the following formula:
Eads = Eadsorbent+MB − Eadsorbent − EMB,
where Eadsorbent+MB is the energy of the MB adsorption configuration on the GP or rGO adsorbent, Eadsorbent is the energy of the adsorbent, and EMB is the energy of the MB molecule.
The optimized adsorption configurations of MB on GP and rGO are shown in Figure 2, and the calculated results are presented in Table 1.
The results demonstrate that the adsorption of MB on both GP and rGO is energetically favorable, as indicated by negative adsorption energy values. However, rGO exhibits a superior adsorption ability due to its significantly lower Eads. The optimal adsorption configuration of MB is a parallel orientation on the adsorbent surface, consistent with previous studies [22]. This alignment is influenced by π-π stacking interactions, which are critical in the adsorption of aromatic organic compounds on carbon materials [23,24]. Despite substantial charge transfer from the MB molecule to the adsorbent, the calculations indicate that the minimal distance from MB to the adsorbent surface and the Wiberg bond order do not suggest the formation of chemical bonds between MB and the surfaces of GP or rGO. For context, the covalent radii of carbon (C), hydrogen (H), and oxygen (O) are 0.76, 0.31, and 0.66 Å [25], respectively, while their van der Waals (vdW) radii are 1.7, 1.20, and 1.52 Å [26], respectively. Thus, the minimal distance from MB to GP or rGO is significantly larger than the sum of the covalent radii of the atoms but smaller than the sum of the vdW radii. This raises questions about the nature of the interaction force between MB and the adsorbent surfaces, given the relatively negative adsorption energy values. It is important to note that the calculated Eads differs from the experimental heat of adsorption determined from adsorption isotherms, as the calculations only consider the interaction between an MB molecule and the adsorbent surface. Due to the large size of the MB molecule and its nature as a cationic dye, the vdW and other weak interactions, as well as electrostatic interactions, are likely to play a significant role. Although the Wiberg bond order between MB and both GP and rGO is negligible, this value only accounts for covalent bonding, not other types of interactions. Therefore, we proceeded to calculate the intrinsic bond strength index (IBSI) [27] to quantify the strength of chemical bonds. The IBSI can also be used to compare the strength of weak interactions. The IBSI is expressed as
I B S I = ( 1 / d 2 ) ∫ δ g p a i r d r ( 1 / d H 2 2 ) ∫ δ g H 2 d r
where d is the distance between the two atoms for which the interaction is being studied. The integral in the numerator is equivalent to the atomic pair δg index defined between the two atoms. The denominator represents the reference system data, the d H 2 and the integral are the bond length and atomic pair δg index of H2 in its equilibrium structure, respectively.
The results obtained are intriguing. In the case of MB adsorption on GP, no significant IBSI value was observed between the MB atoms and the carbon atoms on the GP surface. Conversely, when adsorbed onto rGO, the hydrogen and nitrogen atoms of MB interacted with the oxygen atoms in the epoxide groups of rGO, yielding relatively high IBSI values (see Figure 3).
Reduced density gradient (RDG) analysis was conducted to elucidate the weak intermolecular interactions between MB and GP, as well as between MB and rGO. The resulting map, which shows the dependence of RDG on sign (λ2) ρ (where λ2 is the second largest eigenvalue of the Hessian matrix of electron density and ρ is the electron density), is presented in Figure 4 for both the MB/GP and MB/rGO systems. Figure 5 depicts the RDG isosurfaces of the adsorption configurations.
In the case of MB/GP, the RDG graph (Figure 4a) shows spikes in the range of sign (λ2) ρ values from −0.01 to 0.015 a.u, corresponding to vdW interactions between the MB molecule and the GP surface (colored in green in Figure 5a). Due to the flat structure of the GP surface, the vdW interactions and other weak interactions, such as π-π stacking, between MB and GP are more pronounced than on the curved surface of rGO. However, when interacting with rGO, in addition to vdW interactions similar to those with GP, there are also regions indicating hydrogen bond formation (colored in blue in Figure 5b). Additionally, the interaction between the N-H groups of MB and the oxygen atoms of rGO through hydrogen bonds or electrostatic interactions aligns well with the findings of Manash et al. [15]. Consequently, calculations of adsorption energy, along with structural parameter and population analysis, demonstrate that the adsorption of MB on rGO is more favorable than on GP.

