1. Introduction
Cavern underground storage in salt deposits has been known in the world for many years. This type of storage is considered one of the best for storing both natural gas and liquid fuels in terms of their flexibility of operation and ensuring tightness [
1]. In the era of ongoing energy transformation and the growing share of renewable energy sources (RES) in the country’s energy balance, it is necessary to look for opportunities to store electricity from RES because its production is not correlated with the current demand in the power grid [
2]. Therefore, it is necessary to find a way to store surplus electricity on a large scale and at the same time enable its rapid release in the event of a sudden increase in the demand for electricity in the network. One way to store electricity is to convert it into energy in another form, which allows for its permanent storage in an easy and relatively economical way, both for short and long periods of time [
3]. In the case of using large-scale energy storage in salt caverns, energy stored in the form of natural gas, hydrogen, and compressed air energy can be taken into account [
4,
5].
Due to the increasing share of renewable energy sources in the Polish energy balance, one of the biggest disadvantages of which is the stochastic process of operation, it is becoming necessary to look for possibilities of storing surplus energy generated in the period when there is no high demand for electricity in the power grid [
4,
5]. In the era of the ongoing energy transformation and striving to achieve the goal of “zero emissions”, the use of renewable energy sources in the total energy balance will increase, and consequently, the demand for increasing energy storage capacities will increase. However, achieving the above goal will not happen as quickly as it might seem, and hence, a transition period is necessary during which the energy sector will gradually reduce the emission of harmful substances into the atmosphere. One of the fuels, the increased use of which in the energy sector will significantly reduce the level of emissions compared to coal combustion, is natural gas. Hence, from the perspective of the coming decades, the most advantageous method of storing energy on a large scale will be technologies using a combination of combustion of gaseous fuels in combination with renewable energy sources in order to re-generate electricity.
Surplus electricity from renewable energy sources on a local scale (several individual recipients) is best stored using various types of batteries or accumulators. In the case of large-scale installations, where we are talking about a scale of several dozen or several hundred TWh of energy to store, “conventional” batteries turn out to be ineffective. Building a storage facility based on such batteries would require connecting several thousand such batteries. In the case of many such installations, there will be problems with the possibility of obtaining rare metals needed for their construction. The installation requires huge areas for construction. Using pumped-storage power plants to store energy is a good way to store energy surpluses from the grid, but it is not always possible in a given location. They require access to appropriate hydrological conditions and also huge areas [
6].
Therefore, if we are looking for opportunities to store energy on a large scale, we should focus on the use of geological structures that allow for locating storage facilities below the ground surface with little use of space on the surface [
7].
When comparing underground gas storage in salt caverns to underground gas storage in depleted porous reservoirs or deep aquifers, they have several advantages, such as greater tightness and medium release rate. It is possible to achieve many rapid discharge cycles compared to depleted reservoirs, where typically there is one discharge cycle per year [
8]. If we are looking for a high frequency of storage cycles, we can also consider above-ground tanks, but here again, there is a problem with the capacity of such tanks and the need to develop a large area.
Compressed air energy storage in salt caverns (CAES) is one way of storing excess electrical energy produced by converting it into mechanical energy, and then generating it “anew” and feeding it back to the grid when needed. The solution proposed in CAES technology provides significant savings in terms of energy demand because all the electrical energy produced is fed directly into the grid. In a classic gas turbine installation, a large part of it (energy) is consumed by driving compressors supplying the turbine with air [
4,
5]. The possibility of storage means that the electrical energy produced does not have to be fed into the grid at the time of production [
3,
9]. The advantage of this type of installation is the possibility of rapid filling and emptying, which means that such storage facilities can be successfully used to compensate for excess electrical energy in the grid and relatively quickly supplement its shortages [
10,
11]. CAES salt caverns were used in 1978 in Huntorf, Germany, where the installation served as an emergency power supply for a nuclear power plant (the current capacity of the installation is 320 MW) [
12]. An installation of this type was also built in McIntosh, USA in 1991 (110 MW), and in 2012, a small CAES installation was launched in Gaines, Texas, USA, operating in conditions close to isothermal [
2,
4]. Many years of failure-free operation of the above installations confirmed the technical possibilities of using salt caverns as peak energy storage facilities that can be quickly (several dozen minutes/several hours) emptied or filled [
2,
5].
The analyses conducted in the following part focus on the general parameters of the installation’s operation, but after entering more detailed data, they can be adjusted to specific geological conditions.
Although they are concerned with the use of the potential of salt deposits in Poland and are based on the principles of salt cavern design adopted in Poland, they can also be successfully implemented in other locations in the world with a similar geological structure.
