Mössbauer and X-ray Diffraction Spectroscopy of High-Iron Bauxites from Kazakhstan
Abstract
:1. Introduction
2. Materials and Methods
3. Results
3.1. X-ray Fluorescence Analysis
3.2. Mössbauer Spectroscopy
3.3. X-ray Diffraction
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Deposit | Main Components, wt. % | μSi | |||||
---|---|---|---|---|---|---|---|
CaO | TiO2 | Fe2O3 | Al2O3 | SiO2 | K2O | ||
Ayatskoye | 0.34 | 3.20 | 26.21 | 53.85 | 16.35 | 0.05 | 3.29 |
Krasnooktyabrskoye | 0.86 | 3.45 | 30.15 | 50.81 | 14.70 | 0.03 | 3.46 |
Belinskoye | 1.12 | 2.62 | 33.04 | 48.04 | 15.14 | 0.04 | 3.17 |
East Ayatskoye | 2.18 | 3.20 | 24.14 | 53.48 | 16.68 | 0.32 | 3.21 |
Arkalykskoye (A1) | 1.57 | 4.91 | 22.00 | 57.69 | 13.72 | 0.11 | 4.20 |
Arkalykskoye (A2) | 0.11 | 3.25 | 18.91 | 56.43 | 14.13 | 0.17 | 3.99 |
Deposit | State | A, % | δ, mm/s | Δ/2ε, mm/s | H, kOe | Cal, at. % |
---|---|---|---|---|---|---|
Ayatskoye | Hematite | 72.2 ± 0.1 | 0.37 ± 0.04 | −0.22 ± 0.04 | 511 ± 1 | 3.34 |
Goethite | 2.3 ± 0.1 | 0.42 ± 0.04 | −0.09 ± 0.04 | 364 ± 3 | ||
Kaolinite [Fe3+]octa | 15.9 ± 0.2 | 0.36 ± 0.04 | 0.50 ± 0.04 | |||
Kaolinite [Fe3+]tetra | 3.0 ± 0.2 | 0.35 ± 0.04 | 1.15 ± 0.04 | |||
Siderite | 5.6 ± 0.1 | 1.23 ± 0.04 | 1.79 ± 0.04 | |||
Ilmenite | 1.0 ± 0.1 | 1.00 ± 0.04 | 0.73 ± 0.04 | |||
Krasnooktyabrskoye | Hematite | 54.1 ± 0.3 | 0.37 ± 0.04 | −0.21 ± 0.04 | 508 ± 1 | 5.12 |
Goethite | 1.4 ± 0.3 | 0.42 ± 0.04 | −0.02 ± 0.04 | 370 ± 9 | ||
Kaolinite [Fe3+]octa | 15.5 ± 0.3 | 0.36 ± 0.04 | 0.54 ± 0.04 | |||
Kaolinite [Fe3+]tetra | 5.9 ± 0.3 | 0.34 ± 0.04 | 1.15 ± 0.04 | |||
Kaolinite [Fe2+]octa | 7.2 ± 0.3 | 1.15 ± 0.04 | 2.58 ± 0.04 | |||
Siderite | 15.0 ± 0.4 | 1.24 ± 0.04 | 1.82 ± 0.04 | |||
Ilmenite | 1.1 ± 0.1 | 0.97 ± 0.04 | 0.67 ± 0.04 | |||
Belinskoye | Hematite | 78.3 ± 0.3 | 0.37 ± 0.04 | −0.22 ± 0.04 | 510 ± 1 | 3.93 |
Goethite | 1.1 ± 0.3 | 0.42 ± 0.04 | −0.08 ± 0.05 | 364 ± 8 | ||
Kaolinite [Fe3+]octa | 17.2 ± 0.3 | 0.36 ± 0.04 | 0.49 ± 0.04 | |||
Kaolinite [Fe3+]tetra | 3.5 ± 0.4 | 0.36 ± 0.04 | 0.88 ± 0.04 | |||
East Ayatskoye | Hematite | 74.2 ± 0.4 | 0.37 ± 0.04 | −0.22 ± 0.04 | 508 ± 1 | 5.12 |
Goethite | 1.0 ± 0.4 | 0.42 ± 0.04 | 0.06 ± 0.06 | 360 ± 9 | ||
Kaolinite [Fe3+]octa | 19.0 ± 0.6 | 0.37 ± 0.04 | 0.53 ± 0.04 | |||
