Adsorption Thermodynamics and Dynamics of Three Typical Dyes onto Bio-adsorbent Spent Substrate of Pleurotus eryngii
Abstract
:1. Introduction
2. Materials and Methods
2.1. Preparation of Bio-Adsorbent
2.2. Preparation of Dye Solution
2.3. Batch Bio-Adsorption Procedure
2.4. Determination of Concentration of Dyes
2.5. Removal Efficiency by Adsorption and Equilibrium Adsorption Quantity
2.6. Assays by Fourier Transform Infrared Spectroscopy (FTIR)
2.7. Adsorption Thermodynamics and Dynamics Model
2.7.1. Adsorption Isotherm Model
2.7.2. Adsorption Thermodynamics
2.7.3. Adsorption Kinetics
3. Results
3.1. Effect of pH on Dyes Adsorption
3.2. Adsorption Isotherm
3.3. Adsorption Thermodynamics
3.4. Adsorption Kinetics
4. Conclusions
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Dye | Qm (mg/g) | KL (L/mg) | R2 |
---|---|---|---|
Malachite green | 19.23 | 0.3071 | 0.986 |
Safranine T | 42.02 | 0.0386 | 0.897 |
Methylene blue | 18.45 | 0.5503 | 0.957 |
Dye | n | KF (mg/g) (L/mg)1/n | R2 | n * | KF * (mg/g) (L/mg)1/n | R2 * | Ref. |
---|---|---|---|---|---|---|---|
Malachite green | 1.38 | 4.12 | 0.981 | 1.58 | 8.30 | 0.980 | [25] |
2.18 | 26.27 | 0.980 | [26] | ||||
Safranine T | 1.11 | 1.55 | 0.995 | 1.28 | 15.50 | 0.990 | [25] |
Methylene blue | 1.39 | 5.77 | 0.993 | 2.08 | 58.90 | 0.980 | [25] |
2.04 | 19.31 | 0.983 | [26] | ||||
2.47 | 7.02 | 0.978 | [27] | ||||
1.05 | 1.13 | 0.999 | [28] |
Dye | R2 | ||
---|---|---|---|
Malachite green | −10.35 | −26.1 | 0.984 |
Safranine T | −23.99 | −77.5 | 0.983 |
Methylene blue | −16.00 | −42.6 | 0.981 |
Dye | First Order Kinetic Model | Second Order Kinetic Model | |||
---|---|---|---|---|---|
k1 (1/min) | R2 | Qe (mg/g) | k2 (g/mg)·(1/min) | R2 | |
Malachite green | 0.0891 | 0.609 | 9.662 | 0.595 | ≈1 |
Safranine T | 0.0849 | 0.652 | 9.389 | 0.259 | ≈1 |
Methylene blue | 0.0948 | 0.725 | 9.823 | 0.503 | ≈1 |
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Wu, J.; Xia, A.; Chen, C.; Feng, L.; Su, X.; Wang, X. Adsorption Thermodynamics and Dynamics of Three Typical Dyes onto Bio-adsorbent Spent Substrate of Pleurotus eryngii. Int. J. Environ. Res. Public Health 2019, 16, 679. https://doi.org/10.3390/ijerph16050679
Wu J, Xia A, Chen C, Feng L, Su X, Wang X. Adsorption Thermodynamics and Dynamics of Three Typical Dyes onto Bio-adsorbent Spent Substrate of Pleurotus eryngii. International Journal of Environmental Research and Public Health. 2019; 16(5):679. https://doi.org/10.3390/ijerph16050679
Chicago/Turabian StyleWu, Jianguo, Aiqiang Xia, Chunyan Chen, Liuying Feng, Xiaohui Su, and Xinfeng Wang. 2019. "Adsorption Thermodynamics and Dynamics of Three Typical Dyes onto Bio-adsorbent Spent Substrate of Pleurotus eryngii" International Journal of Environmental Research and Public Health 16, no. 5: 679. https://doi.org/10.3390/ijerph16050679