The Effect of High Selenite and Selenate Concentrations on Ferric Oxyhydroxides Transformation under Alkaline Conditions
Abstract
:1. Introduction
2. Results and Discussion
2.1. Transformation of Iron Precipitates under Alkaline Conditions
2.2. Effect of Selenium Presence on Ferric Oxyhydroxides Transformation
2.3. Effect of the Selenium on Thermal Transformation of Goethite to Hematite
2.4. Selenite and Selenate Interaction with Ferric Iron Precipitates
3. Materials and Methods
3.1. Chemicals and Reagents
3.2. Solid Phase Preparation and Selenium Desorption
3.3. Analytical Procedures
3.4. Iron and Selenium Size Fractionation
4. Conclusions
Author Contributions
Funding
Conflicts of Interest
References
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Sample | 2nd Day of Precipitation | 5th Day of Precipitation | |||||
---|---|---|---|---|---|---|---|
Spectral Component | Dist | S1 | S2 | Dist | S1 | S2 | |
Parameter | |||||||
Selenium-free | Arel (%) | 51.7 | 29.4 | 18.9 | 47.6 | 30.9 | 21.5 |
Bhf (T) | 28.6 | 38.4 | 37.4 | 31.2 | 38.1 | 37.2 | |
δ (mm/s) | 0.35 | 0.37 | 0.24 | 0.35 | 0.37 | 0.24 | |
εΔ (mm/s) | −0.28 | −0.28 | −0.28 | −0.28 | −0.27 | −0.27 | |
Selenite-treated | Arel (%) | 60.0 | 22.2 | 17.8 | 51.5 | 27.6 | 20.9 |
Bhf (T) | 29.4 | 38.0 | 37.0 | 31.1 | 38.0 | 37.1 | |
δ (mm/s) | 0.35 | 0.37 | 0.24 | 0.35 | 0.37 | 0.24 | |
εΔ (mm/s) | −0.29 | −0.27 | −0.27 | −0.28 | −0.27 | −0.27 | |
Selenate-treated | Arel (%) | 56.2 | 27.2 | 16.6 | 47.5 | 31.9 | 20.6 |
Bhf (T) | 28.9 | 38.1 | 37.1 | 30.7 | 38.1 | 37.2 | |
δ (mm/s) | 0.35 | 0.37 | 0.24 | 0.35 | 0.37 | 0.24 | |
εΔ (mm/s) | −0.29 | −0.28 | −0.28 | −0.28 | −0.27 | −0.27 |
Sample | Thermal | Transformation | |||||
---|---|---|---|---|---|---|---|
Spectral Component | S1 | S2 | S3 | S4 | S5 | S6 | |
Parameter | |||||||
Selenium-free | Arel (%) | 31.3 | 27.3 | 12.1 | 5.4 | 18.4 | 5.5 |
Bhf (T) | 51.3 | 50.5 | 49.6 | 48.5 | 47.1 | 38.6 | |
δ (mm/s) | 0.38 | 0.39 | 0.37 | 0.37 | 0.32 | 0.36 | |
εΔ (mm/s) | −0.21 | −0.21 | −0.23 | −0.27 | −0.29 | −0.30 | |
Selenite-treated | Arel (%) | 36.3 | 27.0 | 11.6 | 5.6 | 19.5 | - |
Bhf (T) | 51.2 | 50.3 | 49.2 | 47.9 | 46.6 | - | |
δ (mm/s) | 0.38 | 0.38 | 0.38 | 0.35 | 0.31 | - | |
εΔ (mm/s) | −0.21 | −0.21 | −0.25 | −0.25 | −0.30 | - | |
Selenate-treated | Arel (%) | 31.5 | 28.8 | 12.7 | 6.0 | 16.4 | 4.6 |
Bhf (T) | 51.3 | 50.5 | 49.5 | 48.4 | 46.8 | 38.9 | |
δ (mm/s) | 0.38 | 0.39 | 0.37 | 0.36 | 0.32 | 0.34 | |
εΔ (mm/s) | −0.21 | −0.21 | −0.24 | −0.27 | −0.30 | −0.35 |
Sample | Element (Weight %) | 2nd Day of Precipitation | 5th Day of Precipitation | Thermal Transformation |
---|---|---|---|---|
Selenium-free | Fe | 26.8 ± 3.2 | 26.2 ± 2.3 | 33.2 ± 1.3 * |
Selenite-treated | Fe | 25.7 ± 1.9 | 25.2 ± 1.9 | 25.5 ± 2.5 |
Se | 2.3 ± 0.9 | 1.5 ± 0.1 | 0.93 ± 0.08 ** | |
Selenate-treated | Fe | 25.4 ± 2.5 | 26.1 ± 0.37 | 36.01 ± 2.04 * |
Se | 2.5 ± 1.0 | 1.1 ± 0.20 | 0.95 ± 0.1 |
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Matulová, M.; Bujdoš, M.; Miglierini, M.B.; Cesnek, M.; Duborská, E.; Mosnáčková, K.; Vojtková, H.; Kmječ, T.; Dekan, J.; Matúš, P.; et al. The Effect of High Selenite and Selenate Concentrations on Ferric Oxyhydroxides Transformation under Alkaline Conditions. Int. J. Mol. Sci. 2021, 22, 9955. https://doi.org/10.3390/ijms22189955
Matulová M, Bujdoš M, Miglierini MB, Cesnek M, Duborská E, Mosnáčková K, Vojtková H, Kmječ T, Dekan J, Matúš P, et al. The Effect of High Selenite and Selenate Concentrations on Ferric Oxyhydroxides Transformation under Alkaline Conditions. International Journal of Molecular Sciences. 2021; 22(18):9955. https://doi.org/10.3390/ijms22189955
Chicago/Turabian StyleMatulová, Michaela, Marek Bujdoš, Marcel B. Miglierini, Martin Cesnek, Eva Duborská, Katarína Mosnáčková, Hana Vojtková, Tomáš Kmječ, Július Dekan, Peter Matúš, and et al. 2021. "The Effect of High Selenite and Selenate Concentrations on Ferric Oxyhydroxides Transformation under Alkaline Conditions" International Journal of Molecular Sciences 22, no. 18: 9955. https://doi.org/10.3390/ijms22189955