1. Introduction
Environmental and ecological changes have put various marine species at risk of extermination and poses a real threat to biodiversity. Several species in coastal areas are vulnerable to climate change and environmental pollution. Similar circumstances are also applicable for human beings. Frequent monitoring and observation of various water parameters are required to maintain the high water quality levels that are necessary for living beings. An appropriate range for various water parameters can be identified as a key performance indicator (KPI), for the water quality, particularly for a geographic location [
1,
2,
3]. Water is an unavoidable requirement of livelihood for billions of people all over the world, due to industrialization, the massive growth in population, excessive use of chemicals for agricultural activities, reclamation of land, and oil spillage into the water, and it is being contaminated at an alarming rate which is now a matter of concern. Therefore, it is important to monitor and test water quality real-time on a regular basis to take necessary steps in order to reduce water pollution and control the quality of water whenever it is necessary. The accessibility of quality water is essential for disease control and for enhancing health.
Natural impurities caused by weathering and the decay of marine organisms and various manmade activities introduce impurities in the water, like iron, lead, chromium, and even radioactive uranium [
4,
5]. A set of standards for both surface and drinking water which are established and regulated by the authority of a country, clearly state the limits of the potential of hydrogen (pH), dissolved oxygen (DO), alkalinity, ORP, conductivity, and salinity to maintain a high quality of water. Standards are different from country to country due to differing geographical locations [
6]; however, a standard is not yet well established for Fiji. Henceforward, it is necessary to classify and define the exact values of the parameters for various sources of water available here in Fiji, and this case study will partially address this issue. The Fiji National Drinking Water Quality Standards (FNDWQS) [
3] state that the frequency of measurement for water parameters of the local water supply occur be on a daily basis, which is currently being conducted using portable/mobile testing tools or by the water samples being brought to a central laboratory test water quality parameters, which is obviously not a convenient method. The islands are scattered and therefore there is a need for a robust monitoring device that could provide real-time data and inform stakeholders of any undesired activities impacting on water quality.
The experiment in this research setup has been carried out in Fiji’s capital city (Suva) and Sigatoka, due to locality and ease of access. The challenges that lead to the development of such technologies mainly involve the availability of resources in remote places. To conduct water testing in islands with the present situation and technology available here in this country is quite challenging as the samples need to be brought in every hour or two and have analysis performed on them in Suva. In Fiji, there are not many such technologies or devices available that can investigate the quality of water being supplied to each household. While, people can use water filters as a precaution to ensure safe health, this is an expensive approach for persons with normal middle incomes, so the major sources of drinking water in Fiji are either bore-hole or supplied tap water. The Water Authority of Fiji (WAF) normally performs the water quality test before the water is pumped out to the consumers, but there are still uncertainties regarding the water quality on the consumer end side.
Accordingly, there is a requirement for further improvement of a network based, automated, real-time water quality measurement system that can deliver instant information of the local water quality and also help in controlling the quality of water for different applications ranging from aquaculture farmhouses and coastlines to articulated reservoirs. The proposed system in this research has been designed based on Internet of Things (IoT) [
7] integrated with a wireless sensor network that is not only able to sense various water quality parameter remotely but also able to investigate and provide water quality KPIs information in real-time progressively utilizing GIS. The fundamental objective of this GIS integration and sensor-based water monitoring system is the automation of the measurement of the KPIs [
8] of surface water, resulting in improved reliability and performance. This system will further simplify the respective tasks involved by the various interested parties (i.e., the Water and Environment Management Authority) within the scope of water quality management [
9,
10,
11,
12]. This proposed system enables automated measurement of KPIs at various sites at regular intervals to have reliable quality assurance. Moreover, this sensor-based GIS integrated Smart Water Quality Monitoring System (SWQMS) helps to monitor water quality from a central workbench and provides access to the information whenever required by the various respective stake holders.
Figure 1 shows the schematic of the SWQMS working principle for the experimental setup used here in Fiji to monitor surface water quality during this case study.
The structure of this article is as follows:
Section 2 introduce the KPIs modeling for a specific water quality monitoring system, in
Section 3 the proposed SWQMS is illustrated in detail,
Section 4 presents the GIS interface design, results and discussion are presented in
Section 5, and lastly
Section 6 presents the conclusion.
