Waste for Product—Synthesis and Electrocatalytic Properties of Palladium Nanopyramid Layer Enriched with PtNPs
Abstract
:1. Introduction
2. Materials and Methods
2.1. Reagents
2.2. Method of Analysis
3. Results
3.1. Process of Metal Recovery from Synthetic Waste Solution and Catalyst Synthesis
3.1.1. Pd(II) and Pt(IV) Adsorption on Active Carbon Pellets (ROY 0.8)—Kinetic Study
3.1.2. Raman Analysis of ROY, Pd@ROY, Pt@ROY, and Pd-Pt@ROY
3.1.3. IR Analysis
3.1.4. Thermal Gravimetric Analysis of the Obtained Catalyst
3.1.5. SEM/EDS Analysis
3.1.6. Wettability Tests
3.1.7. XRD Analysis
4. Electrocatalytic Properties of Obtained Materials for the Hydrogen Evolution Reaction
5. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Samples | |||
---|---|---|---|
Pd@ROY | Pt@ROY | Pd-Pt@ROY | |
Rate constant, min−1 | 0.195 | 0.238 | 0.278 |
Sample | ID/IG | ID2/IG2 | La ID/IG | La ID2/IG2 |
---|---|---|---|---|
a.u. | a.u. | nm | nm | |
ROY | 1.271 | 1.013 | 15.13 | 18.98 |
Pt@ROY | 1.256 | 1.013 | 15.31 | 19.22 |
Pd@ROY | 1.228 | 0.953 | 15.66 | 20.18 |
Pd-Pt@ROY | 1.207 | 0.827 | 15.93 | 23.25 |
Plane | Sample | 2 Θ, ° | |
---|---|---|---|
Experimental | ICDD Cards/Ref. | ||
Pt | 39.956 1 | ||
(1 1 1) | Pt-Pd@ACF | 40.035 | [4] |
Pd-Pt@ROY | 40.042 | This work | |
Pd | 40.47 2 | ||
Pd@ACF | 40.110 | [4] | |
Pd@ROY | 40.333 | This work | |
Pt | 46.472 1 | ||
(2 0 0) | Pt-Pd@ACF | 46.629 | [4] |
Pd-Pt@ROY | 46.621 | This work | |
Pd | 46.88 2 | ||
Pd@ACF | 46.684 | [4] | |
Pd@ROY | 46.855 | This work |
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Luty-Błocho, M.; Pach, A.; Kutyła, D.; Kula, A.; Małecki, S.; Jeleń, P.; Hessel, V. Waste for Product—Synthesis and Electrocatalytic Properties of Palladium Nanopyramid Layer Enriched with PtNPs. Materials 2024, 17, 4165. https://doi.org/10.3390/ma17164165
Luty-Błocho M, Pach A, Kutyła D, Kula A, Małecki S, Jeleń P, Hessel V. Waste for Product—Synthesis and Electrocatalytic Properties of Palladium Nanopyramid Layer Enriched with PtNPs. Materials. 2024; 17(16):4165. https://doi.org/10.3390/ma17164165
Chicago/Turabian StyleLuty-Błocho, Magdalena, Adrianna Pach, Dawid Kutyła, Anna Kula, Stanisław Małecki, Piotr Jeleń, and Volker Hessel. 2024. "Waste for Product—Synthesis and Electrocatalytic Properties of Palladium Nanopyramid Layer Enriched with PtNPs" Materials 17, no. 16: 4165. https://doi.org/10.3390/ma17164165