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Article

Analysis of PM10 Substances via Intuitionistic Fuzzy Decision-Making and Statistical Evaluation

by
Ezgi Güler
and
Süheyla Yerel Kandemir
*
Industrial Engineering Department, Bilecik Seyh Edebali University, Bilecik 11230, Türkiye
*
Author to whom correspondence should be addressed.
Sustainability 2024, 16(17), 7851; https://doi.org/10.3390/su16177851
Submission received: 25 June 2024 / Revised: 22 July 2024 / Accepted: 18 August 2024 / Published: 9 September 2024
(This article belongs to the Section Air, Climate Change and Sustainability)

Abstract

:
Air pollution is a situation that negatively affects the health of humans and all living things in nature and causes damage to the environment. The most important cause of air pollution is the amount and density of substances called “particulate matter” above guidelines. Particulate matter (PM) are mixed liquid droplets and solid particles with advective diameters less than 2.5 μm (PM2.5—fine particles) and between 2.5 and 10 μm (PM2.5–10—coarse particles). PM10 is defined as one that can remain in the air for a long time and settle in the respiratory tract, damaging the lungs. It is important to identify the underlying causes of air pollution caused by PM10. In this context, these criteria need to be evaluated to minimize the negative effects of PM10. In the study, monthly average PM10 data obtained from the Air Quality Monitoring Station in Kocaeli, Türkiye, between 2017 and 2023 are used. After determining the criteria for PM10, the criteria are prioritized with the Intuitionistic Fuzzy AHP (IF-AHP) method by taking decision-maker opinions. The proposed decision-making model aims to guide obtaining and focusing on the important causes of out-of-limit and dangerous PM10 concentrations in the air. Additionally, PM10 data is analyzed in the context of COVID-19 and a statistical analysis is conducted. One-way Analysis of Variance (ANOVA) is used to evaluate whether there is a significant difference in average monthly data over the years. The Games–Howell test, one of the post-hoc tests, is used for determining differences between groups (years). In addition, monthly PM10 values for the future are estimated using the Expert Modeler tool in the software IBM® SPSS® Statistics 22. The study is important in that it provides a focus on the criteria affecting PM10 with an intuitionistic fuzzy perspective, along with statistical analysis.