2. A KPI Design for Water Quality
Suva is the capital and a major port of Fiji Island in the center of the country surrounded by the Pacific Ocean. The city has a population of 263,670 within its 790.5 sqmi (2048 sq. km) area [
13]. The majority of the population live around the coastal area and depend on ocean and coastal resources for their livelihoods. The tourism sector, which is an economic driver of the country, is dependent on good coastal water quality to support healthy corals and marine biodiversity. Sigatoka as a coastal town and a hub for tourism activities is the other location in this case study, which is located 125 km west from Suva. The Water Authority Fiji (WAF) manage and regulate the water supply, utilizing ground water and surface sources like river as sources for their water services nationwide.
Figure 2 shows the geographical location of Fiji. Temperature exerts a major influence on biological activity and growth in our atmosphere. It is also a vital parameter because of its effect on water chemistry, as shown in
Figure 3. The solubility of minerals usually escalates at a higher temperature. Water with higher temperatures can dissolve more minerals and will therefore have a higher concentration of inorganic ions or Total Dissolved Substances (TDS), resulting in higher conductivity. Warm water holds less dissolved oxygen (DO) than cold water and may not contain enough DO for the survival of diverse species of marine life. Water temperature must be measured every time water is sampled and investigated, no matter where it is being studied [
14].
Commonly used basic water quality monitoring parameters are temperature, pH, conductivity, turbidity, and DO [
15]. DO is the free oxygen in water necessary to sustain life. However, any increase in the microbial decomposition of organic matter in water bodies due to pollution leads to DO depletion. Oxidation-reduction potential (ORP) is measured in addition to DO as there are other chemical elements apart from oxygen that affect the oxidative capacity of rivers and lakes and provide additional information on the water quality and the degree of pollution. ORP is a measure of reducing or oxidizing potential that governs the biochemical processes in water and is an important monitoring parameter in drinking water and waste water processes and applications. ORP measurements are an indication of some oxidation- reduction reactions such as the corrosion of distribution pipes in drinking water systems, precipitation of iron and manganese compounds, nitrification and denitrification reactions, and microbial disinfection. ORP measurements are becoming a widespread parameter to monitor disinfection through chlorination in drinking water, and show that ORP is affected by pH as well [
16]. There is a strong positive correlation between DO and ORP, and higher values create an optimum environment for nitrogen removal and enhanced microbial activity to break down organic matter [
17]. It is apparent that for water quality monitoring, DO, ORP, and pH should be measured in conjunction. DO measures “residual oxygen” which is instantaneously available at a short period of time. However, ORP measures a kind of cumulative longer-term potential value. So for a continuous measurement, ORP is a much more reliable parameter to avoid any mislaid interpretation from the long-term measurement value of DO. To categorize the water quality pH, conductivity and ORP have been considered as important parameters in this research and were selected as KPIs for the comparison. Afterwards, a quality level is established to determine whether the water sample is polluted or non-polluted with the specific KPI range for the tested water samples. DO could be included in the suite of measurements in future, as there are additional channels that could be utilized. However, for the current measurements, the sites chosen such as Sigatoka, Rewa River, and Nabukalou Creek in Suva are all subjected to wastewater discharge, and perhaps ORP would be a better indicator for industrial and wastewater pollution.
Figure 4 shows the schematic system architecture of the proposed SWQMS. FNDWQS [
3,
18], defined the pH ranges from 6.5 to 8.5 for drinking water with a temperature of 4 °C. However, since the SWQMS system of this research works in real-time, therefore the temperature is used as a dynamic parameter which is directly co-related to the other KPIs. The first essential task was to identify the water parameters that can provide an indication of water contamination through an extensive review and research [
19,
20]; the parameters were selected to be composed of pH, ORP, conductivity, and temperature.
Table 1 provides a brief description of four KPIs chosen in this research and the accepted levels are obtained from a set of empirical results with various sources of surface water from Fiji during summer.
