Synthesis and Corrosion Inhibition Potential of Cerium/Tetraethylenepentamine Dithiocarbamate Complex on AA2024-T3 in 3.5% NaCl
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. Synthesis Procedures
2.2.1. Preparation of the Dithiocarbamate Ligand—Sodium Tetraethylenepentamine Dithiocarbamate (TEPA/CSSNa)
2.2.2. Synthesis of the Metal–Dithiocarbamate Coordinate Compound—Cerium/Ditetraethylenepentamine Dithiocarbamate ((TEPA/CSS)2Ce) Complex
2.3. Characterization of the Synthesized Compounds
2.4. Corrosion Media
2.5. Electrochemical Tests
2.6. Surface Characterization
3. Results
3.1. Characterization of the Synthesized Compounds
3.1.1. FT-IR
TEPA/CSSNa
(TEPA/CSS)2Ce
3.1.2. XRD
3.2. Electrochemical Studies
3.2.1. EIS Measurements
3.2.2. Potentiodynamic Polarization Measurements
3.3. Surface Characterization
3.3.1. SEM-EDS Analysis
3.3.2. XPS Analysis
3.4. Corrosion Inhibition Mechanism
- (a)
- Interaction between CS2− groups and intermetallic compounds.
- (b)
- Interaction between CS2− groups and intermediate Ce compounds.
- (c)
- The direct deposition of the (TEPA/CSS)2Ce complex on the Al surface.
- (d)
- The chemical interactions between the lone electron pairs and unoccupied d-orbitals of the metal.
4. Comparison with Other Corrosion Inhibitors
5. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Medium | Immersion Time (h) | Rs (Ω cm2) | Qf (S cm−2sn) | n | Rf (Ω cm2) | Cdl (S cm−2sn) | Rct (Ω cm2) | Rp (Ω cm2) | E (%) |
---|---|---|---|---|---|---|---|---|---|
3.5% NaCl | 2 | 10.33 | 2.5510−5 | 0.91 | 13.1103 | 0.2410−3 | 8.22103 | 21.32103 | - |
12 | 9.43 | 5.3910−5 | 0.89 | 4.19103 | 1.6610−3 | 5.94103 | 10.13103 | - | |
24 | 9.29 | 6.5810−5 | 0.86 | 4.52103 | 2.3410−3 | 6.36103 | 10.88103 | - | |
72 | 9.19 | 9.1810−5 | 0.83 | 5.58103 | 2.0510−3 | 9.00103 | 14.58103 | - | |
120 | 9.05 | 18.1210−5 | 0.77 | 4.32103 | 6.1810−3 | 4.47103 | 8.79103 | - | |
3.5% NaCl + inhibitor | 2 | 10.34 | 8.0010−5 | 0.94 | 4.13103 | 2.1610−3 | 4.85103 | 8.97103 | - |
12 | 10.39 | 7.9910−5 | 0.93 | 9.01103 | 1.4810−3 | 7.37103 | 16.38103 | 33.55 | |
24 | 9.75 | 3.1910−5 | 0.95 | 3.91103 | 1.3910−3 | 14.2103 | 18.11103 | 39.91 | |
72 | 10.41 | 7.2610−5 | 0.90 | 19.78103 | 0.66 10−3 | 24.03103 | 43.81103 | 66.72 | |
120 | 9.35 | 4.4210−5 | 0.82 | 118.70103 | 0.1210−3 | 158.40103 | 277.10103 | 96.80 |
(a) 24 h | |||||
---|---|---|---|---|---|
Solution | Ecorr (V) | Ebr (V) | EpitEcorr (V) | Icorr (μA cm−2) | E (%) |
3.5% NaCl | −0.63 | - | - | 489 | - |
3.5% NaCl + inhibitor | −0.77 | −0.62 | 0.15 | 331 | 32.31 |
(b) 120 h | |||||
Solution | Ecorr (V) | Ebr (V) | EpitEcorr (V) | Icorr (μA cm−2) | E (%) |
3.5% NaCl | −0.76 | −0.66 | 0.1 | 2390 | - |
3.5% NaCl + inhibitor | −0.89 | −0.57 | 0.32 | 437 | 81.72 |
Solution | Al | O | Cu | Mg | Si | C | S | N | Ce |
---|---|---|---|---|---|---|---|---|---|
3.5% NaCl | 71.1 | 21.6 | 5.3 | 0.9 | 1.1 | - | - | - | - |
3.5% NaCl + inhibitor | 69.4 | 7.2 | 14.1 | 0.7 | - | 7.8 | 0.4 | 0.3 | 0.1 |
Elements | Cl 2p | Na 1s | O 1s | Al 2p | C 1s | N 1s | S 2p | Ce 3d |
---|---|---|---|---|---|---|---|---|
Atomic (%) | 13.2 | 9.1 | 23.15 | 10.00 | 31.71 | 9.53 | 2.61 | 0.70 |
Solutions | Immersion Time (hours) | Efficiency (%) | Year | References |
---|---|---|---|---|
3.5% NaCl + (E)-2-(2,4-dihydroxybenzylidene) Hydrazinecarbothioamide | 120 | 90 | 2018 | [1] |
3.5% NaCl + (E)-2-(2-hydroxybenzylidence) hydrazinecarbothioamide | 120 | 74.9 | 2018 | [1] |
3.5% NaCl + (TEPA/CSS)2Ce | 120 | 96.8 | 2022 | This study |
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Pham, T.H.; Lee, W.-H.; Son, G.-H.; Tran, T.T.; Kim, J.-G. Synthesis and Corrosion Inhibition Potential of Cerium/Tetraethylenepentamine Dithiocarbamate Complex on AA2024-T3 in 3.5% NaCl. Materials 2022, 15, 6631. https://doi.org/10.3390/ma15196631
Pham TH, Lee W-H, Son G-H, Tran TT, Kim J-G. Synthesis and Corrosion Inhibition Potential of Cerium/Tetraethylenepentamine Dithiocarbamate Complex on AA2024-T3 in 3.5% NaCl. Materials. 2022; 15(19):6631. https://doi.org/10.3390/ma15196631
Chicago/Turabian StylePham, Thi Huong, Woo-Hyuk Lee, Gyeong-Ho Son, Trang Thu Tran, and Jung-Gu Kim. 2022. "Synthesis and Corrosion Inhibition Potential of Cerium/Tetraethylenepentamine Dithiocarbamate Complex on AA2024-T3 in 3.5% NaCl" Materials 15, no. 19: 6631. https://doi.org/10.3390/ma15196631