Link between the Reactivity of Slag and the Strength Development of Calcium Aluminate Cement
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. Methods
3. Results
3.1. Chemical Reactivity of GGBS
3.2. Effect of Slags on CAC Paste and Mortar Properties
3.3. Correlation between Reactivity and Compressive Strength
3.4. Effect of Slag Reactivity on CAC Phase Assemblage
3.5. Effect of Slag on CAC Conversion Process
4. Discussion
5. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
Appendix A
Reactivity Index | Definition | Criteria | S1 | S2 | S3 | S4 | S5 |
---|---|---|---|---|---|---|---|
Basicity according to Tetmajer | - | 0.91 | 1.20 | 0.87 | 1.14 | 1.09 | |
German Standard for “Eisenportlandzement” | ≥1 | 0.90 | 1.04 | 0.81 | 1.04 | 0.97 | |
German Standard for “Hochofenzement” I | ≥1 | 1.06 | 1.22 | 0.96 | 1.20 | 1.16 | |
German Standard for “Hochofenzement” II | MnO | ≤5 wt% | 1.80 | 0.20 | 1.60 | 0.40 | 0.30 |
German Standard for special cements | ≥1 | 1.50 | 1.71 | 1.35 | 1.64 | 1.71 | |
F-value according to Keil | >1.5 | 1.31 | 1.63 | 1.22 | 1.54 | 1.58 | |
Reactivity according to De Langavant | - | 33.85 | 42.00 | 30.45 | 39.75 | 41.05 | |
Basicity according to Schwiete | - | 0.77 | 0.97 | 0.73 | 0.92 | 0.93 | |
Reactivity according to Wang | - | 1.48 | 1.68 | 1.31 | 1.62 | 1.66 | |
European Standards for cement and blast-furnace slag I | >1 | 1.18 | 1.38 | 1.05 | 1.34 | 1.33 | |
European Standards for cement and blast-furnace slag II | >67 wt% | 83.10 | 84.30 | 81.70 | 85.80 | 83.10 | |
F-value according to Ehrenberg | - | 1.29 | 1.60 | 1.16 | 1.52 | 1.52 |
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Property | Unit | S1 | S2 | S3 | S4 | S5 |
---|---|---|---|---|---|---|
SiO2 | % | 38.2 | 35.4 | 39.8 | 36.6 | 35.6 |
Al2O3 | % | 12.1 | 11.7 | 12 | 10.8 | 13.5 |
TiO2 | % | 0.6 | 0.6 | 1.4 | 0.5 | 1.2 |
MnO | % | 1.8 | 0.2 | 1.6 | 0.4 | 0.3 |
Fe2O3 | % | 0.3 | 0.5 | 0.8 | 0.3 | 0.5 |
CaO | % | 34.7 | 42.5 | 34.6 | 41.9 | 38.8 |
MgO | % | 10.3 | 6.4 | 7.3 | 7.3 | 8.7 |
K2O | % | 1.3 | 0.3 | 1 | 0.4 | 0.7 |
Na2O | % | 0.4 | 0.3 | 0.2 | 0.2 | 0.4 |
Na2O eq | % | 1.2 | 0.6 | 0.9 | 0.5 | 0.8 |
SO3 | % | 0.3 | 1.2 | 0.4 | 1.4 | 0.6 |
Chloride | % | nd | 0.14 | nd | nd | nd |
Sulphide (S2−) | % | 0.12 | 0.48 | 0.16 | 0.56 | 0.24 |
Moisture | % | 0 | 8.7 | 2.6 | 9.1 | 0.2 |
d50 | μm | 53 | 41 | 26 | 36 | 31 |
Fineness | cm2/g | 1768 | 2076 | 2668 | 2178 | 2407 |
Density | g/cm3 | 2.94 | 2.86 | 2.93 | 2.85 | 2.94 |
Compressive Strength, MPa | |||||
---|---|---|---|---|---|
6 h | 24 h | 7 d | 28 d | ||
Basicity according to Tetmajer (CaO/SiO2) | Pearson’s Corr. | 0.32 | −0.57 | 0.19 | 0.93 |
p-value | 0.30 | 0.16 | 0.38 | 0.01 | |
German Standard for “Eisenportlandzement” (CEM II-S) | Pearson’s Corr. | 0.31 | −0.34 | 0.30 | 0.85 |
p-value | 0.30 | 0.28 | 0.62 | 0.03 | |
German Standard for “Hochofenzement” I | Pearson’s Corr. | 0.20 | −0.41 | 0.72 | 0.86 |
p-value | 0.37 | 0.25 | 0.27 | 0.03 | |