1. Introduction

Since air is one of the most basic elements required for the vital functioning of humans and many living things, “air pollution” is an issue that concerns all people. Increases in the concentrations of pollutants that cause air pollution also greatly affect humans, living things, and environmental health. According to the World Health Organization (WHO), approximately seven million people in the world die every year due to air pollution-related causes such as lung cancer, heart disease, and acute respiratory diseases [1]. It is reported that air pollution is the cause of approximately 45 thousand preventable premature deaths every year in Türkiye [2]. It is possible to group air pollutants into gases and aerosol pollutants. Particulate matter (PM10 and PM2.5) is the most dangerous fraction of aerosol pollutants due to inhalation risks. Airborne PM is not a single pollutant but rather is a mixture of many chemical species. It is a complex mixture of solids and aerosols composed of small droplets of liquid, dry solid fragments, and solid cores with liquid coatings [3]. Particulate matter can occur naturally, such as in volcanic eruptions, dust storms, forest fires, vegetation, and sea sprays (the mixing of aerosol particles into the air by the explosion of bubbles). It can also be caused by human-made fixed and mobile structures such as vehicle exhausts, construction and demolition operations, residential fires, construction sites, and industrial sites. Particles can form in the atmosphere not only naturally or as a result of human activities, but also through the transformation of gas emissions such as sulfur oxide and nitrogen [4].
Türkiye, which is in the process of obtaining European Union (EU) membership, has harmonized its legislation with the EU and reduced the guidelines for air pollutants, bringing them to the level of the values applied in European countries. As of the beginning of 2019, the guidelines for PM10 and SO2 applied in EU countries have also come into force in Türkiye. Air quality in our cities is constantly monitored thanks to the National Air Quality Monitoring Network operated by the Türkiye Ministry of Environment and Urbanization, and the results are announced via its website and mobile application. The Ministry of Environment, Urbanization, and Climate Change has published the Türkiye Environmental Problems and Priorities Assessment Report. According to the report prepared using 2022 data; air pollution ranked first in 22 provinces of Türkiye and among the top three environmental problems in 66 provinces. It was stated that air pollution continues to increase in Türkiye [5]. Since changes in air quality need to be constantly monitored and evaluated, it is often possible to come across studies on this subject. However, when the time aspect of the work comes into play, or in other words when time passes and the work loses its currentness, the work must be repeated. The guidelines set by the WHO for the PM10 pollutant is on average 15 μg/m3 (daily) and 5 μg/m3 (annually). The guidelines for PM10 pollutants have been determined for Türkiye at the national level. The guidelines determined for PM10 pollutants in Türkiye were the same in 2021, 2022, and 2023. These values are on average 50 μg/m3 (daily), 40 μg/m3 (winter period), and 40 μg/m3 (annually). All guidelines are given in Table 1 [6,7,8].
According to Table 1, the difference between WHO and Türkiye national guidelines is remarkable and is worth examining and taking precautions. It is important to scientifically examine the parameters affecting air pollution to monitor air pollution and minimize the effects of pollutants such as PM10. Air pollution, defined as the presence of pollutants in the atmosphere at levels and durations that may harm human health, animals, plants, natural environments, and commercial and private properties, needs to be monitored and evaluated, and its distribution and change analyzed [9,10]. There are many studies in the literature examining the parameters affecting PM10 concentrations and pollution relationships.
Eroğlu [11] aimed to determine the extent of air pollution in the Çerkezköy and Kapaklı districts of Türkiye and the natural and human factors that cause air pollution. For this purpose, measurement values from Çerkezköy Air Quality Monitoring Station between 2013 and 2023 were used. Annual average PM10, PM2.5, SO2, NO2, NOx, and NO values were measured in Çerkezköy and Kapaklı. It has been determined that the annual averages of PM10 and NOx among these pollutants are higher than the guidelines for Türkiye, the EU, and the WHO. In terms of the sustainability of the human–space relationship in Çerkezköy and Kapaklı districts, taking into account the factors that cause air pollution, practices have been suggested to solve the problems. Birim et al. [12] examined correlations between PM10 pollutant data and meteorological parameters such as temperature, relative humidity, and wind speed and direction. Two different regions of Izmir province in Turkey were used as case studies and PM10 data were evaluated between 1 January 2017 and 31 December 2021. The t-test was used to statistically determine the relationship between PM10 pollutant data and meteorological parameters. As a further study, to assess the practical significance of parameters, the effect size method was employed. Relative humidity emerged as the most effective parameter based on correlation coefficient calculations. Zajusz-Zubek et al. [13] used dendrogram (DE), heat map (HM), and principal component analysis (PCA) methods to determine possible emission factors from PM10. In their study, PCA was shown to be the most useful statistical tool for PM10 factors. The main sources identified by the PCA are coal combustion, resuspension of soil and road dust, pesticide use, and waste incineration. Ul-Saufie et al. [14] used machine learning approaches in their study, apart from statistical method feature selection, to predict PM10 concentrations in Malaysia. The impact variables of the prediction model were investigated to compare the prediction model performance and predict the daily PM10 concentrations. In the study, weight-guided and genetic algorithm evolution, predictive analytical multiple linear regression (MLR), and artificial neural network (ANN)) were applied. The methods were compared based on The Root Mean Square Error (RMSE) and Absolute Error (AE) metrics. Erener et al. [15] examined the relationship between air pollution and seasonal meteorological data in Kocaeli, Türkiye. They made evaluations by regression analysis with daily SO2 and PM10 parameters and meteorological data such as temperature, wind direction, wind speed, relative humidity, and air pressure for 2015. Bai et al. [16] conducted a study on natural and socioeconomic factors affecting air pollution along with urban air quality monitoring data from 2015 in the Yangtze River Economic Zone. As a result of the study, they concluded that topographic, meteorological, economic development and urbanization factors are related to air pollution. Some scientists have shown in their research that meteorological factors (temperature, precipitation, humidity, atmospheric pressure, wind speed, etc.) have a significant impact on air pollution [17,18]. Jiang et al. [19] concluded in their study that the topographic structure prevents the clustering and dispersion of pollutants, and it was also revealed that as population and income levels increase, factors such as fossil fuel use, the number of vehicles, urbanization, and industrialization increase, causing pollutant emissions to increase, and therefore these factors affect air pollution. Lin and Wang [20] stated that air pollution is significantly dependent on energy consumption, industrialization, and technological developments in China.
In these studies on PM10 concentration values, the relationships between pollutants and pollutant factors are examined [11,12,15,16,17,18,19,20], while in some studies, the success of the methods used in the estimation of pollutants is examined [13,14].
Two different methods are used to evaluate air pollution: deterministic methods and statistical methods. Although deterministic methods are methods that model physical and chemical processes such as discharge, accumulation, or transfer processes of pollutants using meteorological, emission, and chemistry models, the accuracy of these methods varies depending on the quality and scale of the data used and it takes a long time to apply these methods to big data. The importance of statistical methods, which compensate for the shortcomings and weaknesses of deterministic methods, is increasing in studies [21]. Statistical methods have also been used in the literature, especially in studies involving the PM10 pollutant. Some of these methods include estimation and examination of the relationship between variables, and some include statistical analysis according to significance levels [22,23,24,25]. There are many decision-making problems in daily life. Multi-criteria decision-making (MCDM) methods, considered among deterministic methods, allow decision-makers to choose among a separate set of decisions or criteria or to prioritize these criteria or decisions. An exemplary study [26] on PM pollutants is on the material selection and evaluation of PM sensors. They proposed an analytical framework based on multi-criteria decision-making to evaluate and select the most suitable materials for the fabrication of PM sensors. In order to demonstrate the suitability of the analytical framework in the study, an empirical study was conducted based on recent research and received the opinions of 13 different decision-makers. A hybrid model has been developed using frequently used MCDM techniques such as DEMATEL, Analytic Network Process (ANP), and VIKOR. In many studies involving deterministic MCDM methods, there is actually a process of digitizing specific judgments, which essentially enables difficult decision processes to be concretized. In other studies, MCDM methods and even fuzzy logic have been included among the deterministic methods [27,28,29].
The COVID-19 pandemic has had serious negative effects on human health and the world economy; however, limiting social and economic activities also mediated the reduction in air pollution [30] because the main source of air pollution is anthropogenic activities [31]. It appears that the measures taken reduced the volume of these activities to a large extent. For example, during quarantine, mobility decreased by approximately 50% in Italy and 79% in France [32,33]. Particularly with travel restrictions and flexible working opportunities, the density in the transportation sector, which constitutes approximately one-quarter of total greenhouse gas emissions and is considered the main cause of air pollution in cities, was greatly reduced [34]. The decrease in emission sources of air pollutants has played an encouraging role in research conducted to determine changes in air quality.
In this study, the criteria affecting PM10 values are examined in detail; the criteria weights are obtained from the IF-AHP perspective, and the criteria importance ranking is determined. In this context, the criterion or criteria affecting PM10 that will be focused on and evaluated are discussed from an intuitionistic fuzzy decision-making perspective. This point is the motivation for the study as it fills the gap in the literature. In addition to this decision analysis, a statistical evaluation was also presented using 7-year PM10 values covering the COVID-19 period in Kocaeli, Türkiye. Determination of whether there was a significant difference between the average data is evaluated using one-way ANOVA. PM10 concentration values were estimated monthly based on statistical data analysis using Expert Modeler in the IBM® SPSS® Statistics 22 software. In the Section 2 of the study, the materials and methods are presented. The Section 3 covers the results. The Section 4 contains a discussion. Conclusions are given in the Section 5.

2. Materials and Methods

A flow diagram of this study’s process is presented in Figure 1.
The main source of innovation in this study is to provide decision-makers with a roadmap on PM10 by using deterministic and statistical methods together and to fill the literature gap in this field. The absolute data obtained will be analyzed statistically and a decision model that includes criterion prioritization will be presented to decision-makers in line with the subjective criteria in the decision process.

