Controlling the Degradation Rate of Biodegradable Mg–Zn-Mn Alloys for Orthopedic Applications by Electrophoretic Deposition of Hydroxyapatite Coating
Abstract
:1. Introduction
2. Materials and Methods
2.1. Magnesium Alloys and Hydroxyapatite
- -
- obtaining Mg alloy specimens and evaluating their surface properties;
- -
- preparing HAP solution;
- -
- deposing HAP on the ZM21, ZMX410 alloys surface by EPD.
2.1.1. Preparation of Hydroxyapatite Solution
2.1.2. Deposition of Hydroxyapatite on the Magnesium Alloys Surface by Electrophorethic Method
2.2. Characterization Methods
2.2.1. Scanning Electron Microscopy coupled with Energy Dispersive Spectroscopy
2.2.2. X-ray Diffraction
2.2.3. Fourier-Transform Infrared Spectroscopy
2.2.4. Corrosion Resistance of the Magnesium Alloys in the Simulated Media
Immersion Test
Evaluation of Electrochemical Corrosion Behaviour of the Uncoated and Hydroxyapatite Coated Specimens
- open circuit potential (Eoc) measurement over 1 h;
- plotting the linear polarization curves from –250 mV (vs. OCP) to + 250 mV (vs. OCP) - Tafel curves, with a scan rate of 1 mV/s.
- open circuit potential (Eoc);
- corrosion potential (Ecorr);
- the density of the corrosion current (icorr);
- the slope of the cathodic curve (βc);
- the slope of the anodic curve (βa).
- corrosion rate (CR);
- polarization resistance (Rp);
- corrosive attack efficiency (Pe).
2.2.5. Contact Angle Determination
3. Results and Discussion
3.1. Scanning Electron Microscopy (SEM) Coupled with Energy-Dispersive Spectroscopy (EDS) Results
3.2. XRD Results
3.3. FTIR Results
3.4. Corrosion Behaviour of the Mg Alloys in the SBF
3.4.1. Immersion Test
3.4.2. Evaluation of Electrochemical Corrosion Behavior of the Uncoated and HAP Coated Specimens
Corrosion Resistance
Surface Analysis by SEM- EDS of the Samples after Corrosion Experiments
XRD Analysis of the Samples after Corrosion Experiments
FTIR Analysis of the Samples after Corrosion Experiments
3.5. Contact Angle
4. Conclusions
Author Contributions
Funding
Conflicts of Interest
References
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Alloy | Chemical Element | ||||
---|---|---|---|---|---|
Mg (%wt) | Zn (%wt) | Y (%wt) | Mn (%wt) | Ca (%wt) | |
ZM21 | 96.68 | 2.00 | 0.16 | 1.16 | – |
ZMX410 | 94.78 | 4.30 | – | 0.62 | 0.30 |
Time (h) | 24 | 48 | 72 | 96 | 120 | 192 | 336 |
---|---|---|---|---|---|---|---|
ZM21 CR (mm/year) | 0.28 | 0.42 | 0.47 | 0.52 | 0.61 | 0.73 | 1.01 |
ZMX410 CR (mm/year) | 37.81 | 38.58 | 39.77 | – |
Sample | Ecorr (V) | icorr (µA/cm2) | βc (mV) | βa (mV) | CR (mm/year) | Rp (Ωxcm2) | Pe (%) |
---|---|---|---|---|---|---|---|
ZM21 | −1.704 | 314.4 | 319.616 | 332.8 | 6.85 | 225.44 | − |
ZM21-1 | −1.722 | 192.2 | 246.422 | 296.7 | − | 304.48 | 38.86 |
ZM21-2 | −1.727 | 181.3 | 296.368 | 420.8 | − | 416.96 | 42.33 |
ZMX410 | −1.620 | 295.7 | 290.676 | 236.2 | 6.34 | 191.56 | − |
ZMX410-1 | −1.581 | 283.8 | 220.632 | 111.3 | − | 113.39 | 4.04 |
ZMX410-2 | −1.560 | 282.6 | 233.624 | 90.8 | − | 100.62 | 4.42 |
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Antoniac, I.; Miculescu, F.; Cotrut, C.; Ficai, A.; Rau, J.V.; Grosu, E.; Antoniac, A.; Tecu, C.; Cristescu, I. Controlling the Degradation Rate of Biodegradable Mg–Zn-Mn Alloys for Orthopedic Applications by Electrophoretic Deposition of Hydroxyapatite Coating. Materials 2020, 13, 263. https://doi.org/10.3390/ma13020263
Antoniac I, Miculescu F, Cotrut C, Ficai A, Rau JV, Grosu E, Antoniac A, Tecu C, Cristescu I. Controlling the Degradation Rate of Biodegradable Mg–Zn-Mn Alloys for Orthopedic Applications by Electrophoretic Deposition of Hydroxyapatite Coating. Materials. 2020; 13(2):263. https://doi.org/10.3390/ma13020263
Chicago/Turabian StyleAntoniac, Iulian, Florin Miculescu, Cosmin Cotrut, Anton Ficai, Julietta V. Rau, Elena Grosu, Aurora Antoniac, Camelia Tecu, and Ioan Cristescu. 2020. "Controlling the Degradation Rate of Biodegradable Mg–Zn-Mn Alloys for Orthopedic Applications by Electrophoretic Deposition of Hydroxyapatite Coating" Materials 13, no. 2: 263. https://doi.org/10.3390/ma13020263