3. System Design
The system was comprised of a Waspmote V1.2 microcontroller board [
23], water sensors, a SIM-900 GPRS/GSM module, and a GIS for interface and monitoring. The overall system is represented by
Figure 5, while
Figure 6 presents the GIS Node location for KPI measurement around the Fiji Islands. The SWQMS also has an analog to digital converter (ADC), a data storage card, and a GSM module.
Furthermore, as the setup needs to work for a long time, power preservation is essential. To conserve the power, this system used a sleep mode operation around reading intervals of 1 h. To extend battery life, a rechargeable Lithium-ion battery was used and the power supply was provided by a Photovoltaic (PV) system, as shown in
Figure 7, while the specifications of the PV system are given in
Table 2. To design a stand for SWQMS, a PV array with two strings characterized by a rated current of 2 A was used. Each string was subdivided into 11 modules characterized by a rated voltage of 1.2V and connected in series. Thus, the total output voltage of the PV array was 13.2 V, and its output had a current of 2 A. The value of the DC-link capacitor was 25 μF, the line resistance 0.001 Ω and inductance was 0.2 μH. The power supply system was simulated and designed under atmospheric conditions, for which the values of solar irradiation and temperature needed to be 1 kWm
−2 and 298 K, respectively, to charge a lithium-ion battery of 12 V. The PV system was integrated from the concept of previous research done by references [
24,
25].
The Waspmote architecture is based on the Atmega 1281, an eight (8) bit microcontroller for the SWQMS. The boot loader binary was executed by this microcontroller, which is stored in the FLASH memory. This enables the main program created by the user to be run. There are seven (7) analog inputs for the sensors which are connected to the microcontroller. Within the microcontroller lies a 10 bit successive approximation ADC. Furthermore, there are several digital pins which can be configured to act as either inputs or outputs when 0 V is low and 3.3 V is high.
Figure 8 highlights the microcontroller, sensory sockets, and radio sockets along with other features.
The GSM device uses a sim900 (provided by Simcon) as its baseband engine and as a communication module. It is a quad-band engine working with GSM 850 MHz, EGSM 900 MHz, DCS 1800 MHz, and PCS 1900 MHz. Furthermore, it has very small constructions where the dimensions are 24 mm × 24 mm × 3 mm to keep the design compact. The sim 900 is integrated with TCP/IP protocols, which is one of the most flexible forms of data transmission.
Figure 9 presents a block diagram of Sim 900 showing the primary functions which are the radio frequency, baseband engine, and the flash memory along with other interfaces. Four (04) different types of sensors have been utilized for this SWQMS to measure the water quality in this case study, which is detailed later in this section, and the SWQMS setup is shown in
Figure 10.
The Waspmote architecture is based on the Atmega 1281, an eight (8) bit microcontroller for the SWQMS. The boot loader binary is executed by this microcontroller, which is stored in the FLASH memory. This enables the main program created by the user to be run. There are seven (7) analog inputs for the sensors which are connected to the microcontroller. Within the microcontroller lies a 10-bit successive approximation ADC. Furthermore, there are several digital pins which can be configured to act as either inputs or outputs when 0 V is low and 3.3 V is high.
Figure 8 highlights the microcontroller, sensory sockets, and radio sockets along with other features.
3.1. Temperature Sensor
The SWQMS uses a PT1000 sensor for its temperature measurements. The PT1000 sensor generally has a linear relationship over a small temperature range. In this research, the temperature range for sensing is 0–100 °C, which will provide a linear relationship between temperature and resistance as shown below in Equation (1).
where A = 3.9083 × 10
−3 °C, B = −5.775 × 10
−7 °C, and
R0 is the temperature at 0 °C.
The temperature sensor is used in a voltage divider configuration with a 1 K ohm resistor, hence
Vt can be obtained using Equation (2) as follows:
This is then amplified by an instrumental amplifier with a gain of 11 and fed to a 24 bit ADC.
Figure 11 below shows a summarized model of the temperature sensors.
3.2. Conductivity Sensor
The SWQMS also uses a conductivity sensor. The sensor has two (2) electrode types, which were constructed using platinum. This sensor determines the conductivity of a solution by applying a small AC current through the solution. An AC signal is used to avoid polarization of the platinum electrodes.