2.1. Study Area and Data

Kocaeli province is located in the Marmara Region of Türkiye. Figure 2 shows the location of Kocaeli. Kocaeli is the 10th most populous city in Türkiye and according to 2023 TURKSTAT data, its population is 2,102,907 people and its area is 3626 km2 [35].
Since the negative effects of air pollution on human health are known, air quality sampling data should be collected at a certain frequency to determine the level of emissions. For this purpose, 125 air pollution surveys were conducted in 81 provinces between 2005 and 2007 by the Türkiye Ministry of Environment, Urbanization, and Climate Change to measure air pollution accurately, establish air pollution policies in all provinces, and improve air quality in the provinces within the framework of these policies compared to the values of the previous year. A quality measurement station was established and a National Air Quality Monitoring Network was established throughout Türkiye. Particulate matter (PM10) parameters can be measured fully automatically in all established air pollution measurement stations. Measurement data collected at measurement stations are monitored and transferred to the Ministry’s Environmental Reference Laboratory Data Processing Center via GSM Modems over a special network (VPN) belonging to the Türkiye Ministry of Environment, Urbanization, and Climate Change and published simultaneously [37]. Verification studies are carried out by examining the data received from the stations in the form of hourly averages, and monthly and annual reports are prepared and published with the data in question. These measurements have been made continuously at stations in Kocaeli province since 1987. Air pollution parameters are measured hourly at air quality monitoring stations. There are a total of 12 measurement stations in Kocaeli province under the control of the Türkiye Ministry of Environment, Urbanization, and Climate Change [36]. Air quality monitoring stations are established in four different categories: urban, traffic, industrial, and rural. At the air quality measurement station, PM10 concentration values are measured with automatic devices in accordance with international standards. The Kocaeli air quality monitoring station is shown in Figure 3. The station in Figure 3 is an urban-type station.
Monthly average PM10 concentration values for the years 2017–2023 obtained from the Kocaeli air quality monitoring station (central) are given in Table 2.
Monthly average values are calculated based on the measured “daily” PM10 concentration values in Table 2. The numbers of days exceeding Türkiye’s guideline of 50 μg/m3 for each year are as follows: “2017: 164 days”; “2018: 225 days”; “2019: 164 days”; “2020: 75 days”; “2021: 90 days”; “2022: 119 days”; “2023: 84 days”. While the maximum number of limit-day exceedances was in 2018, the minimum number of limit-day exceedances was in 2020.
Statistical descriptives for Kocaeli’s monthly average PM10 concentration values in Table 2 are calculated using the IBM® SPSS® Statistics 22 software. The findings obtained are given in Table 3.
According to Table 2 and Table 3, the highest monthly average PM10 concentration value was recorded in “November 2017”, at “86.18 μg/m3”, while the lowest monthly average PM10 concentration value was recorded in “June 2023”, at “23.16 μg/m3”. According to Table 3, the highest standard deviation of PM10 concentration values was calculated for 2017, with a value of 18.51, while the lowest standard deviation was calculated for 2020, with a value of 4.96. The highest annual average value, 61.95, was achieved in 2018 when the COVID-19 pandemic had not yet started. Due to restrictions around the world, the annual average PM10 concentration value decreased significantly in 2020. The annual average PM10 concentration value started to increase again in 2021 and 2022. In 2023, it showed a serious decrease again. It can be assumed that this decrease is related to the introduction of various measures against air pollution and the adoption of remote working principles by most businesses due to the COVID-19 pandemic. In this context, it is important that the criteria affecting PM10 concentration be considered in a region-specific manner and be examined in detail by decision-makers. In this study, the selection of some criteria affecting PM10 concentration values is made using the “brainstorming” method by decision-makers who evaluated the literature. For this purpose, the scale that will be detailed in the next section is used. Decision-makers are asked to compare the evaluation criteria pairwise and the IF-AHP algorithm is included in the process. It is aimed at obtaining criterion weights for each criterion at the end of the IF-AHP process steps. Thus, the order of importance of the criteria from the decision-making perspective can be obtained. In addition, statistical analysis is performed on actual PM10 concentration values, and one-way ANOVA is used to evaluate whether there is a significant difference between average PM10 concentration values in the context of COVID-19. The results obtained using one-way ANOVA are evaluated and prospective monthly PM10 concentration “prediction” values are handled using Expert Modeler.
In the following sections, IF-AHP, one-way ANOVA, and Expert Modeler methodologies are presented.

