Adsorption of Lead Ion from Wastewater Using Non-Crystal Hydrated Calcium Silicate Gel
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials and Equipment
2.2. Method
2.2.1. Sample Preparation
2.2.2. Adsorption Performance
3. Results
3.1. Structure and Morphology
3.2. Adsorption Performance of Lead Ions Using CSH
3.2.1. Effect of Calcium Silicon Ratio on the Adsorption of Lead Ions Using CSH
3.2.2. Influencing Factors of CSH Adsorption of Lead Ions
3.3. Thermodynamic and Kinetic Analysis of CSH Adsorption of Lead Ions
3.4. Study on Adsorption Mechanism and Stability of CSH Adsorbing Pb(II)
3.5. Comparison with Other Adsorbents
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Calcium-Silicon Ratio | aBET (m2·g−1) | Average Pore Size (nm) | pH Value of the System | Zeta Potential (mV) |
---|---|---|---|---|
0.6 | 68 | 9.25 | 9.38 | −21.26 |
1.2 | 122 | 11.53 | 9.45 | −19.16 |
2.0 | 124 | 14.54 | 9.42 | −11.32 |
2.2 | 128 | 13.43 | 9.48 | −9.86 |
Langmuir Parameter | Freundlich Parameter | ||||
---|---|---|---|---|---|
Qm (mg/g) | KL (L/mg) | RL2 | KF (L/mg) | 1/n | RF2 |
238.095 | 0.2 | 0.9835 | 98.5634 | 5.6915 | 0.9433 |
Pseudo-First Order Kinetic Model | Pseudo-Second Order Kinetic Model | Intraparticle Diffusion Model | |||||
---|---|---|---|---|---|---|---|
k1 /min−1 | Qe /mg·g−1 | R2 | k2 /g·mg−1·h−1 | Qe /mg·g−1 | R2 | Kid /mg·(g·h0.5)−1 | R2 |
0.0172 | 250.6105 | 0.8729 | 0.0001015 | 263.1679 | 0.9697 | 15.419 | 0.9678 |
Adsorbents | Qm (mg·g−1) | References |
---|---|---|
Cellulose-MT-CBM a | 39.02 | [47] |
SC/ALG b | 179.10 | [48] |
NCS/SA/MC c | 114.47 | [49] |
CA/PCL d | 70.50 | [50] |
CSH gel | 263.17 | This work |
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Liu, S.; Cui, S.; Guo, H.; Wang, Y.; Zheng, Y. Adsorption of Lead Ion from Wastewater Using Non-Crystal Hydrated Calcium Silicate Gel. Materials 2021, 14, 842. https://doi.org/10.3390/ma14040842
Liu S, Cui S, Guo H, Wang Y, Zheng Y. Adsorption of Lead Ion from Wastewater Using Non-Crystal Hydrated Calcium Silicate Gel. Materials. 2021; 14(4):842. https://doi.org/10.3390/ma14040842
Chicago/Turabian StyleLiu, Shijie, Suping Cui, Hongxia Guo, Yali Wang, and Yan Zheng. 2021. "Adsorption of Lead Ion from Wastewater Using Non-Crystal Hydrated Calcium Silicate Gel" Materials 14, no. 4: 842. https://doi.org/10.3390/ma14040842