2. CAES Potential in Salt Caverns in Poland
Based on the assessment of the potential of identified salt deposits in Poland and the determination of the possibility of using these structures as potential compressed air energy storage facilities [
1,
2,
13], an analysis was carried out in comparison with the map of average wind speeds blowing in Poland. Based on the analysis of salt deposits (
Figure 1) and wind speed (
Figure 2), the most favorable conditions for the construction of a CAES power plant occur in the area of the Łeba elevation and the Bay of Puck. Based on borehole data, the average thickness of salt deposits ranges from 150 to 160 m at a depth of 600 to 900 m below ground level [
13]. It can be assumed that these conditions are similar to the existing CAES installation in Huntorf, where the caverns are located at an interval of 650–900 m below ground level [
2]. The entire area of occurrence of central Polish salt domes can also be considered a potential location for such a storage facility [
13,
14].
CAES storage systems largely make electricity production independent of constant access to a renewable source (e.g., wind). If the wind force does not reach the established minimum required to drive a wind turbine 24 h a day, during periods of “wind calm”, it is possible to use the energy stored in compressed air to produce electricity in a gas turbine. Thanks to this, CAES technology can be treated as a supplement to wind energy during periods when energy production from wind turbines is not possible [
5]. However, the basic goal of using the CAES system is to cover peak demand, which is why it is necessary to consider locations where the average wind speed is as high as possible, which is why such an area was selected as the most advantageous for the construction of wind turbines, which are the source of drive for compressors [
12]. According to the author, in order to use the advantages of the CAES installation most effectively, it would be most advantageous to connect it to a natural gas storage facility (
Figure 3) so that the storage potential of this medium can also be used. Hence, potential places where it would be possible to build a compressed air storage facility in Poland are primarily locations located near the existing natural gas cavern storage facilities, i.e., CUGS Mogilno and CUGS Kosakowo [
1,
13].
2.1. Cavern Underground Gas Storage in Poland (CUGS)
Currently, there are two cavern storage facilities for natural gas in Poland. Their main task is to balance the peak demand for gas in the network. According to data from the Gas Storage Poland Company website [
16], the active storage capacity of the CUGS Mogilno is 580.92 million m
3 (in 14 storage caverns); maximum injection capacity: 9.60 million m
3/day, withdrawal capacity: 18.00 million m
3/day. Currently, the CUGS Kosakowo has 296.80 million m
3 of active storage capacity (in eight caverns); maximum injection capacity: 2.40 million m
3/day, maximum withdrawal capacity: 9.60 million m
3/day.
2.2. Compressed Air Energy Storage Cavern (CAES)
When analyzing the work of the CAES cavern, it should be noted that it operates in a relatively small pressure range (compared to natural gas storage caverns)—in the Huntorf installation, the range is 5–7 MPa; However, the cavern empties within 2 h (the gas cavern empties within around a dozen days). The rapid pressure changes during operations will cause changes in the temperature of the stored medium, mass rock, and casing [
17].
Based on the parameters of the existing CAES installation in Huntorf, assumptions for calculations were determined. They do not result from geological conditions but from technical and economic conditions related to the strength of the operating pipes, casing pipes, and cement, which are exposed to high-temperature fluctuations and rapid stress changes in the operating conditions of the CAES system. For example, in the Huntorf power plant, the operating efficiency exceeds 1 million m
3/h from one borehole, which requires the use of operating pipes with diameters of 24” [
12,
18], which is significant compared to the diameters commonly used in the drilling industry, and at the same time, requires the use of better materials (especially in terms of strength). The parameters of the storage caverns for storing energy and gas were adopted based on the average values from geological data for the Łeba and Mechelinki deposits and in relation to the existing KPMG Kosakowo storage facility. The parameters adopted for further calculations are presented in
Table 1.
Based on the above assumptions, the maximum geometric volume of the cavern that could be constructed in a deposit of this thickness was estimated. The active volume was determined based on the volume loss during leaching of the cavern into insoluble parts at the level of 20% of the geometric volume [
19].
Of course, the values presented in the table above are the maximum values that can be achieved for the assumed parameter values.
Assuming the parameters of the Huntorf power plant [
4,
20] (with a capacity of approx. 300 MW and a cavern volume of 310,000 m
3, emptied in 2 h) as a reference point, the active volume of caverns V to generate power P should be [
19]:
where
V—volume in 103 [m3];
t—working time [h];
P—power [MW].
The number of caverns n that must be leached to reach the required volume V
active:
Based on the above relationships, it is possible to estimate the number of caverns that must be made to obtain the required power in a deposit of a given thickness [
19]. Assuming a thickness of about 160 m, to achieve a power of approx. 200 MW and energy release for 4 h, two caverns must be made. If the time of energy release is increased, the number of necessary storage caverns must be increased.
2.3. Caverns Parameters
The range of operating pressures of the storage cavern depends primarily on the depth of the cavern foundation, geological structure, stored medium, and the scenario of the storage operation.
The maximum pressure that can be achieved in the cavern is traditionally determined for the depth of the last cemented exploitation pipe and is proportional to the depth, taking into account the micro-fracturing factor (g
frac) determined on the basis of well tests. In practice, for Polish conditions, it is assumed that 0.018 MPa/m +/− 0.001 [
19].