2.2. Intuitionistic Fuzzy AHP (IF-AHP)

The AHP method was developed by Professor Thomas L. Saaty and is used for decision-making problems. AHP is a methodology based on one-to-one comparisons of the criteria and sub-criteria affecting the decision according to their degree of importance, using a binary comparison scale in any decision problem. The AHP method also aims to prioritize by distinguishing between alternative options to meet interconnected goals [38]. However, AHP cannot fully reflect the functioning of the complex human thought system. For this reason, the method has been used by many researchers in problem-solving by combining it with the fuzzy logic approach [39,40,41]. In the following periods, the uncertain and hesitant situations of decision-makers and the decision environment brought about the search for heuristics in the fuzzy AHP method. By developing intuitionistic fuzzy set theory, this approach has been integrated with the AHP method and investigated by several researchers [42]. Abdullah and Najib [42] proposed a new heuristic fuzzy AHP with a new pairwise matching comparison matrix evaluation preference scale. This new preference scale led to the proposal of a new consistency test for matrix evaluation using the values of the degree of hesitation. The steps of the IF-AHP method presented by Abdullah and Najib are as follows:
Step 1: A hierarchical structure is created for the decision problem.
Step 2: Pairwise comparison matrices are created with the triangular intuitive fuzzy numbers preference scale in Table 4. In the decision-making process, evaluation criteria are analyzed by decision-makers using pairwise comparison. For this purpose, in the normal AHP method, the criteria are compared with each other in pairs based on the “Comparison Preference” and “AHP Preference Correspondence” columns in Table 4. Inverse reciprocals are expressed as fractions. In the IF-AHP method, a pairwise comparison of evaluation criteria is made with triangular and opposite triangular intuitive fuzzy number logic. The equivalents of the AHP comparison scale in IF-AHP are also included in Table 4. As stated in Section 2.1, each decision-maker subjects each evaluation criterion to a pairwise comparison.
Step 3: The weights of decision-makers are determined. The degree of importance of the decision-makers to the decision problem is also expressed by linguistic variables. Triangular intuitive fuzzy numbers defined for linguistic variables are given in Table 5. D k ( μ k , v k ,   τ k )   is the expression of the degree of importance of expertise of the decision maker “k” for the decision in terms of an intuitive fuzzy number. The aim is to include different levels of expertise in the decision-making process. The importance levels of the decision-makers in the decision-making group in the process are determined according to the linguistic variables and their equivalents in Table 5.
The weight of the k decision-maker is calculated using Equation (1) [43].
λ k = μ k + τ k ( μ k μ k + v k ) k = 1 l ( μ k + τ k μ k μ k + v k )
where
k = 1 l λ k = 1 , k = ( 1,2 , l ) .
Step 4: The aggregated intuitive fuzzy decision matrix based on the decision-maker’s opinion is created using the intuitive fuzzy weighted average (IFWA) operator developed by Xu [44].
The combination form of the IFWA operator is given in Equation (2), where R ( k ) = ( r i j k ) m x n is the intuitive fuzzy decision matrix of the k decision-maker and λ = ( λ 1 , λ 2 , λ n ) is the weight of all decision-makers.
r i j = I F W A λ ( r i j 1 , r i j 2 , , r i j l ) = ( λ 1 r i j 1 +   λ 2 r i j 2 +   +   λ l r i j l )
r i j = ( 1 k = 1 l ( 1 μ i j k ) λ k , k = 1 l ( v i j k ) λ k , k = 1 l ( 1 μ i j k ) λ k k = 1 l ( v i j k ) λ k ) .
From here to r i j = ( μ i j , v i j , τ i j );
It is expressed as;
μ i j = 1 k = 1 l ( 1 μ i j k ) λ k
v i j = k = 1 l ( v i j k ) λ k
τ i j = k = 1 l ( 1 μ i j k ) λ k k = 1 l ( v i j k ) λ k
Step 5: The consistency ratio (CR) is calculated for the collective heuristic fuzzy decision matrix. Since the bulk intuitionistic fuzzy matrix contains the τ (x) value, which is the hesitation value of triangular intuitionistic fuzzy numbers, a new method is presented for calculating the consistency ratio [42]. Random index (RI) values were taken from Table 6 presented by Saaty in the standard AHP method [45]. These RI values are also used in the IF-AHP method. According to the new method presented, CR is calculated using the equation in Equation (3). (λmaxn) in Equation (3) is the average of the τ(x) values in the aggregated intuitive fuzzy matrix of each criterion. The value of n is the size of the matrix.
C R = ( λ m a x n ) / n 1 R I
The matrix is confirmed to be consistent if the CR value does not exceed 0.10. If this value is greater than 0.10, there is an inconsistent decision matrix and, in this case, it is necessary to reconstruct the comparison matrices.
Step 6: The intuitive fuzzy entropy weights of the weighted aggregated intuitive fuzzy decision matrix are calculated using the equation given in Equation (4) and the final weights are calculated with the equation in Equation (5). Afterward, final criterion weights can be obtained by taking arithmetic averages.
w ̿ i = 1 n l n 2 [ μ i l n μ i + v i l n v i 1 τ i ln 1 τ i τ i l n 2 ]
w i = 1 w ̿ i n j = 1 n w ̿ i ,   j = 1 n w i = 1

2.3. One-Way ANOVA

The concept of analysis of variance used in statistics is the general name of a group method that includes many statistical methods. The simplest form of variance analysis is a one-way analysis of variance (one-way ANOVA). As with other tests, some prerequisites must be met in the application of this test. These conditions are the homogeneity of group variances and that the dependent variable consists of quantitative data. One-way ANOVA is used to analyze how independent variables interact with each other and the effect of this interaction on the dependent variable [46]. Multiple comparison post-hoc tests are divided into two groups as shown in Table 7, according to equal or different variance approaches.
In the variance homogeneity analysis results, it is said that there is a significant difference between the groups when the significance level (Sig.) value is less than 0.05. If the Sig. value is less than 0.05, it is necessary to find out which groups this difference is between using the tests in Table 7.

2.4. Expert Modeler

Expert modeler is a tool used in the IBM® SPSS® Statistics 22 software to choose the ideal model among exponential smoothing or ARIMA models in time series that can be used for forecasting. Often known as a skilled data analyst, an expert modeler can create complex models to analyze data and make predictions. Expert modeler allows not only the theoretical foundations of various modeling techniques but also the process of applying the selected model based on the characteristics of the data and the goals of the analysis [47]. IBM notes: “Expert Modeler provides options you can use, including restricting the set of candidate models, handling outliers, and event variables” [48]. In many studies in the literature, statistical analysis and predictions are made using Expert Modeler [47,49,50,51]. The Expert Modeler’s feature automatically determines the best Autoregressive Integrated Moving Average (ARIMA) or exponential smoothing model for time series [52]. The Expert Modeler interface as a time series tool is shown in Figure 4.