2.2. Interaction between Graphene and Reduced Graphene Oxide with Ceria Cluster

The CeO2-GP and CeO2-rGO models were constructed by placing (CeO2)6 clusters on the surfaces of GP and rGO. The CeO2 cluster model was selected to simulate small-sized CeO2 nanoparticles dispersed on the surfaces of GP and rGO. Similar approaches using CeO2 clusters have been employed in studies of other surface catalytic reactions [28,29].
As previously indicated, rGO demonstrates a significantly superior MB adsorption ability compared to GP due to the presence of oxygen-containing functional groups. Consequently, utilizing rGO enhances the concentration of dyes on the surface of the catalytic system, thereby creating favorable conditions for subsequent conversions at the photocatalytic centers, including ceria or rGO/MB itself. Further, we estimate the interaction of GP and rGO with ceria clusters. Effective interaction between the components in the CeO2/GP or CeO2/rGO catalytic system is anticipated to enhance photocatalytic activity by promoting the efficient release of photogenerated electrons and holes.
First, we calculated the interaction energy (Eint) between the (CeO2)6 cluster and both GP and rGO. Eint is determined using the following formula:
Eint = Eadsorbent+cluster − Eadsorbent − Ecluster,
where Eadsorbent+cluster is the energy of (CeO2)6/GP or (CeO2)6/rGO, and Ecluster is the energy of the ceria cluster.
The optimized structures of CeO2/GP and CeO2/rGO are shown in Figure 6. The .xyz files of these optimized structures are presented in the Supplementary Materials. Calculation results show that the interaction between (CeO2)6 and GP has an Eint value of +108.48 kJ mol–1, while the interaction between this cluster and rGO releases 32.63 kJ mol–1 of energy. These findings indicate that the interaction between the ceria cluster and the GP surface is much less energetically favorable than the interaction between the cluster and rGO. The presence of oxygen-containing functional groups on the surface of rGO allows it to interact more favorably with metal-based catalysts. This result aligns well with previous experimental studies. In the work of Pandey et al. on novel three-phase polymer nanocomposites based on cerium oxide (CeO2) nanoparticles and graphene nanoplatelets (GNPs) incorporated in poly (vinylidene fluoride) (PVDF) [30], the authors pointed out that the addition of GNPs in the PVDF/CeO2 nanocomposites did not cause any notable change in the FTIR spectra, indicating weak or no interaction between CeO2 and GP.
On the other hand, the interaction between CeO2 and rGO is energetically favorable, as evidenced by the negative Eint value. In fact, CeO2/rGO material systems are widely studied in photocatalytic applications [31,32].
Due to the complexity of calculating the bandgap values for the studied materials, particularly because of the presence of an f-element (Ce), we instead evaluate the photocatalytic ability by examining the spatial distribution of HOMOs and LUMOs, as discussed in [33]. A greater spatial separation between HOMOs and LUMOs may correlate with a lower recombination rate of photogenerated electrons and holes. Figure 7 presents the frontier molecular orbitals, including the HOMO and LUMO, for the CeO2/GP (a) and CeO2/rGO (b) systems.
In the CeO2/GP system, both the ceria cluster and the carbon atoms of GP mainly contribute to the HOMO and LUMO. In contrast, in the CeO2/rGO system, the HOMO is primarily located on the ceria cluster, while the LUMO is mainly contributed by rGO. This distribution suggests that the HOMO-LUMO configuration of CeO2/rGO will be more favorable for reducing the recombination of photogenerated electrons and holes compared to CeO2/GP.
We further calculated the fractional occupation number weighted density (FOD) to quickly and robustly provide information on the localization of “hot” (strongly correlated and chemically active) electrons in catalytic systems. The FOD map of GP and rGO (Figure 8) reveals that in the absence of CeO2, the active electrons are concentrated on the carbon atoms on the surface of the material. In the CeO2/GP and CeO2/rGO systems, active electrons are also distributed on the ceria cluster, which is particularly noticeable in the case of CeO2/rGO. This finding is interesting when correlated with the HOMO and LUMO images of CeO2/rGO (Figure 7c,d). The active electrons are primarily located in the HOMO of the ceria cluster, which can be excited and transferred to the LUMO located on rGO, thereby reducing the recombination ability.
To facilitate a more detailed analysis of charge transfer during electron excitation, we calculated the centroid distance between the HOMO and the LUMO of the photocatalytic systems. The centroid distance (Dij) was determined as follows:
D i j = ( X i − X j ) 2 + ( Y i − Y j ) 2 + ( Z i − Z j ) 2
where X, Y, and Z are the coordinates of the centroid of the orbitals. The calculated results are presented in Table 2, along with parameters related to the electronic properties including absolute electronegativity (χ), the global electrophilicity index (GEI) of the photocatalytic systems, and the band gap of CeO2/GP and CeO2/rGO. Due to the complexities involved in calculating the UV-VIS spectra for large systems containing f-elements such as Ce, we have employed an alternative approach based on IP and EA values to evaluate the transport band gap of the studied system. According to this method, the transport band gap (Eg) is defined as Eg = IP − EA [34,35].
The computational results indicate that the calculated Eg values of CeO2/GP and CeO2/rGO are relatively close to each other and smaller than the experimental values. It is important to note that, due to the size limitations of the model, the calculated band gap values for the studied systems are intended to assess the trends in variation rather than provide absolute values. Experimental measurements reveal that the optical band gap values of CeO2/GP and CeO2/rGO are also relatively similar, approximately 2.7 eV [31,36]. Therefore, from the standpoint of light absorption capability, there is no significant difference between CeO2/GP and CeO2/rGO. Consequently, the variation in photocatalytic activity is likely primarily attributed to the recombination rates of photogenerated electrons and holes.
The Dij value of the material systems increases in the following order: (CeO2)6 < GP < CeO2/GP < rGO < CeO2/rGO. This indicates that combining ceria with GP and rGO can significantly reduce the recombination ability of photogenerated electrons and holes. Among the studied material systems, the CeO2/rGO system exhibits the best ability to separate e*–h+.
The incorporation of ceria into GP and rGO increases both the absolute electronegativity value and the global electrophilicity index (GEI) compared to the original materials. Notably, the GEI can be used as a measure of Lewis acidity [37,38]. Previous studies have highlighted a positive correlation between Lewis acidity, or the number of Lewis acid centers, and the photocatalytic decomposition activity of methylene blue and rhodamine B in photocatalysts [39,40]. Therefore, the increased GEI value of material systems due to the presence of ceria is favorable for the decomposition of methylene blue.