German Standard for “Hochofenzement” II | Pearson’s Corr. | −0.18 | 0.74 | −0.24 | −0.84 |
p-value | 0.39 | 0.08 | 0.35 | 0.04 | |
German Standard for special cements | Pearson’s Corr. | −0.07 | −0.54 | 0.53 | 0.83 |
p-value | 0.46 | 0.18 | 0.18 | 0.04 | |
F-value according to Keil | Pearson’s Corr. | 0.04 | −0.63 | 0.40 | 0.88 |
p-value | 0.48 | 0.13 | 0.25 | 0.03 | |
Reactivity according to De Langavant | Pearson’s Corr. | 0.05 | −0.58 | 0.43 | 0.87 |
p-value | 0.47 | 0.15 | 0.24 | 0.03 | |
Basicity according to Schwiete | Pearson’s Corr. | 0.17 | −0.66 | 0.29 | 0.91 |
p-value | 0.39 | 0.11 | 0.32 | 0.02 | |
Reactivity according to Wang | Pearson’s Corr. | −0.01 | −0.47 | 0.51 | 0.84 |
p-value | 0.49 | 0.21 | 0.19 | 0.04 | |
European Standards for cement and blast-furnace slag I | Pearson’s Corr. | 0.11 | −0.46 | 0.43 | 0.86 |
p-value | 0.43 | 0.22 | 0.23 | 0.03 | |
European Standards for cement and blast-furnace slag II | Pearson’s Corr. | 0.52 | 0.01 | 0.20 | 0.60 |
p-value | 0.19 | 0.50 | 0.37 | 0.14 | |
F-value according to Ehrenberg | Pearson’s Corr. | 0.13 | −0.54 | 0.37 | 0.90 |
p-value | 0.41 | 0.18 | 0.27 | 0.02 | |
6 h Heat, J/g SCM (R3 test) | Pearson’s Corr. | 0.75 | −0.24 | −0.39 | 0.84 |
p-value | 0.07 | 0.35 | 0.26 | 0.04 | |
24 h Heat, J/g SCM (R3 test) | Pearson’s Corr. | 0.84 | −0.10 | −0.46 | 0.73 |
p-value | 0.04 | 0.43 | 0.22 | 0.08 | |
3 d Heat, J/g SCM (R3 test) | Pearson’s Corr. | 0.84 | 0.07 | −0.47 | 0.62 |
p-value | 0.04 | 0.46 | 0.21 | 0.13 | |
7 d Heat, J/g SCM (R3 test) | Pearson’s Corr. | 0.81 | 0.18 | −0.46 | 0.55 |
p-value | 0.05 | 0.39 | 0.22 | 0.17 | |
Bound water content, % (R3 test) | Pearson’s Corr. | 0.97 | 0.05 | −0.77 | 0.41 |
p-value | 0.00 | 0.47 | 0.07 | 0.25 | |
CaO/Al2O3 | Pearson’s Corr. | 0.81 | −0.15 | −0.22 | 0.68 |
p-value | 0.05 | 0.40 | 0.36 | 0.10 | |
CaO | Pearson’s Corr. | 0.48 | −0.53 | 0.06 | 0.90 |
p-value | 0.21 | 0.18 | 0.46 | 0.02 | |
Al2O3 | Pearson’s Corr. | −0.92 | −0.37 | 0.53 | −0.16 |
p-value | 0.01 | 0.27 | 0.18 | 0.40 | |
SiO2 | Pearson’s Corr. | 0.05 | 0.57 | −0.48 | −0.86 |
p-value | 0.47 | 0.16 | 0.20 | 0.03 | |
Moderate correlation | |||||
High correlation | |||||
Strong correlation |
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Skočibušić Pejić, J.; Bašić, A.-D.; Grubor, M.; Serdar, M. Link between the Reactivity of Slag and the Strength Development of Calcium Aluminate Cement. Materials 2024, 17, 3551. https://doi.org/10.3390/ma17143551
Skočibušić Pejić J, Bašić A-D, Grubor M, Serdar M. Link between the Reactivity of Slag and the Strength Development of Calcium Aluminate Cement. Materials. 2024; 17(14):3551. https://doi.org/10.3390/ma17143551
Chicago/Turabian StyleSkočibušić Pejić, Josipa, Alma-Dina Bašić, Martina Grubor, and Marijana Serdar. 2024. "Link between the Reactivity of Slag and the Strength Development of Calcium Aluminate Cement" Materials 17, no. 14: 3551. https://doi.org/10.3390/ma17143551