3. Results

3.1. Findings of IF-AHP

Some of the criteria in the literature are examined to determine the criteria affecting PM10 concentrations and they are weighted using IF-AHP [53]. The criteria determined within the scope of this study are given in Table 8.
Adverse Meteorological Conditions (C1): The climate of a region affects the distribution of PM10 substances in the atmosphere [60]. The relationship between air quality and meteorological conditions in cities has been the subject of research in recent years [61]. Basic meteorological features such as temperature, humidity, wind speed, and pressure have a positive and negative effect on PM10 values [62]. Many studies have been conducted to determine the effect of meteorological parameters on PM10 concentrations. In these studies, it was determined that there was a relationship between PM10 levels and meteorological conditions [63].
Density of Industrial Facilities (C2): Pollutants are released into the atmosphere when the fuel used to obtain the energy needed in industrial facilities such as factories, power plants, combustion plants, and industrial facilities is burned. In addition, the concentration of PM10 in the air increases as a result of the burning of solid waste in furnaces and open areas [64].
Population Growth (C3): Population growth and development are rapidly changing the environment. Due to rapid population growth and increasing industrialization and urbanization, damages such as climate change, difficulty in accessing clean water, air pollution, increase in hazardous waste, deforestation, and desertification occur. It is known that the PM10 rate is higher in areas with high population densities [65].
Unplanned Urbanization (C4): Unplanned urbanization along with increasing energy use, the use of coal with high sulfur content for heating, the destruction of nature, and the negative impact on the climate have made air pollution and the increase in PM10 levels an important problem, especially in big cities [66].
Lack of Green Areas (C5): Urban green areas have many important and even vital functions, especially ecological, economic, social, and planning [67]. However, infrastructure systems must support ecosystem functions. Reducing and balancing air pollution is one of these important functions. The most important role of green areas in reducing air pollution is their ability to absorb particulate matter in the air. The decrease in green areas increases the PM10 rate in the air [68].
Topographic Structure (C6): The unsuitable topographic features of the settlements have negative effects on air quality [69]. The topography of the regions affects the distribution of air pollution in the atmosphere. Topographic differences in the city also cause spatial differences in air pollution [70]. Settlements built without taking into account the topographic characteristics of the areas where cities are established further increase the existing air pollution. In regions with basin geomorphology surrounded by elevations, the amount of PM10 and its residence time in the environment are high. In cases where the topographic features of cities prevent wind flow, PM10 pollutants cannot disperse in the air [71].
Motor Vehicle Emissions (C7): High levels of engine emissions occur due to low levels of engine technology, the lack of a comprehensive vehicle emissions inspection and maintenance program, as well as poor enforcement of vehicle emissions requirements. Toxic hydrocarbons and organic oxygenates, carbon monoxide, nitrogen oxides, and soot particles are released from motor vehicle exhaust, and the PM10 rate also increases [53].
According to the flow chart in Figure 1, decision-makers’ opinions are used to weigh the criteria, and the IF-AHP methodology is applied. The intuitive triangular fuzzy numbers in Table 5 are used when determining the importance of the weights of the DM group in the decision process. In this study, environmental engineers (DM1 and DM2), chemical engineers (DM3 and DM4), and industrial engineers (DM5) constitute the DM group. Triangular intuitive fuzzy number equivalents based on the linguistic variables determined for the DM group are given in Table 9. While calculating λk (weights) in Table 9, Equation (1) in Step 3 of the IF-AHP is used. The calculated weights of the DM group are given in Table 9.
The decision-makers, consisting of five different decision-makers whose contribution of weights to the process are given in Table 9, compared the evaluation criteria pairwise, taking into account the scale in Table 4. The IFWA operator in Equation (2) is used. The resulting aggregated intuitive fuzzy decision matrix (rij) is given in Table 10.
The consistency ratios in the DM group matrices obtained using the formulation in Equation (3) of the IF-AHP methodology are obtained as DM1: 0.07, DM2: 0.07, DM3: 0.03, DM4: 0.04, and DM5: 0.03, respectively. Since these ratios are less than 0.10, the process is meaningful.
The decision-maker weights obtained with Equation (1) are included in the system with the IFWA operator and a weighted aggregated intuitive fuzzy decision matrix is obtained. The weighted aggregated intuitive fuzzy decision matrix is given in Table 11.
The final criterion weights obtained from the weighted aggregated intuitive fuzzy decision matrix using Equations (4) and (5) are given in Table 12.
According to Table 9, the criterion with the highest importance weight was determined to be C2: density of industrial facilities. The criterion with the lowest level of importance is C1: adverse meteorological conditions. The importance level ranking of the criteria obtained is C2 > C6 > C3 = C7 > C4 = C5 > C1.

3.2. Findings of One-Way ANOVA

The first restriction decisions in Türkiye due to the COVID-19 pandemic were taken on 12 March 2020. The first curfews were imposed on 10–12 April 2020. In this context, while the COVID-19 pandemic had no impact in Türkiye, as in the rest of the world, in 2019, the social, environmental, and material effects of the COVID-19 pandemic have been felt since 2020. To examine the environmental impact in detail over the years, one-way ANOVA was conducted for the data in Table 2. For this, first, variance homogeneity was tested. The results of the variance homogeneity test are given in Table 13.
Since the Sig. value (0.001) in Table 13 is less than 0.05, the established variance homogeneity hypothesis is rejected, and it is determined that the variance is not homogeneous between the groups. The results of the one-way ANOVA test applied to the data are given in Table 14.
According to the findings in Table 14, the hypothesis that there is no significant difference between year groups is rejected because the Sig. value (0.002) is less than 0.05. In other words, there is a significant difference between years for Kocaeli’s PM10 concentration values.
To determine whether there is a significant difference between years, the Games–Howell Post-hoc test given in Table 7, which is used in cases where there is no homogeneity of variance, is applied. The findings obtained as a result of the Games–Howell test are given in Table A1 in Appendix A.
According to the Sig. and mean difference values obtained in Table 13 and written in bold, there are significant differences in average Kocaeli’s PM10 concentration values between some years. The significant differences between these years are expressed in the comparison table in Table 15.
According to Table 15, there is a significant and meaningful statistical difference between the average PM10 concentration values for the 3 years before 2020 and the 3 years after 2020. For this reason, a forecast study has been planned for the period after 2020. In this context, the monthly average PM10 concentration values for 2020, 2021, 2022, and 2023 in Table 2 are used.

