A Polymethionine Nanoparticle Fluorescent Probe for Sensitive Detection of Naringin and Naringenin
Abstract
:1. Introduction
2. Experimental Section
2.1. Materials
2.2. Synthesis of the PMNPs
2.3. Characterizations
2.4. General Procedure for NRG and NRGe Sensing
2.5. Analysis of NRG and NRGe in Citrus Fruits Samples
3. Results and Discussion
3.1. Characterization of PMNPs
3.2. Stability Studies of PMNPs
3.3. Fluorescence Sensing of NRG and NRGe Based on the PMNPs Probe
3.4. Selectivity of the Sensing System
3.5. Fluorescence Quenching Mechanism
3.6. Practical Application in Real Samples
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Method | Probe | Linear Range | LOD | Reference |
---|---|---|---|---|
HPLC | - | - | 0.2 μmol/L (LOD) | [17] |
Electrochemical Method | - | - | 0.55 μmol/L (LOD) | [25] |
Photo-electrochemistry | CPPI-TiO2/CdS/FTO | 1~332 μmol/L | 0.03 μmol/L (LOD) | [21] |
Electrochemistry Method | Hanging mercury drop electrode | 0.172~68.8 μmol/L | 0.05 μmol/L (LOD) | [22] |
Fluorescence method | PMNPs | 1~200 μmol/L | 0.33 μmol/L (LOD) | [This work] |
Method | Probe | Linear Range | LOD | Reference |
---|---|---|---|---|
HPLC | - | - | 1.286 μmol/L (LOD) | [17] |
Electrochemical method | - rGO/GSH/GCE | 10~1200 μmol/L | 3.33 μmol/L (LOD) | [24] |
Fluorescence method | PMNPS | 1~200 μmol/L | 0.83 μmol/L(LOD) | [This work] |
Samples | τ1 (ns) | τ2 (ns) | B1 | B2 | τavg (ns) |
---|---|---|---|---|---|
PMNPs | 0.9191 | 6.5754 | 975.2305 | 519.9597 | 5.4 |
PMNPs + NRG | 0.6949 | 6.1699 | 1081.1244 | 417.5455 | 4.93 |
PMNPs + NRGe | 0.8548 | 6.4076 | 1042.3488 | 454.1409 | 5.10 |
Samples (%) | Detected (μΜ) | Added (μΜ) | Found (μΜ) | Recovery (%) | RSD | |
---|---|---|---|---|---|---|
Grapefruit peel | NRG | 12.4 | 2.5 | 14.85 | 102.0 | 3.4 |
5.0 | 17.55 | 103.0 | 4.6 | |||
10.0 | 22.48 | 99.2 | 4.3 | |||
NRGe | 8.26 | 5.0 | 13.28 | 100.4 | 4.4 | |
10.0 | 18.16 | 99.0 | 3.2 | |||
20.0 | 27.10 | 94.2 | 4.5 | |||
Orange juice | NRG | 1.23 | 2.5 | 3.78 | 102.0 | 2.4 |
5.0 | 6.16 | 98.6 | 1.8 | |||
10.0 | 11.19 | 99.6 | 1.5 | |||
NRGe | 2.63 | 5.0 | 7.52 | 97.8 | 3.2 | |
10.0 | 12.42 | 97.9 | 4.2 | |||
20.0 | 21.03 | 92.0 | 3.8 |
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Jiao, Y.; Li, L.; Ge, J.; Tai, Y.; Han, H. A Polymethionine Nanoparticle Fluorescent Probe for Sensitive Detection of Naringin and Naringenin. Materials 2024, 17, 3919. https://doi.org/10.3390/ma17163919
Jiao Y, Li L, Ge J, Tai Y, Han H. A Polymethionine Nanoparticle Fluorescent Probe for Sensitive Detection of Naringin and Naringenin. Materials. 2024; 17(16):3919. https://doi.org/10.3390/ma17163919
Chicago/Turabian StyleJiao, Yuhong, Lu Li, Jinlong Ge, Yanfang Tai, and Hui Han. 2024. "A Polymethionine Nanoparticle Fluorescent Probe for Sensitive Detection of Naringin and Naringenin" Materials 17, no. 16: 3919. https://doi.org/10.3390/ma17163919