Conductivity can be calculated using ohms law, shown here as Equation (3). Since the supply to the electrodes is an AC current, the voltage can be measured between the two electrodes and hence the resistance of the solution can be found.
where
R is the resistance of the solution. Conductance (
G) can also be found using the Equation (4).
Finally, the conductivity of the solution can be calculated using the cell constant obtained from the calibration process. This constant is specified in the manufacturer’s datasheet [
21]; but it is advised to carry out the calibration using a solution of known resistivity using Equation (5).
where
k = conductivity (S/cm),
G = conductance (S), and where
G = 1/R and
K = cell constant (cm
−1). A summarized model of the conductivity sensor is described below in
Figure 12.
3.3. PH Sensor
This research exercises the use of a combination electrode to measure the pH of a solution. Since the design and operation of the pH sensor used in the SWQMS are very complex, it is necessary to understand the potential between the two (2) electrodes and how it is interpreted. The pH value can be obtained by the negative logarithm of the H+ in a given solution (pH = log aH+). This value of pH needs to be converted into a voltage signal using the following the Equation (6) to obtain the sensor’s output.
where Nernst factor is
,
E = measured potential (mV),
T = Temperature in
K, and
F = the Faraday constant (96,485 C mol
−1);
As the voltage produced by the electrodes has a linear relationship to the pH of the solution, at the reference pH of 7, the potential between the electrodes is 0 V. At an acidic or low pH level, the potential between the electrodes is linear. Likewise, at a high pH, the potential between the electrodes will be at the opposite polarity. The overall working principle of the pH sensor can be seen in the following mathematical model shown in
Figure 13.
3.4. ORP Sensor
The oxidation Reduction Potential (ORP) sensor is the other types of sensor that used for SWQMS in a similar manner to that of the pH sensor. The sensor consists of two electrodes, a reference electrode and an ORP electrode. It uses inert metals (platinum in this case) which give up or accept electrons for an oxidant/reductant. This is done until a potential outcome is developed that is linear to the ORP of the solution. There is no unit conversions done since the potential is already in mili volt (mV). The electrode behavior is defined by the Nernst equation shown in Equation (7):
where
E0 = measured potential (mV) at a concentration of
Cox = Cred;
R = universal gas constant;
n = electrical charge of the ion,
Cox = oxidant concentration in moles/L, and
Cred = reductant density in moles/L.
5. Result and Discussion
The experimental setup has been established in different location of the Fiji Islands (i.e., Suva City and the Sigatoka Coastal area; as shown in
Figure 6) using five nodes and a GIS interface to study the water quality parameters. Different sources and locations were used to conduct the research (i.e., Marine, Coastal, River, Creek and Tap) for aforementioned KPIs (i.e., Temp., pH, Conductivity, and ORP; as shown earlier in
Table 1). The measurements were taken within 1 foot of water depth from the surface. Geographic information system within the experimental setup allows the user to access the data necessary from any location through the internet. However, this section will discuss the statistical analysis of the data collected during the experiment to measure the reliability/efficiency of the proposed SWQMS.
KPIs data from all the nodes were analyzed, which demonstrates the fundamental co-relation between KPIs, for instance, temperature has a linear positive co-relationship to oxidation-reduction and also with the conductivity, but a linear negative co-relationship to pH. The results also showed consistency with a slight deviation, which was found to be the impact of peripheral variables (i.e., high/low tide).
Table 4 presents the Mean and Standard Deviation (SD) of the four parameters/KPIs measured for a different type of waters. It has been observed that the average temperature measured during the investigation period varies from a minimum of 25.39 °C found in creeks to a maximum of 26.22 °C found in rivers. An analysis of variance test was used and found that the variation of the temperature in different water is significant (
p < 0.001). The difference range observed in temperature is very minimal or can be explained by any other KPIs. Temperature can be defined as a quantity of the average thermal energy of an element [
29]. This energy can be shifted between elements as the movement of heat. Heat transfer, whether, from light, another water source, or pollution such as hot water discharge can change the water’s temperature [
22]. The Nabukalou creek is a one of the most polluted waterbodies in the city and a low temperature rules out any thermal pollution. Its low temperature could be attributed to large buildings alongside the creek providing some shade from direct sunlight, whereas other sites are exposed to direct sunlight.