3.3. Findings of the Expert Modeler

The Expert Modeler tool is used in the IBM® SPSS® Statistics 22 software based on the monthly average PM10 concentration values for 2020, 2021, 2022, and 2023. The Expert Modeler determined the analysis method most suitable for the data as the “Simple Seasonal Model”. At this point, it is appropriate to give brief information about the Simple Seasonal Model. The simple seasonal model is suitable for time series data that do not have a trend and whose seasonal effect is constant over time. The exponential smoothing parameters described by the following equations (Equations (6)–(8)) are level and seasonal [72].
Level :     L t = α A t S t s + ( 1 α ) ( L t 1 )
Seasonal :   S t = γ A t L t + ( 1 γ ) S t s
Forecast :   F ( t + h ) = ( L t + S t s + h )
where
L = level of the series,
α = level smoothing constant between 0 and 1,
A = actual values,
s = number of seasonal periods in a year,
S = seasonal component,
γ = seasonal smoothing constant between 0 and 1,
t = some time period,
h = number of time periods ahead to be forecast,
The simple seasonal model description, statistics, and model parameters obtained are given in Table 16.
The time series sequence chart showed seasonal periodic fluctuations. Therefore, the Expert Modeler in the IBM® SPSS® Statistics 22 software suggested a simple seasonal model as the most suitable model for this time series data. The Ljung-Box test in Table 16 is a test that analyzes whether the model is correctly specified for the data. Since the value 0.530 is >0.05, the simple seasonal model is determined to be correct for monthly data between 2020–2023. Also, as shown in Table 16, the Expert Modeler detected no outliers in the data. A constant R-squared value is used in the analysis to test the goodness of fit. Maximum R-squared values indicate a better fit of the model. The value of 0.732 here means that the model can explain 73.2% of the observed changes in the time series. Additionally, in Table 16, the MAPE value is calculated as 12.787%. This value shows that the model has a good and reliable value.
Estimated monthly average PM10 concentration values for the years 2024, 2025, and 2026, obtained with the simple seasonal model in Expert Modeler, are given in Table A2 in Appendix A together with their lower (LCL) and upper (UCL) values. LCL and UCL values are confidence intervals for the estimated values.
A graphical view of the estimated PM10 concentration values obtained is given in Figure 5.

4. Discussion

There are many studies in the literature that statistically examine the relationship between COVID-19 and PM10 concentration values [73,74,75,76,77]. Indeed, it is clear that there were serious changes in PM10 concentration values as a result of the decrease in human movements due to COVID-19 measures. In this context, being able to analyze these changes and make future predictions is important for human and environmental health.
There are also studies in which PM10 concentration values or measured weather stations are evaluated deterministically using MCDM approaches [78,79,80]. Obtaining the importance levels of the criteria that may affect changes in PM10 concentration values specifically and through decision-maker evaluations working in the region is an important input for the control and analysis of PM10 concentration values. In this study, decision-making judgments and decisions are digitized with IF-AHP, and related criteria that may cause changes in the impact of COVID-19 are ranked according to their importance levels.
Some limitations of this study should be mentioned. In the study that hybridizes the statistical process and the intuitive fuzzy decision-making process, the interpretations that can be made may vary if the decision-making group itself or the decision-maker’s judgments change. In this context, the structure of the decision problem and the status of the measures to be taken should be taken into consideration. The comments made on the COVID-19 pandemic and the criteria weighting process to be used are also open to different methodologies. When considered in terms of statistical analysis, the success of different forecasting methods can be examined. This study is planned for Kocaeli province in the Marmara Region of Türkiye. Decision process and statistical process analyses in different countries or regions may yield different results.
This study aims to provide a holistic perspective on the examination, evaluation, and prediction of PM10 concentration values and their effects through deterministic and statistical analysis.

5. Conclusions

In this study, PM10 is analyzed in Kocaeli province, which is located in the north of Turkey’s Marmara region and is one of the most important industrial cities.
  • As stated in the flowchart given in Figure 1, the study aimed to propose a decision model using deterministic and statistical analyses. For deterministic analysis, the criteria affecting PM10 concentration values in Kocaeli city center are determined from a literature review and decision-makers’ opinions. The IF-AHP method is used for criterion weighting. The purpose of determining criterion weights with IF-AHP logic in the evaluation of criteria affecting PM10 concentration values on a regional basis stems from the nature of the decision problem. The degree of hesitation is important for such intuitive decisions. According to the results obtained with IF-AHP, the most important criterion is determined to be C2: density of industrial facilities. The criterion that has the least impact on PM10 concentration values is C1: adverse meteorological conditions.
  • In the statistical analysis part of the study, PM10 concentration values between 2017 and 2023, covering the pandemic period, are examined. Although significant decreases in air pollutant levels are observed in Europe and other regions during the pandemic period, these changes are not permanent as a result of the decrease in outdoor activities, transportation, and even industrial activities due to quarantine and restriction periods. Looking at the center of Kocaeli, the highest annual average PM10 concentration value was recorded in 2018, when pandemic-related restrictions had not yet occurred. PM10 concentration values started to increase significantly in 2020, 2021, and 2022. This increase may be an indication that heavy restrictions and measures are starting to lose their effectiveness. When this situation is associated with the results obtained using IF-AHP, effects such as remote working decisions or production restrictions in industrial facilities may have caused changes. Surprisingly, the monthly average concentration value reached its lowest level in 2023. The impact of this situation can be shown as the impact of economic pressure on industrial centers, but it may also be related to the adoption of some measures developed in 2023. The COVID-19 period quickly became permanent. Looking at the one-way ANOVA test results, there is a significant difference between the monthly average PM10 concentration values for the years. Accordingly, it can be said that the harmful effects of air pollution and PM10 in 2022 will be similar to the monthly average levels in 2019. The results obtained with the Games–Howell test valid for groups without variance homogeneity are given in Table A1 in Appendix A. According to Table A1 in Appendix A, considering that 2020 is the most critical year for COVID-19, there are significant differences between the years before 2020 and those after 2020. In this context, it is important to base the forecast on the period after 2020 for the sake of accuracy.
  • In this study, monthly average PM10 values in 2020–2023 are estimated with the Expert Modeler tool in the software IBM® SPSS® Statistics version 22. The Expert Modeler tool determined the most appropriate forecasting model to be the simple seasonal model. Using the model data, 36-month estimated PM10 concentration values for 2024–2026 were obtained (Table A2 in Appendix A). In checking the estimated values obtained, the criterion weights obtained with IF-AHP can be examined by policymakers and decision-makers, and this examination may pave the way for more detailed analyses in future studies.
The motivation and innovation part of this study is that it can provide some inferences to decision-makers and managers with a statistical and deterministic MCDM approach specifically for PM10 particulate matter.

Author Contributions

E.G. and S.Y.K.; investigation, data curation, E.G. and S.Y.K.; writing—original draft preparation. All authors have read and agreed to the published version of the manuscript.

