Cr(VI) Adsorption from Aqueous Solution by UiO-66 Modified Corncob
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. Synthesis of UiO-66 Modified Corncob
2.3. Characterization
2.4. Adsorption Experiments
2.5. Data Analysis
3. Results and Discussion
3.1. Characterization of UiO-66 Modified Corncob
3.2. Adsorption Kinetics
3.3. Cr(VI) Adsorption Equilibrium
3.4. Effects of Solution Chemistry
3.5. Regeneration Studies
3.6. Adsorption Mechanism of Cr(VI)
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Adsorbents | qe,exp (mg/g) | Pseudo-First-Order Model | Pseudo-Second-Order Model | Intra-Particle Diffusion Model | ||||||
---|---|---|---|---|---|---|---|---|---|---|
K1 (min−1) | qe,calculated (mg/g) | R2 | K2 | qe,calculated (mg/g) | R2 | kpi (mg/(g·min0.5) | c | R2 | ||
(g/(mg·min)) | ||||||||||
UiO-66@Corn+ | 30.621 | 0.003 | 8.802 | 0.813 | 0.002 | 31.056 | 1.000 | 0.540 | 15.473 | 0.550 |
UiO-66@Corn− | 12.166 | 0.002 | 4.180 | 0.665 | 0.003 | 12.110 | 0.999 | 0.231 | 5.275 | 0.657 |
Adsorbents | Langmuir Model | Freundlich Model | Langmuir–Freundlich Model | |||||||
---|---|---|---|---|---|---|---|---|---|---|
KL (L/mg) | qm (mg/g) | R2 | 1/n | KF (L/g) | R2 | Qg (mg/g) | KLF (L/mg) | n | R2 | |
Corn+ | 0.053 | 60.232 | 0.993 | 0.452 | 6.944 | 0.950 | 54.971 | 0.066 | 1.175 | 0.994 |
UiO-66 | 0.031 | 109.88 | 0.990 | 0.484 | 9.334 | 0.961 | 102.00 | 0.037 | 1.115 | 0.989 |
UiO-66@Corn+ | 0.032 | 90.038 | 0.993 | 0.565 | 5.810 | 0.975 | 84.940 | 0.037 | 1.059 | 0.992 |
UiO-66@Corn− | 0.066 | 22.383 | 0.990 | 0.470 | 2.787 | 0.939 | 19.539 | 0.090 | 1.272 | 0.994 |
Adsorbents | qm | Reference | Adsorbents | qm | Reference |
---|---|---|---|---|---|
Ce-UiO-66 | 30.00 | [2] | TiO2-Ag | 25.70 | [31] |
EDTA-chitosan/Cu-BTC | 46.51 | [32] | CaAl-CO3 LDH | 20.24 | [33] |
UiO-66 | 36.40 | [34] | Rice husk | 25.2 | [35] |
UiO-66-(OH)2 | 59.20 | [34] | GO-NiFe LDH | 53.6 | [36] |
CoMgAl-LDH | 59.27 | [37] | Wool keratin/PET composite | 75.86 | [38] |
MSS | 46.08 | [39] | MOF-867 | 53.4 | [40] |
MnO2-deposited diatomites | 48.2 | [41] | UiO-66@Corn+ | 90.04 | This study |
Modified montmorillonite | 43.84 | [42] | UiO-66@Corn− | 22.38 | This study |
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Xie, H.; Wan, Y.; Chen, H.; Xiong, G.; Wang, L.; Xu, Q.; Li, X.; Zhou, Q. Cr(VI) Adsorption from Aqueous Solution by UiO-66 Modified Corncob. Sustainability 2021, 13, 12962. https://doi.org/10.3390/su132312962
Xie H, Wan Y, Chen H, Xiong G, Wang L, Xu Q, Li X, Zhou Q. Cr(VI) Adsorption from Aqueous Solution by UiO-66 Modified Corncob. Sustainability. 2021; 13(23):12962. https://doi.org/10.3390/su132312962
Chicago/Turabian StyleXie, Hongzhong, Yanlei Wan, Hao Chen, Guangcheng Xiong, Lingqing Wang, Qi Xu, Xiang Li, and Qiuhong Zhou. 2021. "Cr(VI) Adsorption from Aqueous Solution by UiO-66 Modified Corncob" Sustainability 13, no. 23: 12962. https://doi.org/10.3390/su132312962