It is difficult to provide a general formula for determining the minimum pressure because it depends not only on the depth but also on the strength and creep rate of salt rock, as well as the size and shape of the cavern [
19].
Since the operation of the CAES storage cavern does not require very high pressures, hence that the cavern does not have to be very deeply founded, it was decided to adopt parameters similar to the Łeba deposit due to its location for calculations [
14]. Therefore, an average level of salt layer deposition can be assumed to be in the interval of 670–890 m, with an average thickness of 160 m.
The cavern parameters were estimated based on the following equations [
19]:
where
The temperature of the rock mass is usually determined according to the geothermal gradient [
19]:
where
Tg0—thermal coefficient, for the Łeba elevation: 283 K;
gT—geothermal gradient, for the Łeba elevation: 0.01 .
For further calculations, the compressed air storage cavern was assumed: pmax = 7 MPa; pmin = 5 MPa.
In the case of caverns used for storing natural gas, the proposed storage facility could use the gas stored in the caverns of the Kosakowo CUGS or it would also be necessary to create caverns for natural gas in the Łeba deposit [
19]. By analogy to Kosakowo, the geometric volume of such a single cavern could be about 200,000 m
3. Assuming the deposit parameters as seen in
Table 1, it is possible to estimate the parameters of the natural gas storage cavern (
Table 3).
For further calculations, the natural gas storage cavern was assumed: p
max = 12 MPa; p
min = 4.5 MPa.
where
Vactive—geometric active volume (storage volume);
∆p—working pressure: pmax − pmin;
R—gas constant: ;
ρgas—gas density: ;
Trock—rock mass temperature calculated according to Equation (7): 290.854 K.
Based on Equation (8) [
19], the storage capacity of the natural gas cavern was determined to be approximately 14 million m
n3 of natural gas.
5. Conclusions
The calculations carried out in the article confirmed the technical possibility of cooperation of CAES installations with natural gas storage caverns in terms of small volume loss in the case of their continuous use for balancing the power grid.
The loss of active cavern capacity due to the convergence phenomenon is one of the key problems that arise during the operation of storage caverns in rock salt deposits.
With a relatively large operating regime of the CAES storage cavern (4 h of emptying) and the adopted operating scenarios of 24 h, 2 days, 1 week, and 2 weeks, no significant decreases in the active volume of the storage were observed after 40 years of operation, the difference between the individual variants of the operating scenarios reached a maximum of 20 m3.
In the case of the CUGS storage cavern, emptying the cavern from maximum to minimum pressure will take 30 days, and depending on the scenario, the filling time will be 60 or 120 days; the observed difference does not exceed 50 m3 of the active volume.
The differences in the obtained mean annual convergence speeds between the CAES and CUGS caverns are primarily due to the different operating pressure ranges but also to different operating scenarios.
The period when the cavern remains empty has the greatest impact on the loss of volume. The most important thing is to shorten this period to a minimum.
The analyses and calculations carried out indicate that the large-scale storage of surplus electricity from RES is possible using CAES technology installations connected to natural gas storage caverns. Such an installation can operate practically every day and will not significantly affect the loss of storage capacity over the 40 years of operation of such a storage facility.
Calculations were performed on the averaged parameter values for a given location. In the case of moving to the design phase of such an installation, it would be necessary to first conduct detailed geological studies to confirm the possibility of creating caverns of a given volume.
During the stage of designing the installation, attention should also be paid to the aspect related to the need to dispose of brine from the leaching of salt caverns. Discharging brine into surface waters is not legally permitted in Poland or in the EU. Hence, the only possibility is its injection into deep aquifers, discharging diluted brine into seawater (note by CUGS Kosakowo), or using brine as a semi-finished product in the chemical and spa industry (note by CUGS Mogilno).
The economic aspect of building and later operating such an installation will also be of key importance. At the current stage of energy transformation, economic indicators will not be promising, but as forecasts indicate, the constantly growing share of renewable energy will force the need to adapt the network by creating energy storage facilities.
In the era of the ongoing energy transformation in Poland, it is possible in the future to consider the possibility of replacing the gas turbine for electricity production with a hydrogen-powered turbine or using fuel cells instead. In such a case, natural gas storage caverns should be replaced with caverns storing hydrogen. However, such a solution requires separate analyses, taking into account the use of alkaline electrolyzers for hydrogen production, which, compared to other solutions, allows for a relatively flexible possibility of quick start-up and shutdown of the installation at any time (short-term surplus energy from renewable energy sources). Analyses should also include the need to obtain large amounts of water of appropriate purity for the production of “green hydrogen” in electrolyzers, which is often not mentioned.
Of course, in the case of large-scale energy storage, the storage of “green” hydrogen is currently being considered but it seems that in the “transitional” period, the concept proposed in the article, this type of installation will certainly prove useful in covering peak demand for energy storage from renewable sources. Moreover, in the author’s opinion, from the perspective of the next 30–35 years, it will definitely be the most advantageous solution in relation to Polish conditions.