Kaolinite [Fe3+]tetra | 2.4 ± 0.3 | 0.39 ± 0.04 | 1.33 ± 0.04 | |||
Kaolinite [Fe2+]octa | 1.3 ± 0.5 | 1.16 ± 0.04 | 2.59 ± 0.04 | |||
Siderite | 1.2 ± 0.2 | 1.35 ± 0.04 | 1.53 ± 0.04 | |||
Ilmenite | 0.9 ± 0.2 | 0.99 ± 0.04 | 0.90 ± 0.04 | |||
Arkalykskoye (A1) | Hematite | 75.8 ± 0.2 | 0.37 ± 0.04 | −0.22 ± 0.04 | 507 ± 1 | 5.73 |
Kaolinite [Fe3+]octa | 19.5 ± 0.9 | 0.36 ± 0.04 | 0.51 ± 0.04 | |||
Kaolinite [Fe3+]tetra | 2.7 ± 0.8 | 0.33 ± 0.04 | 1.34 ± 0.04 | |||
Ilmenite | 2.0 ± 0.3 | 0.98 ± 0.04 | 0.80 ± 0.04 | |||
Arkalykskoye (A2) | Hematite | 73.7 ± 0.2 | 0.37 ± 0.04 | −0.21 ± 0.04 | 508 ± 1 | 5.12 |
Goethite | 2.2 ± 0.2 | 0.42 ± 0.04 | −0.12 ± 0.04 | 374 ± 2 | ||
Kaolinite [Fe3+]octa | 18.7 ± 0.3 | 0.36 ± 0.04 | 0.51 ± 0.04 | |||
Kaolinite [Fe3+]tetra | 3.8 ± 0.3 | 0.35 ± 0.04 | 1.05 ± 0.04 | |||
Ilmenite | 1.5 ± 0.1 | 0.97 ± 0.04 | 0.69 ± 0.04 |
Deposit | d(104) | d(110) | d(300) | a, Å | c, Å |
---|---|---|---|---|---|
Ayatskoye | 2.698 | 2.513 | 1.453 | 5.033 | 13.736 |
Krasnooktyabrskoye | 2.695 | 2.510 | 1.453 | 5.028 | 13.677 |
Belinskoye | 2.696 | 2.511 | 1.453 | 5.027 | 13.746 |
East Ayatskoye | 2.690 | 2.505 | 1.451 | 5.023 | 13.727 |
Arkalykskoye (A1) | 2.693 | 2.510 | 1.452 | 5.020 | 13.719 |
Arkalykskoye (A2) | 2.689 | 2.505 | 1.450 | 5.022 | 13.726 |
Deposit | Average Particle Sizes, nm | |
---|---|---|
XRD | MS | |
Ayatskoye | 29 | 32 |
Krasnooktyabrskoye | 33 | 29 |
Belinskoye | 31 | 36 |
East Ayatskoye | 26 | 28 |
Arkalykskoye (A1) | 24 | 24 |
Arkalykskoye (A2) | 32 | 26 |
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Shokanov, A.; Vereshchak, M.; Manakova, I.; Migunova, A. Mössbauer and X-ray Diffraction Spectroscopy of High-Iron Bauxites from Kazakhstan. Materials 2023, 16, 6706. https://doi.org/10.3390/ma16206706
Shokanov A, Vereshchak M, Manakova I, Migunova A. Mössbauer and X-ray Diffraction Spectroscopy of High-Iron Bauxites from Kazakhstan. Materials. 2023; 16(20):6706. https://doi.org/10.3390/ma16206706
Chicago/Turabian StyleShokanov, Adilkhan, Mikhail Vereshchak, Irina Manakova, and Anastassiya Migunova. 2023. "Mössbauer and X-ray Diffraction Spectroscopy of High-Iron Bauxites from Kazakhstan" Materials 16, no. 20: 6706. https://doi.org/10.3390/ma16206706