Synthesis of High-Purity Hydroxyapatite and Phosphoric Acid Derived from Moroccan Natural Phosphate Rocks by Minimizing Cation Content Using Dissolution–Precipitation Technique
Abstract
:1. Introduction
2. Results and Discussion
3. Materials and Methods
3.1. Hydroxyapatite Precipitation
3.2. Purification Process of Hydroxyaptite
3.3. Preparation of High-Quality PA and GP
3.4. Characterizations
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Compound | CaO | P2O5 | SiO2 | F | Al2O3 | MnO | MgO | Fe2O3 | Na2O | SO3 | TiO2 | Other * |
---|---|---|---|---|---|---|---|---|---|---|---|---|
Concentration (wt%) | 44.01 | 39.58 | 5.26 | 5.12 | 1.50 | 0.56 | 0.40 | 0.30 | 0.22 | 0.64 | 0.06 | 0.17 |
Elements | Ca | P | Al | Fe | Mg | Mn | Ti | Cd | Sn | Pb |
---|---|---|---|---|---|---|---|---|---|---|
c-Liq (mg/L) | 142.4 | 101 | 22.983 | 17.134 | 14.438 | 0.369 | 0.5133 | 0.1954 | 0.1 | 0.05 |
Solution | Elements (mg/L) | |||||||
---|---|---|---|---|---|---|---|---|
Sn | Pb | Cd | Mn | Ti | Mg | Al | Fe | |
c-Liq | 0.1 | 0.05 | 0.1954 | 0.369 | 0.3234 | 14.438 | 22.983 | 17.134 |
r-Liq | 0.053 | 0.0001 | 0.0209 | 0.1315 | 0.1311 | 5.416 | 7.399 | 7.962 |
r1-Liq | - | 0.0023 | 0.1151 | 0.09 | 4.771 | 6.138 | 6.513 | |
r3-Liq | - | - | - | 0.1012 | 0.007 | 4.642 | 5.294 | 5.013 |
Solution | Elements (mg/L) | ||||
---|---|---|---|---|---|
Mg | Al | Fe | Mn | Ti | |
r3-Liq | 4.242 | 5.894 | 5.013 | 0.1012 | 0.007 |
PA | 0.4647 | 0.3242 | 0.1897 | 0.0009 | - |
Compound | SO3 | CaO | Al2O3 | P2O5 | Fe2O3 | Other | LOI a |
---|---|---|---|---|---|---|---|
Concentration (wt.%) | 48.70 | 29.74 | 0.096 | 0.01602 | 0.09 | 0.129 | 21.23 |
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Benataya, K.; Lakrat, M.; Hammani, O.; Aaddouz, M.; Ait Yassine, Y.; Abuelizz, H.A.; Zarrouk, A.; Karrouchi, K.; Mejdoubi, E. Synthesis of High-Purity Hydroxyapatite and Phosphoric Acid Derived from Moroccan Natural Phosphate Rocks by Minimizing Cation Content Using Dissolution–Precipitation Technique. Molecules 2024, 29, 3854. https://doi.org/10.3390/molecules29163854
Benataya K, Lakrat M, Hammani O, Aaddouz M, Ait Yassine Y, Abuelizz HA, Zarrouk A, Karrouchi K, Mejdoubi E. Synthesis of High-Purity Hydroxyapatite and Phosphoric Acid Derived from Moroccan Natural Phosphate Rocks by Minimizing Cation Content Using Dissolution–Precipitation Technique. Molecules. 2024; 29(16):3854. https://doi.org/10.3390/molecules29163854
Chicago/Turabian StyleBenataya, Karim, Mohammed Lakrat, Othmane Hammani, Mohamed Aaddouz, Youssef Ait Yassine, Hatem A. Abuelizz, Abdelkader Zarrouk, Khalid Karrouchi, and Elmiloud Mejdoubi. 2024. "Synthesis of High-Purity Hydroxyapatite and Phosphoric Acid Derived from Moroccan Natural Phosphate Rocks by Minimizing Cation Content Using Dissolution–Precipitation Technique" Molecules 29, no. 16: 3854. https://doi.org/10.3390/molecules29163854