Catena-[Triaquabis(μ2-1,4-bis(diphenylphosphoryl)butane)nitrato-κ2O-praseodymium(III)] Nitrate Monohydrate Methanol Solvate
Abstract
:1. Introduction
2. Results
3. Discussion
4. Materials and Methods
4.1. Synthesis of Bis(diphenylphosphoryl)butane (dppbO2)
4.2. Synthesis of Catena-[{Pr(NO3)(H2O)3-μ-dppbO2}2-μ-dppbO2](NO3)4·(dppbO2)·2MeOH·2H2O
5. Conclusions
Supplementary Materials
Author Contributions
Funding
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Pr1–O1 | 2.358(5) | P1–O1 | 1.504(5) |
Pr1–O2 | 2.358(5) | P2–O2 | 1.503(5) |
Pr1–O3 | 2.389(3) | P3–O3 | 1.496(4) |
Pr1–O5 | 2.492(3) | P4–O4 | 1.497(4) |
Pr1–O6 | 2.499(4) | N1–O11 | 1.265(7) |
Pr1–O7 | 2.482(4) | N1–O12 | 1.269(7) |
Pr1–O11 | 2.597(4) | O4⋯H5b | 1.75(3) |
Pr1–O12 | 2.588(4) | O4⋯H6b | 1.82(4) |
O4⋯O5 | 2.688(5) | O4⋯O6 | 2.733(5) |
O4⋯H6b | 1.82(4) | O4⋯H5b | 1.75(3) |
O1–Pr1–O2 | 165.5(1) | O5–Pr1–O6 | 68.6(1) |
O1–Pr–O3 | 89.7(1) | O6–Pr1–O7 | 70.6(1) |
O2–Pr1–O3 | 95.7(1) | ||
C29–C30–C30–C29 | 180.0(5) | C1–C2–C3–C4 | 71.1(6) |
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Fern, E.S.M.; Lunt, M.I.; Minch, G.D.; Roeterdink, J.; Scheu Rodriguez, A.P.; Smith, C.A.; Venters, J.J.; McKay, A.P.; Cordes, D.B.; Chalmers, B.A. Catena-[Triaquabis(μ2-1,4-bis(diphenylphosphoryl)butane)nitrato-κ2O-praseodymium(III)] Nitrate Monohydrate Methanol Solvate. Molbank 2024, 2024, M1861. https://doi.org/10.3390/M1861
Fern ESM, Lunt MI, Minch GD, Roeterdink J, Scheu Rodriguez AP, Smith CA, Venters JJ, McKay AP, Cordes DB, Chalmers BA. Catena-[Triaquabis(μ2-1,4-bis(diphenylphosphoryl)butane)nitrato-κ2O-praseodymium(III)] Nitrate Monohydrate Methanol Solvate. Molbank. 2024; 2024(3):M1861. https://doi.org/10.3390/M1861
Chicago/Turabian StyleFern, Eilidh S. M., Maia I. Lunt, Guy D. Minch, Julia Roeterdink, Ana P. Scheu Rodriguez, Charlotte A. Smith, Johnathan J. Venters, Aidan P. McKay, David B. Cordes, and Brian A. Chalmers. 2024. "Catena-[Triaquabis(μ2-1,4-bis(diphenylphosphoryl)butane)nitrato-κ2O-praseodymium(III)] Nitrate Monohydrate Methanol Solvate" Molbank 2024, no. 3: M1861. https://doi.org/10.3390/M1861