Research of High-Purity Lanthanum Prepared by Zone Refining
Abstract
:1. Introduction
2. Experimental Procedure
3. Results and Discussion
3.1. Calculation of Equilibrium Distribution Coefficient
3.2. The Effect of Zone-Refining Rate on Impurity Distribution
- The parameter keff is assumed to be constant during zone refining.
- The widths of the molten zone, cross-sectional area, zone-refining rate, temperature, and other relevant process parameters remained unaltered and stable.
- Impurities are uniformly distributed over the whole molten zone area without segregation.
- The diffusion of impurities in the solid phase is negligible.
- The solidification interface is flat and in equilibrium.
3.3. The Effect of the Number of Refining Passes on Impurity Distribution
4. Conclusions
- By calculating the effective partition coefficients of impurities, it was revealed that keff of Fe and Si was less than 1 under different conditions, which confirmed that the removal of Fe and Si impurities in lanthanum by zone refining is both feasible and effective.
- The concentrations of Fe and Si in the metal gradually increased from the beginning to the end after zone refining and increased drastically in the last region. The purification effect will increase with the decrease of the zone-refining rate, and Si was easier to remove than Fe in lanthanum.
- With the increase of the number of zone refining, the purification effect increased significantly, but impurities approached the limiting distribution at 10 passes. Increasing the number of refining passes did not show a large impact on the purification effect.
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
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Impurity | 1 | 2 | 3 | 4 | Average |
---|---|---|---|---|---|
Fe | 46 | 47 | 49 | 50 | 48 |
Cu | 0.3 | 0.5 | 0.6 | 0.6 | 0.5 |
Cr | 0.65 | 0.32 | 0.51 | 0.6 | 0.52 |
Si | 39 | 31 | 25 | 41 | 34 |
Mn | 0.015 | 0.014 | 0.013 | 0.018 | 0.015 |
Zn | 0.003 | 0.007 | 0.006 | 0.008 | 0.006 |
Ti | 0.004 | 0.001 | 0.005 | 0.006 | 0.004 |
Pr | 0.003 | 0.001 | 0.002 | 0.006 | 0.003 |
Ce | 0.11 | 0.13 | 0.15 | 0.09 | 0.12 |
Co | 0.012 | 0.007 | 0.004 | 0.005 | 0.007 |
Metal | Impurity | k0 | |||
---|---|---|---|---|---|
La | 6196.50 J/mol | 1193.15 K | Fe | −1746.03 | 0.0859 |
Si | −1715.26 | 0.102 |
Impurity | D | v | |
---|---|---|---|
Fe | 1.32 × 10−8m2s−1 | 5 mm/min | 0.150133 |
15 mm/min | 0.384395 | ||
25 mm/min | 0.688194 | ||
Si | 3.47 × 10−8m2s−1 | 5 mm/min | 0.119956 |
15 mm/min | 0.164083 | ||
25 mm/min | 0.220380 |
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Yu, C.; Pan, B.; Wang, Z.; Chen, D.; Zhang, X.; Yang, W.; Zhang, D.; Lu, W. Research of High-Purity Lanthanum Prepared by Zone Refining. Materials 2022, 15, 4603. https://doi.org/10.3390/ma15134603
Yu C, Pan B, Wang Z, Chen D, Zhang X, Yang W, Zhang D, Lu W. Research of High-Purity Lanthanum Prepared by Zone Refining. Materials. 2022; 15(13):4603. https://doi.org/10.3390/ma15134603
Chicago/Turabian StyleYu, Chuang, Bo Pan, Zhiqiang Wang, Dehong Chen, Xiaowei Zhang, Wensheng Yang, Dongwei Zhang, and Wenli Lu. 2022. "Research of High-Purity Lanthanum Prepared by Zone Refining" Materials 15, no. 13: 4603. https://doi.org/10.3390/ma15134603