3. Computational Methods

All geometry calculations were performed using density functional theory (DFT) methods, as implemented in the CP2K code (https://www.cp2k.org/). The exchange-correlation potential was described using the generalized gradient approximation (GGA) with the Perdew–Burke–Ernzerhof (PBE) spin-polarized functional [41]. Wavefunctions were expanded using a double-zeta valence polarized (DZVP) basis set, supplemented by an auxiliary plane-wave basis with a cutoff energy of 250 Ry. Core electrons were modeled using norm-conserving pseudopotentials [42]. Brillouin zone integration was performed using a reciprocal space mesh that included only the Γ-point. Dudarev’s approach for DFT+U calculations was employed to describe the Ce 4f electrons [43]. It should be noted that the bandgap value of the bulk CeO2 varies from 2.94 to 3.42 eV [44]. However, this value varies significantly for the (CeO2)6 cluster model due to the influence of cluster structures and sizes. In this study, a U–J value of 16.0 eV was used, corresponding to the highest bandgap value simulated for the (CeO2)6 cluster, which is 1.99 eV. Additionally, van der Waals forces were included using DFT-D calculations based on the Grimme D3 method to accurately estimate interaction forces [45].
The electronic properties of the studied systems, specifically the vertical ionization energy (IP), vertical electron affinity (EA), and global electrophilicity index (GEI), were determined through single-point calculations utilizing the GFN1-xTB method [46,47]. Non-covalent interactions were analyzed using Multiwfn software v3.8 [48].

4. Conclusions

The superior photocatalytic efficacy of CeO2/rGO over CeO2/GP in the photodegradation of methylene blue has been demonstrated through the evaluation of MB adsorption on the rGO substrate relative to GP, alongside an examination of the electronic characteristics inherent to these catalytic systems. The calculated adsorption energy and population analysis reveal that the adsorption of MB onto both GP and rGO is energetically favorable, primarily driven by non-covalent interactions, including van der Waals forces, π-π stacking interactions, and electrostatic interactions. Notably, rGO exhibits a heightened MB adsorption capacity relative to GP, attributable to the formation of weak bonds such as hydrogen bonds with oxygen atoms on its surface. The calculated interaction energies indicate that the combination of ceria with GP lacks energetic favorability compared to rGO. Through a comprehensive assessment of frontier molecular orbitals, fractional occupation density, the centroid distance between molecular orbitals, and the Lewis acid index of the catalysts, it has been demonstrated that CeO2/rGO exhibits superior efficacy in the separation of photogenerated electrons and holes compared to CeO2/GP. These findings hold substantial implications for understanding the mechanisms governing the photocatalytic degradation of organic dyes, as well as for the development of novel effective photocatalysts.

Supplementary Materials

The following supporting information can be downloaded at: https://www.mdpi.com/article/10.3390/molecules29163821/s1. Coordinates of atoms for the optimized CeO2/rGO and CeO2/GP structures.

Author Contributions

Conceptualization, N.T.T.H.; Methodology, L.M.C. and N.T.T.H.; Formal analysis, N.H.H., N.N.H. and L.M.C.; Investigation, N.H.H., P.T.L., N.N.H. and L.M.C.; Data curation, P.T.L.; Writing—original draft, N.H.H. and N.T.T.H.; Writing—review & editing, N.T.T.H.; Funding acquisition, N.H.H. All authors have read and agreed to the published version of the manuscript.

