Corrosion Rate and Mechanism of Degradation of Chitosan/TiO2 Coatings Deposited on MgZnCa Alloy in Hank’s Solution
Abstract
:1. Introduction
2. Results and Discussion
2.1. Structure of the Substrate and the Chitosan/TiO2 Coating
2.2. Corrosion Resistance of Uncoated and Coated Mg19Zn1Ca Alloys
2.3. The Influence of the Chitosan/TiO2 Coating on Corrosion Mechanisms
2.4. Corrosion Rate of Uncoated and Coated Mg19Zn1Ca Alloy
2.5. Corrosion Degradation of Uncoated and Coated Mg19Zn1Ca Alloy
3. Materials and Methods
3.1. Materials
3.2. Coatings Preparation
3.3. Corrosion Measurements
3.4. Characterisation Techniques
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Rs (Ω·cm2) | Rct (Ω·cm2) | Y (S·cm−2·sn) | n | RL (Ω·cm2) | L (H·cm2) | |
---|---|---|---|---|---|---|
2 h | 66.0 ± 0.4 | 191.9 ± 1.8 | 2.4 × 10−4 ± 4 × 10−6 | 0.84 ± 0.009 | 436.5 ± 21 | 1117.0 ± 87 |
7 h | 68.0 ± 0.67 | 239.6 ± 2.5 | 2.9 × 10−4 ± 1.3 × 10−5 | 0.84 ± 0.003 | 489.5 ± 27.0 | 2229.0 ± 127.0 |
Rs (Ω·cm2) | Rct (Ω·cm2) | Y1 (S·cm−2·sn) | n1 | Y2 (S·cm−2·sn) | n2 | GE-T (S·cm−2·s0.5) | GE-P | |
---|---|---|---|---|---|---|---|---|
2 h | 13.2 ± 2.0 | 585.9 ± 4.9 | 2.6 × 10−5 ± 2.2 × 10−7 | 0.9 ± 0.005 | 0.029 ± 4.4 × 10−4 | 0.42 ± 0.017 | 2.1 × 10−4 ± 1.2 × 10−5 | 2938 ± 946 |
7 h | 33 ± 0.8 | 991.2 ± 7.3 | 3.4 × 10−5 ± 3.8 × 10−7 | 0.82 ± 0.006 | 5.8 × 10−5 ± 2.2 × 10−7 | 0.49 ± 0.02 | 5.8 × 10−5 ± 3.0 × 10−6 | 27,652 ± 449 |
Step | Time, s | Speed, rps |
---|---|---|
S1 | 5 | 250 |
S3 | 30 | 1000 |
S3 | 60 | 1500 |
drying | 60 | 250 |
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Krawiec, H.; Kozina, I.; Starowicz, M.; Lekka, M.; Zanella, C.; Fedrizzi, L.; Fedel, M.; Deflorian, F. Corrosion Rate and Mechanism of Degradation of Chitosan/TiO2 Coatings Deposited on MgZnCa Alloy in Hank’s Solution. Int. J. Mol. Sci. 2024, 25, 5313. https://doi.org/10.3390/ijms25105313
Krawiec H, Kozina I, Starowicz M, Lekka M, Zanella C, Fedrizzi L, Fedel M, Deflorian F. Corrosion Rate and Mechanism of Degradation of Chitosan/TiO2 Coatings Deposited on MgZnCa Alloy in Hank’s Solution. International Journal of Molecular Sciences. 2024; 25(10):5313. https://doi.org/10.3390/ijms25105313
Chicago/Turabian StyleKrawiec, Halina, Iryna Kozina, Maria Starowicz, Maria Lekka, Caterina Zanella, Lorenzo Fedrizzi, Michele Fedel, and Flavio Deflorian. 2024. "Corrosion Rate and Mechanism of Degradation of Chitosan/TiO2 Coatings Deposited on MgZnCa Alloy in Hank’s Solution" International Journal of Molecular Sciences 25, no. 10: 5313. https://doi.org/10.3390/ijms25105313