Phosphate Additives for Aging Inhibition of Impregnated Activated Carbon against Hazardous Gases
Abstract
:1. Introduction
2. Results and Discussion
2.1. CK Adsorption on IAC
2.1.1. Pre-Humidified IAC
2.1.2. Effect of Phosphate Additive (NaH2PO4·H2O) on IAC Aging
2.1.3. Effect of Phosphate Concentration (NaH2PO4·H2O) on IAC Aging
2.1.4. Effect of Phosphate Type on LIAC Aging
2.2. The Effect of Phosphate on the Physical Adsorption of Toluene
2.3. Effect of a Phosphate Additive on the Textural Properties of IACs
2.4. Effect of a Phosphate Additive on Impregnated Metal Migration to the External Carbon Surface
3. Materials and Methods
3.1. Chemicals
3.2. Impregnated Activated Carbon Preparation
3.3. Addition of Phosphate Additives
3.4. Preparation of Activated Carbon Beds
3.5. IAC Pretreatments
3.5.1. Humidification of the Carbon Beds
3.5.2. Accelerated Aging
3.5.3. Carbon Bed Drying
3.6. CK Dynamic Adsorption
3.7. Toluene Dynamic Adsorption
3.8. Carbon Characterization
- I.
- Changes in the surface elemental composition of the carbon adsorbents were analyzed using energy-dispersive X-ray spectrometry (EDX) using a PhenomProX scanning electron microscope (SEM) produced by Thermo Fisher Scientific. All data were recorded using a 15 keV electron acceleration voltage. Since the metal distribution on the external surface of the carbon is heterogeneous even for a given granule, the elemental concentration was determined as the average of 10 different areas on different granules. The analyzed area in each measurement was 316 μm × 316 μm (magnification of 850×).
- II.
- The Brunauer‒Emmett‒Teller (BET) surface area and pore volume were obtained from N2 adsorption–desorption isotherms at 77 K using a NOVA 1200 e (Quantachrome) system. Before analysis, the samples were outgassed under vacuum at 80 °C. The micropore surface area was derived from a t-plot analysis of the adsorption isotherm. The outgassing was performed at a temperature of 80 °C because, at higher temperatures, a significant sublimation of TEDA from the IAC may occur. Furthermore, the sublimation rate of the TEDA from the IAC at high temperatures may vary for the different types of IACs.
4. Conclusions
Author Contributions
Funding
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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ASZMT without Phosphate | ASZMT with 6.54 wt.% NaH2PO4·H2O | LIAC without Phosphate | LIAC with 5.15 wt.% NaH2PO4·H2O |
---|---|---|---|
347 | 394 | 331 | 356 |
ASZMT without Phosphate | ASZMT with 6.54 wt.% NaH2PO4·H2O | LIAC without Phosphate | LIAC with 5.15 wt.% NaH2PO4·H2O | |
---|---|---|---|---|
Surface area (m2/g) (BET) | 687 | 699 | 734 | 696 |
% microporosity | 80.1 | 84.0 | 81.1 | 81.1 |
Micropore volume (cm3/g) | 0.295 | 0.305 | 0.298 | 0.288 |
IAC Type | Cu | Zn | Mo |
---|---|---|---|
ASZMT–new | 8.4 | 23.8 | 3.7 |
ASZMT–aged 3 M | 23.4 | 37.5 | 4.2 |
ASZMT–aged 6 M | 23.2 | 40.7 | 2.9 |
ASZMT with 6.54 wt.% NaH2PO4·H2O–new | 6.3 | 13.1 | 2.8 |
ASZMT with 6.54% NaH2PO4·H2O–aged 3 M | 8.9 | 15.6 | 3.0 |
ASZMT with 6.54% NaH2PO4·H2O–aged 6 M | 8.8 | 17.5 | 2.6 |
LIAC–new | 8.9 | 28.5 | 2.5 |
LIAC–aged 3 M | 20.8 | 30.9 | 5.2 |
LIAC–aged 6 M | 19.6 | 26.5 | 5.1 |
LIAC with 5.15 wt.% NaH2PO4·H2O–new | 13.3 | 23.5 | 1.7 |
LIAC with 5.15% NaH2PO4·H2O–aged 3 M | 21.8 | 22.3 | 2.6 |
LIAC with 5.15% NaH2PO4·H2O–aged 6 M | 25.3 | 28.5 | 2.1 |
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Nir, I.; Shepelev, V.; Pevzner, A.; Marciano, D.; Rosh, L.; Amitay-Rosen, T.; Rotter, H. Phosphate Additives for Aging Inhibition of Impregnated Activated Carbon against Hazardous Gases. Int. J. Mol. Sci. 2023, 24, 13000. https://doi.org/10.3390/ijms241613000
Nir I, Shepelev V, Pevzner A, Marciano D, Rosh L, Amitay-Rosen T, Rotter H. Phosphate Additives for Aging Inhibition of Impregnated Activated Carbon against Hazardous Gases. International Journal of Molecular Sciences. 2023; 24(16):13000. https://doi.org/10.3390/ijms241613000
Chicago/Turabian StyleNir, Ido, Vladislav Shepelev, Alexander Pevzner, Daniele Marciano, Lilach Rosh, Tal Amitay-Rosen, and Hadar Rotter. 2023. "Phosphate Additives for Aging Inhibition of Impregnated Activated Carbon against Hazardous Gases" International Journal of Molecular Sciences 24, no. 16: 13000. https://doi.org/10.3390/ijms241613000