Investigation of CO2 Adsorption on Avocado Stone-Derived Activated Carbon Obtained through NaOH Treatment
Abstract
:1. Introduction
2. Materials and Methods
3. Results and Discussion
- q—gas equilibrium adsorption at pressure p;
- p—equilibrium pressure;
- qm—saturation capacity;
- b—equilibrium constant;
- n—exponential parameter representing the heterogeneity of the material.
- qe,o—theoretical adsorption capacity calculated from the model;
- qe,z—adsorption capacity determined experimentally;
- N—total number of measurements.
- xg1 (xg2)—the molar fractions of gas 1/gas 2 (g1/g2) in the adsorbed phase;
- yg1, (yg2)—the molar fractions of gas 1/gas 2 (g1/g2) in the bulk phase.
- -
- the changes in the gas absorption values (and the saturation capacity) with the increase in the temperature;
- -
- the isosteric heat of adsorption value.
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Biomass | qCO2_0C | References |
---|---|---|
(mmol/g) | ||
rice husk | 5.83 | [21] |
walnut shell | 5.22 | [22] |
palm sheath | 5.28 | [23] |
Amazonian nutshells | 5.13 | [24] |
lignocellulose | 5.20 | [25] |
peanut shells | 5.20 | [26] |
pomegranate peels | 3.90 | [26] |
birch | 4.50 | [27] |
coconut shell | 6.04 | [28] |
corn cobs | 2.70 | [26] |
AC | SSA | Vtot | Vmicro | maxD | qCO2_0C |
---|---|---|---|---|---|
[m2/g] | [cm3/g] | cm3/g | [nm] | [mmol/g] | |
C_NaOH_750 | 817 | 0.538 | 0.259 | 297 | 4.6 |
C_NaOH_800 | 1172 | 0.691 | 0.375 | 312 | 5.9 |
C_NaOH_850 | 918 | 0.574 | 0.295 | 241 | 3.7 |
AC | Temp. | qm | b | n | LSM |
---|---|---|---|---|---|
[°C] | [mmol/g] | [bar−1] | |||
Carbon dioxide | |||||
C_NaOH_750 | 0 | 10.26 | 0.84 | 0.62 | 4 × 10−3 |
C_NaOH_800 | 0 | 14.46 | 0.69 | 0.64 | 7 × 10−3 |
C_NaOH_850 | 0 | 12.21 | 0.43 | 0.65 | 4 × 10−3 |
C_NaOH_800 | 20 | 10.59 | 0.67 | 0.72 | 15 × 10−3 |
Nitrogen | |||||
C_NaOH_800 | 20 | 2.34 | 0.39 | 0.99 | 3 × 10−5 |
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Siemak, J.; Wróbel, R.J.; Pęksiński, J.; Michalkiewicz, B. Investigation of CO2 Adsorption on Avocado Stone-Derived Activated Carbon Obtained through NaOH Treatment. Materials 2023, 16, 4390. https://doi.org/10.3390/ma16124390
Siemak J, Wróbel RJ, Pęksiński J, Michalkiewicz B. Investigation of CO2 Adsorption on Avocado Stone-Derived Activated Carbon Obtained through NaOH Treatment. Materials. 2023; 16(12):4390. https://doi.org/10.3390/ma16124390
Chicago/Turabian StyleSiemak, Joanna, Rafał J. Wróbel, Jakub Pęksiński, and Beata Michalkiewicz. 2023. "Investigation of CO2 Adsorption on Avocado Stone-Derived Activated Carbon Obtained through NaOH Treatment" Materials 16, no. 12: 4390. https://doi.org/10.3390/ma16124390