Funding

This work is funded by the Ministry of Education and Training under grant no. B2022-TDV-06.

Institutional Review Board Statement

Not applicable.

Informed Consent Statement

Not applicable.

Data Availability Statement

The data that support the findings of this study are available from the corresponding author upon reasonable request.

Conflicts of Interest

The authors declare that they have no conflicts of interest.

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Molecules 29 03821 g001
Figure 1. Models of GP (a) and rGO (b); color codes: brown—C; ivory—H; red—O.
Figure 1. Models of GP (a) and rGO (b); color codes: brown—C; ivory—H; red—O.
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Molecules 29 03821 g002
Figure 2. Optimized adsorption configurations of MB on GP (a) and rGO (b); color codes: brown—C; ivory—H, yellow—Ce; red—O; green—Cl; gray—N; light yellow—S.
Figure 2. Optimized adsorption configurations of MB on GP (a) and rGO (b); color codes: brown—C; ivory—H, yellow—Ce; red—O; green—Cl; gray—N; light yellow—S.
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Molecules 29 03821 g003
Figure 3. IBSI values corresponding to the interatomic interactions between atoms of MB and atoms of rGO.
Figure 3. IBSI values corresponding to the interatomic interactions between atoms of MB and atoms of rGO.
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Molecules 29 03821 g004
Figure 4. Scatter graph of RDG for MB/GP (a) and MB/rGO (b) systems.
Figure 4. Scatter graph of RDG for MB/GP (a) and MB/rGO (b) systems.
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Molecules 29 03821 g005
Figure 5. RDG isosurfaces (isovalue = 0.8) of MB/GP (a) and MB/rGO (b) systems.
Figure 5. RDG isosurfaces (isovalue = 0.8) of MB/GP (a) and MB/rGO (b) systems.
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Molecules 29 03821 g006
Figure 6. Optimized structures of CeO2/GP (a) and CeO2/rGO (b).
Figure 6. Optimized structures of CeO2/GP (a) and CeO2/rGO (b).
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Molecules 29 03821 g007
Figure 7. Frontier molecular orbitals of CeO2/GP: HOMO (a) and LUMO (b); and CeO2/rGO: HOMO (c) and LUMO (d).
Figure 7. Frontier molecular orbitals of CeO2/GP: HOMO (a) and LUMO (b); and CeO2/rGO: HOMO (c) and LUMO (d).
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Molecules 29 03821 g008
Figure 8. The FOD maps of GP, rGO, CeO2/GP, and CeO2/rGO.
Figure 8. The FOD maps of GP, rGO, CeO2/GP, and CeO2/rGO.
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Table 1. Calculated results for the adsorption of MB on GP and rGO.
Table 1. Calculated results for the adsorption of MB on GP and rGO.
ParameterEads, kJ mol−1dmin, Åq(MB), auBO
MB/GP−102.722.640 (H–C)0.249<0.10
MB/rGO−405.781.996 (H···O)0.411<0.10
Note for Table 1: dmin is the minimal distance from the adsorbed MB molecule to the surface of the adsorbent.
Table 2. Electronic properties and Eg of (CeO2)6, GP, rGO CeO2/GP, and CeO2/rGO.
Table 2. Electronic properties and Eg of (CeO2)6, GP, rGO CeO2/GP, and CeO2/rGO.
SystemDij, Åχ, eVGEI, eVEg, eV
(CeO2)60.0235.37923.4417-
GP0.0295.09838.7913-
rGO8.1815.462210.0683-
CeO2/GP3.4728.765726.60791.4439
CeO2/rGO9.6667.621820.74401.4001
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Hao, N.H.; Lan, P.T.; Ha, N.N.; Cam, L.M.; Ha, N.T.T. Theoretical Analysis of Superior Photodegradation of Methylene Blue by Cerium Oxide/Reduced Graphene Oxide vs. Graphene. Molecules 2024, 29, 3821. https://doi.org/10.3390/molecules29163821

AMA Style

Hao NH, Lan PT, Ha NN, Cam LM, Ha NTT. Theoretical Analysis of Superior Photodegradation of Methylene Blue by Cerium Oxide/Reduced Graphene Oxide vs. Graphene. Molecules. 2024; 29(16):3821. https://doi.org/10.3390/molecules29163821

Chicago/Turabian Style

Hao, Nguyen Hoang, Phung Thi Lan, Nguyen Ngoc Ha, Le Minh Cam, and Nguyen Thi Thu Ha. 2024. "Theoretical Analysis of Superior Photodegradation of Methylene Blue by Cerium Oxide/Reduced Graphene Oxide vs. Graphene" Molecules 29, no. 16: 3821. https://doi.org/10.3390/molecules29163821

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