Standard deviation for temperature and conductivity for all sources were varied on three decimal point and rounding off gives the same values as those shown in
Table 4.
pH was found to be different in different sources of water (
p < 0.001). The maximum pH was found in marine water (Mean = 8.54, SD = 0.10) and the minimum was obtained in river water (Mean = 7.39, SD = 0.10). The pH value of marine water responds to the following changes: dissolved CO
2 concentrations, alkalinity, hydrogen ion concentrations, as well as slightly due to temperature changes. The pH values obtained for different water sources were within the typical range, particularly for seawater where the modeled pH values were 8.08–8.33 [
30]. The pH of the river was comparable to the pH of 7.22 obtained for Chao Phraya River, Bangkok, Thailand, which is more polluted than Rewa River. The intrusion of saltwater into Nabukalou Creek could slightly elevate the pH. However, the pH of a water system is greatly affected by the natural buffer or alkalinity of the water body, and alkalinity was not measured in this project to account for differences in pH for different water sources.
Variation in conductivity was found to be statistically different (
p < 0.001) with the minimum found in the creek (Mean = 44.21, SD = 0.50) and the maximum found in the river (Mean = 70.22, SD = 0.50). Surprisingly, the conductivity of the Nabukalou Creek is low despite the fact that the creek has poor water quality status with large inter-annual variability in the parameters monitored [
31]. Despite sewage and industrial effluent being discharged into the creek, it still shows that ion concentrations are diluted with a large amount of rainfall decreasing the TDS, hence decreasing the conductivity. There have been studies that approximate TDS from conductivity measurements, but the relationship is not always linear and is affected by salinity levels [
32]. However, for the natural creek waters, it should be relatively simple to approximate TDS from conductivity [
32]. Sea water normally records higher conductivity than freshwater. In contrast, the Rewa river recorded the highest conductivity. The plausible explanation for this observation could be that there is some mixing of freshwater with salt water, and this could have been confirmed by salinity measurements. The other reasons could be that Rewa River runs through the agricultural plains and therefore experiences agricultural run-off, dissolution of ions from nearby rocks, and wastewater discharge and waste disposal into the river.
Variation in ORP is found with the minimum in the creek (Mean = −0.73, SD = 0.07) and the maximum in tap water (Mean = 321.48, SD = 9.75). The ORP level will govern which reactions are prevalent along with the DO and pH levels. Research data reveals that mineral waters, including tap water, have an ORP of +200 MV to +400 MV [
33]. The tested tap water falls within this range and suggest that it is an oxidizing condition and that there is lots of oxygen present, probably due to the small amount of organic matter and even smaller amount of microbial activity due to effective chlorination disinfectant processes. The ORP is on the lower side at the marine site, probably due to the presence of high organic matter, resulting in decomposition and therefore reducing the DO. An interesting feature of ORP measurements is the negative values observed at the Nabukalou creek suggesting a reduced environmental quality due to pollution. This confirms the findings of other studies that found high levels of fecal coliforms and nutrients from human discharge and industrial wastewater in the creek. Obtaining a negative value for Nabukalou creek increases the confidence of the data obtained from SWQMS. The data measured for polluted water provides an ORP of around −2 mV and conductivity within a 42–45 mS/cm range, which indicates that the sample water is polluted. It was expected as the water sample was collected from Node-1 (Nabukalou Creek having waste lines (Sewage) connected to the creek). A summary is given in
Table 4 for all other nodes used in this case study.
A different set (Node-3; Sigatoka coastal water) of data for all KPIs were analyzed and presented in this section to validate the system reliability and sensitivity. The experiment was conducted over the course of a month. The starting date of the experiment was 7 December 2015 and the experiment were concluded on 6 January 2016. The following graphs in
Figure 14 shows the average hourly (from hours 1–24) variations of the values of four KPIs/parameters during the investigation period within an interval of 5 min every hour in a particular day and only average hour readings from one (1) day are shown here as a reference in
Table 5.