Funding

This research received no external funding.

Institutional Review Board Statement

Not applicable.

Informed Consent Statement

Not applicable.

Data Availability Statement

The data presented in this study are available upon request from the corresponding author.

Conflicts of Interest

The authors declare no conflicts of interest.

Appendix A

Table A1. Findings of the Games–Howell test.
Table A1. Findings of the Games–Howell test.
(I) Time(J) TimeMean Difference (I − J)Std. ErrorSig.95% Confidence Interval
Lower BoundUpper Bound
20172018−3.4385.9060.996−23.29316.418
20193.8126.2430.996−16.80724.432
202018.397 *5.5320.044−0.81537.609
202115.9905.7510.147−3.56835.548
202213.2956.1100.356−7.00733.597
202318.6726.2320.090−1.92039.263
201820173.4375.9060.996−16.41823.293
20197.2504.0900.579−6.06220.562
202021.834 *2.8920.00012.24431.424
202119.427 *3.2900.0008.75230.103
202216.732 *3.8850.0054.13029.335
202322.109 *4.0730.0008.85635.362
20192017−3.8126.2430.996−24.43216.807
2018−7.2504.0900.579−20.5626.062
202014.584 *3.5300.0122.66626.502
202112.1783.8630.065−0.50924.865
20229.4824.3800.353−4.70423.669
202314.859 *4.5490.0470.13829.580
20202017−18.3975.5320.064−37.6090.815
2018−21.834 *2.8920.000−31.424−12.244
2019−14.584 *3.5300.012−26.502−2.666
2021−2.4072.5600.961−10.8035.990
2022−5.1023.2890.713−16.1405.937
20230.2753.5101.000−11.57012.120
20212017−15.9905.7510.147−35.5483.568
2018−19.427 *3.2900.000−30.103−8.752
2019−12.1773.8630.065−24.8650.510
20202.4072.5600.961−5.99010.803
2022−2.6953.6440.988−14.6049.214
20232.681673.8450.991−9.94115.304
20222017−13.2956.1100.356−33.5977.007
2018−16.732 *3.8840.005−29.335−4.130
2019−9.4824.3800.353−23.6694.704
20205.1023.2900.713−5.93716.140
20212.6953.6440.988−9.21414.604
20235.3774.3640.874−8.75619.510
20232017−18.6726.2320.090−39.2631.920
2018−22.110 *4.0730.000−35.362−8.856
2019−14.859 *4.5490.047−29.580−0.138
2020−0.2753.5101.000−12.12011.571
2021−2.6823.8450.991−15.3049.941
2022−5.3774.3640.874−19.5108.756
* The mean difference is significant at the 0.05 level.
Table A2. Estimated PM10 concentration values obtained using the simple seasonal model.
Table A2. Estimated PM10 concentration values obtained using the simple seasonal model.
Months/YearsForecastUCLLCL
Jan 202444.0657.0631.05
Feb 202447.5360.6034.46
Mar 202441.9955.1328.86
Apr 202442.7755.9729.57
May 202436.6249.8923.36
Jun 202433.5346.8620.21
Jul 202433.5646.9520.17
Aug 202436.9550.4023.50
Sep 202436.0449.5522.52
Oct 202444.3357.9130.76
Nov 202450.0463.6836.41
Dec 202452.6466.3438.94
Jan 202544.0657.8230.30
Feb 202547.5361.3533.71
Mar 202541.9955.8828.11
Apr 202542.7756.7128.83
May 202536.6250.6322.62
Jun 202533.5347.6019.47
Jul 202533.5647.6819.44
Aug 202536.9551.1422.77
Sep 202536.0450.2821.80
Oct 202544.3358.6330.03
Nov 202550.0464.4035.68
Dec 202552.6467.0638.22
Jan 202644.0658.5329.58
Feb 202647.5362.0633.00
Mar 202641.9956.5927.40
Apr 202642.7757.4228.12
May 202636.6251.3321.92
Jun 202633.5348.3018.77
Jul 202633.5648.3818.74
Aug 202636.9551.8322.08
Sep 202636.0450.9721.10
Oct 202644.3359.3229.34
Nov 202650.0465.0935.00
Dec 202652.6467.7437.54

