Polyurethane Nanocomposite Coatings Coupled with Titanium-Based Conversion Layers for Enhanced Anticorrosion, Icephobic Properties, and Surface Protection
Abstract
:1. Introduction
2. Results and Discussion
2.1. Surface Characterization
2.2. Ice Nucleation Temperature and Freezing Time Delay
2.3. Ice Adhesion
2.4. Performance of a Polyurethane Nanocomposite When Coupled with a Titanium-Based Conversion Coating
2.4.1. Anticorrosion Performance and Coating Adhesion
2.4.2. Weathering Resistance
3. Materials and Methods
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Sample Code | Contact Angle (°) | Contact Angle Hysteresis (°) | |
---|---|---|---|
FPU | 91 ± 1 | 75 ± 3 | |
FPU-SiO2 4% | 164 ± 3 | 3 ± 0.5 | |
FPU-SiO2 7% | 165 ± 2 | 9 ± 1 | |
FPU-SiO2 10% | 169 ± 3 | 25 ± 1 |
Coating | Average Roughness (nm) |
---|---|
PU | 28.2 ± 7.1 |
PU-SiO2 4% | 132.1 ± 9.5 |
PU-SiO2 7% | 201.3 ± 11.3 |
PU-SiO2 10% | 283.1 ± 8.1 |
Sample Code | |Z|@0.01 Hz (Ω·cm2) 1 Day | |Z|@0.01 Hz (Ω·cm2) 60 Days | |Z|@0.01 Hz (Ω·cm2) 90 Days |
---|---|---|---|
FPU-SiO2 4% | 1.7 × 1010 | 2.2 × 109 | 1.6 × 108 |
FPUSiO2 4%-CC | 3 × 1010 | 9 × 109 | 1.6 × 109 |
Sample Code | ΔL* | Δa* | Δb* | ΔE* |
---|---|---|---|---|
FPU | 0.74 | −1.00 | 3.05 | 3.3 |
FPU-SiO2 4% | −0.13 | −1.07 | 1.05 | 2.1 |
FPU-SiO2 4%-CC | −0.75 | −0.95 | 1.59 | 1.9 |
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Roshan, S.; Jafari, R.; Momen, G. Polyurethane Nanocomposite Coatings Coupled with Titanium-Based Conversion Layers for Enhanced Anticorrosion, Icephobic Properties, and Surface Protection. Molecules 2024, 29, 3901. https://doi.org/10.3390/molecules29163901
Roshan S, Jafari R, Momen G. Polyurethane Nanocomposite Coatings Coupled with Titanium-Based Conversion Layers for Enhanced Anticorrosion, Icephobic Properties, and Surface Protection. Molecules. 2024; 29(16):3901. https://doi.org/10.3390/molecules29163901
Chicago/Turabian StyleRoshan, Shamim, Reza Jafari, and Gelareh Momen. 2024. "Polyurethane Nanocomposite Coatings Coupled with Titanium-Based Conversion Layers for Enhanced Anticorrosion, Icephobic Properties, and Surface Protection" Molecules 29, no. 16: 3901. https://doi.org/10.3390/molecules29163901