The data highlighted that there were little variations in pH, conductivity, and ORP readings over the 24 h period and therefore it could be concluded that the sensors were reliable. Conductivity values were observed in the range of 50.3–51.95, pH values had the range 8.4–8.7, and ORP was observed in the range of 232–252 mV. These all show signs of healthy water according to research gathered [
3,
18,
19,
20].
Figure 15 and
Table 6 show the temperature relationship with pH, conductivity, and ORP for a particular day, which confirms the trends that they follow a linear positive or negative co-relation inclined with the theories. More specifically, conductivity is strongly positively correlated with temperature in all types (04) of water. pH is strongly negatively correlated with temperature in all types (03) of water, except in creek water. ORP has no significant correlation with temperature except for the creek water in this case study.
Predictions of conductivity (y1), pH (y2) and ORP (y3) for a given temperature have also been modeled that can be used in further applications. However, for predicting the conductivity, pH, and ORP, the following
Table 7 presents the best model found using the regression analysis.
Table 7 also presents the predicted values of conductivity, pH, and ORP when the temperature of the day was observed at 25 °C.
Through the 30 days deployment, the results observed had fluctuations, however this was anticipated since tidal behavior was not expected to carry over from day-to-day. Furthermore, the KPI parameters behavior was mostly influenced by temperature. The 30 days results were measured with a daily average reading for a month at Node-3 (Sigatoka coastal water) and tabulated in
Table 8.
Table 9 presents the correlation between daily average KPIs data for all four (04) types of water. Conductivity values are strongly positively correlated with temperature for all types of water. It is observed that pH was strongly negatively correlated with temperature for all types of water. Although it was observed that the ORP parameter had no correlation with temperature for any types of water that are used in this case study, it is still recommended that one calibrates an ORP sensor before any critical measurements and uses multiple ORP sensors to cross-reference or conduct further research with other measurements such as sulfides or nitrates. As the values of correlations are the same for all three (03) types of water, except for the ORP in creeks, the results in
Table 9 also presents these values with changes of temperature, the rate of change of conductivity, and pH in any types of water at the same ratio, while ORP does not follow this phenomenon.
The relationship with temperature is seen to be consistent throughout the deployment duration and also confirms the temperature relation theories explained earlier in this paper. Scatter plot results of 30 days trial at Node-3 (Sigatoka coastal water) are shown in
Figure 16 which shows that the conductivity and ORP maintain a linear positive co-relationship with temperature but pH showed a linear negative co-relationship with temperature change that again validates SWQMS reliability.
6. Conclusions
In the SWQMS, sensor data has been interfaced with GIS, and four (04) different sources of water samples were monitored in real-time measuring four (04) KPIs in this case study conducted in the Fiji Islands. This paper also presents the use of REs to supply the power for the SWQMS. Finally, the developed system has been tested and validated based on a Case Study for Fijian surface water. The data obtained for tap water are consistent with the FNDWQS and therefore increases confidence in the reliability and accuracy of the measurements. In addition, the daily measurements for a month and diurnal data show very little variability, which re-affirms the reproducibility of the data and rules out any sensor fouling in field conditions for a month. The sensors were calibrated before deployment, but for future work it is imperative for external verification and validation of sensors to be undertaken. Water from different sources (creek, sea, river, and tap) were studied and the correlation between all the KPIs was observed utilizing several nodes.
The system demonstrated its usefulness by providing precise and reliable data/information throughout the experiment. SWQMS with GIS platforms used to monitor water quality in real-time provided a suitable answer for several PICs to improve the performance of the water management system. Although all of this information is currently not available in the public domain, over the next several years the SWQMS for Fiji Islands will continue to improve its public web maps and query tools to provide this data/information to the public, watershed stakeholders, and state and local governments. Consequently, SWQMS for Fiji Islands will better inform decisions to check, control, and reduce water pollution in the country. SWQMS is a unique technology designed to provide high-quality water parameter monitoring using renewable (PV) energy for the Pacific nations.
This SWQMS can be integrated with a cloud computing system for robust water quality monitoring in the future with a few more sensors added for DO, salinity, and nitrate. This designed SWQMS can be connected to the live cloud server with the help of the Internet of Things (IoT) and can access necessary information in real-time to effectively maintain water quality.