Robust Photocatalytic MICROSCAFS® with Interconnected Macropores for Sustainable Solar-Driven Water Purification
Abstract
:1. Introduction
2. Results and Discussion
2.1. Characterization of the MICROSCAFS® before and after Heat Treatment and Photocatalyst (P25 TiO2 NPs) Loading
2.2. Photocatalytic Studies on the P25 TiO2 NPs-Loaded MICROSCAFS®
2.3. Kinetics Studies
2.4. Study of the By-Products from Photocatalytic MO Degradation
2.5. Scavenger’s Study on the Photocatalytic MICROSCAFS® and Photocatalysis Mechanistic Study
3. Materials and Methods
3.1. Materials
3.2. Synthesis of the MICROSCAFS®
3.3. Preparation of the Photocatalytic MICROSCAFS®
3.4. Characterization
3.5. Photocatalytic Tests
3.6. Kinetics Modeling of the Photocatalytic Performance
3.7. Analytical Methods for Photocatalysis By-Products Determination
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Sample Acronym | Average Kinetic Rate Constant k (mL min−1 mg−1) | Average Apparent Flow Reaction Rate Constant kapp (mL min−1 mg−1) |
---|---|---|
P−/HT/P25 | (3.47 ± 0.1) × 10−2 | (2.28 ± 0.3) × 10−3 |
P0/HT/P25 | (4.40 ± 0.3) × 10−2 | (3.01 ± 0.5) × 10−3 |
P+/HT/P25 | (6.45 ± 0.08) × 10−2 | (4.19 ± 0.7) × 10−3 |
S−/HT/P25 | (4.99 ± 0.7) × 10−2 | n. a. |
Compound | Structure | tR (min) | Proposed Empirical Formula | [M−H]− [m/z (∆ppm) mSigma] |
---|---|---|---|---|
MO | 9.5 | C14H15N3O3S | [304.0770 (−2.9; 6.5)] | |
TP320-a | 10.9 | C14H15N3O4S | [320.0722 (−3.7; 9.2)] | |
TP306 | 9.0 | C13H13N3O4S | [306.0562 (−2.7;12.5)] | |
TP290 | 7.8 | C13H13N3O3S | [290.0614 (−3.2; 10.5)] | |
TP276 | 5.8 | C12H11N3O3S | [276.0453 (−3.2; 21.6)] | |
TP320-b | 3.9 | C14H15N3O4S | [320.0712 (−0.2; 9.7)] |
Compound | Acute Toxicity | Chronic Toxicity | ||||
---|---|---|---|---|---|---|
(mg/L) | (mg/L) | |||||
Fish (LC50) | Daphnid (LC50) | Green Algae (EC50) | Fish (ChV) | Daphnid (ChV) | Green Algae (ChV) | |
MO | 1513.99 | 793.35 | 424.07 | 134.62 | 61.88 | 92.88 |
TP320-a | 173.97 | 39.22 | 192.16 | 15.97 | 7.47 | 91.02 |
TP320-b | 592.29 | 97.78 | 512.74 | 49.07 | 18.64 | 245.03 |
TP306 | 433.60 | 76.62 | 395.85 | 36.73 | 14.60 | 188.80 |
TP290 | 4479.49 | 2231.63 | 967.94 | 375.25 | 151.23 | 189.43 |
TP276 | 922.37 | 2.07 | 9.26 | 5.36 | 0.13 | 13.94 |
Harmless LC50/EC50/ChV > 100 | Harmful 100 > LC50/EC50/ChV > 10 | Toxic 10 > LC50/EC50/ChV > 1 | Very toxic LC50/EC50/ChV < 1 |
Sample Acronym | Volume of GPTMS (mL) | Volume of Span® 80 (mL) | Mass of Pluronic® P123 (g) |
---|---|---|---|
P− | 10.4 | 6.0 | 0 |
P0 (reference) | 13.8 | 6.0 | 0 |
P+ | 17.3 | 6.0 | 0 |
S− | 13.8 | 7.7 | 2.3 |
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Vale, M.; Barrocas, B.T.; Serôdio, R.M.N.; Oliveira, M.C.; Lopes, J.M.; Marques, A.C. Robust Photocatalytic MICROSCAFS® with Interconnected Macropores for Sustainable Solar-Driven Water Purification. Int. J. Mol. Sci. 2024, 25, 5958. https://doi.org/10.3390/ijms25115958
Vale M, Barrocas BT, Serôdio RMN, Oliveira MC, Lopes JM, Marques AC. Robust Photocatalytic MICROSCAFS® with Interconnected Macropores for Sustainable Solar-Driven Water Purification. International Journal of Molecular Sciences. 2024; 25(11):5958. https://doi.org/10.3390/ijms25115958
Chicago/Turabian StyleVale, Mário, Beatriz T. Barrocas, Rita M. N. Serôdio, M. Conceição Oliveira, José M. Lopes, and Ana C. Marques. 2024. "Robust Photocatalytic MICROSCAFS® with Interconnected Macropores for Sustainable Solar-Driven Water Purification" International Journal of Molecular Sciences 25, no. 11: 5958. https://doi.org/10.3390/ijms25115958