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Figure 1. Flow diagram of this study’s process.
Figure 1. Flow diagram of this study’s process.
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Figure 2. Location of Kocaeli on the map of Türkiye [36].
Figure 2. Location of Kocaeli on the map of Türkiye [36].
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Figure 3. Kocaeli air quality monitoring station (central).
Figure 3. Kocaeli air quality monitoring station (central).
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Figure 4. Expert Modeler interface in IBM® SPSS® Statistics 22 software.
Figure 4. Expert Modeler interface in IBM® SPSS® Statistics 22 software.
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Figure 5. Graphical view of the estimated PM10 concentration values.
Figure 5. Graphical view of the estimated PM10 concentration values.
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Table 1. PM10 guidelines for WHO and Türkiye national values based on period.
Table 1. PM10 guidelines for WHO and Türkiye national values based on period.
PollutantPeriodWHOTürkiye National Values
PM10Daily15 μg/m350 μg/m3
Annually5 μg/m340 μg/m3
Winter Period-40 μg/m3
Table 2. Monthly average PM10 concentration values for the years 2017–2023 obtained from the Kocaeli air quality monitoring station (central) (μg/m3).
Table 2. Monthly average PM10 concentration values for the years 2017–2023 obtained from the Kocaeli air quality monitoring station (central) (μg/m3).
Years2017201820192020202120222023
Months
January37.8969.9459.4543.1844.6739.8549.55
February74.2859.7258.444.5347.7452.4546.42
March69.0577.9251.6945.1138.351.0834.51
April47.2971.6345.4739.3942.5855.9334.2
May39.0849.658.0539.2437.7740.130.41
June47.2255.151.4239.5137.6834.8123.16
July42.6158.5240.7831.5940.2529.933.52
August42.5354.1141.9830.7338.9139.8939.31
September53.854.3945.5338.437.2439.6929.84
October76.9867.9255.5545.5439.7439.2253.85
November86.1857.2878.0639.563.6255.7242.35
December85.2967.3270.0744.7241.8264.0261.02
Table 3. Statistical descriptives for Kocaeli’s average PM10 concentration values by years.
Table 3. Statistical descriptives for Kocaeli’s average PM10 concentration values by years.
Year MeanStd. Deviation
(Standard Deviation)
Std. Error
(Standard Error)
MaxMin
20171258.5218.515.3486.1837.89
20181261.958.702.5177.9249.60
20191254.7011.183.2378.0640.78
20201240.124.961.4345.5430.73
20211242.537.362.1263.6237.24
20221245.2210.262.9664.0229.90
20231239.8411.103.2061.0223.16
Total8448.9813.651.4986.1823.16
Table 4. Triangular intuitive fuzzy numbers comparison preference scale.
Table 4. Triangular intuitive fuzzy numbers comparison preference scale.
Comparison PreferenceAHP Preference CorrespondenceTriangular Intuitive Fuzzy NumbersOpposite Triangular Intuitive Fuzzy Numbers
Equal Important1(0.02  0.18  0.80)(0.02  0.18  0.80)
Middle2(0.06  0.23  0.70)(0.23  0.06  0.70)
Somewhat Important3(0.13  0.27  0.60)(0.27  0.13  0.60)
Middle4(0.22  0.28  0.50)(0.28  0.22  0.50)
Strongly Important5(0.33  0.27  0.40)(0.27  0.33  0.40)
Middle6(0.47  0.23  0.30)(0.23  0.47  0.30)
Very Strongly Important7(0.62  0.18  0.20)(0.18  0.62  0.20)
Middle8(0.80  0.10  0.10)(0.10  0.80  0.10)
Absolutely Important9(1     0     0)(0     1     0)
Table 5. Linguistic variables and triangular intuitive fuzzy number correspondence for the importance levels of decision-makers.
Table 5. Linguistic variables and triangular intuitive fuzzy number correspondence for the importance levels of decision-makers.
Linguistic VariablesTriangular Intuitive Fuzzy Number Correspondence
Very important(0.90  0.05  0.05)
Important(0.75  0.20  0.05)
Somewhat Important(0.50  0.40  0.10)
Insignificant(0.25  0.60  0.15)
Very unimportant(0.10  0.80  0.10)
Table 6. RI values for the standard AHP and IF-AHP methods.
Table 6. RI values for the standard AHP and IF-AHP methods.
n 1–23456789
RI0.00.580.901.121.241.321.411.45
Table 7. Post-hoc tests used based on variance homogeneity.
Table 7. Post-hoc tests used based on variance homogeneity.
Tests Using the Equal Variance TheoryTests Using Different Variance Theory
LSD (Fisher’s significant difference test)Tamhane Test
Bonferroni TestDunnet T3 Test
Tukey HSD TestGames–Howell Test
Scheffe TestDunnet–C Test
Duncan Test
Dunnet Test
Waller–Duncan Test
Table 8. Criteria affecting PM10 concentration values, criteria no, and references.
Table 8. Criteria affecting PM10 concentration values, criteria no, and references.
Criteria Affecting PM10 Concentration ValuesCriteria NumberReference
Adverse Meteorological ConditionsC1[54,55]
Density of Industrial FacilitiesC2[11]
Population GrowthC3[56]
Unplanned UrbanizationC4[57]
Lack of Green AreasC5[58]
Topographic StructureC6[59]
Motor Vehicles EmissionsC7[11]
Table 9. Triangular intuitive fuzzy number and weights of the DM group for the decision process.
Table 9. Triangular intuitive fuzzy number and weights of the DM group for the decision process.
DM GroupTriangular Intuitive Fuzzy Numberλk (Weights)
DM1(0.90  0.05  0.05)0.2351
DM2(0.90  0.05  0.05)0.2351
DM3(0.75  0.20  0.05)0.1959
DM4(0.75  0.20  0.05)0.1959
DM5(0.50  0.40  0.10)0.1378
Table 10. The aggregated intuitive fuzzy decision matrix (rij).
Table 10. The aggregated intuitive fuzzy decision matrix (rij).
Criteria NumberDM1DM2
μ i j v i j τ i j μ i j v i j τ i j
C10.17440.32990.49570.22000.17410.6059
C20.22560.27250.50190.28390.22950.4866
C30.25440.23460.51100.32280.24050.4367
C40.18180.31710.50110.21060.19280.5966
C50.24630.21790.53580.17920.24310.5777
C60.32620.21530.45850.17920.24310.5777
C70.20870.25660.53470.17920.24310.5777
Criteria NumberDM3DM4
μ i j v i j τ i j μ i j v i j τ i j
C10.17710.42470.39830.14320.45350.4033
C20.38070.27890.34040.38630.17270.4410
C30.33550.28340.38120.21520.32520.4596
C40.21060.38960.39990.22360.27280.5036
C50.26600.30510.42890.50950.19120.2993
C60.43740.21680.34580.47540.20030.3242
C70.49910.20330.29760.29490.27460.4305
Criteria NumberDM5
μ i j v i j τ i j
C10.17350.42330.4031
C20.38070.27890.3404
C30.26420.27690.4589
C40.17660.35730.4661
C50.26600.30510.4289
C60.43740.21680.3458
C70.54300.18690.2701
Table 11. The weighted aggregated intuitive fuzzy decision matrix.
Table 11. The weighted aggregated intuitive fuzzy decision matrix.
Criteria Number μ i j v i j τ i j
C10.17980.32860.4916
C20.32580.24120.4329
C30.28150.26710.4514
C40.20190.28990.5082
C50.29930.24390.4568
C60.36730.21890.4138
C70.33870.23480.4265
Table 12. Final weights of criteria affecting PM10 concentration values.
Table 12. Final weights of criteria affecting PM10 concentration values.
Criteria NumberFinal Weights
C10.1387
C20.1478
C30.1428
C40.1420
C50.1424
C60.1437
C70.1426
Table 13. Test of homogeneity of variance results.
Table 13. Test of homogeneity of variance results.
Levene Statisticdf1df2Sig.
7.2556770.001
Table 14. Findings of one-way ANOVA.
Table 14. Findings of one-way ANOVA.
Sum of SquaresdfMean SquareFSig.
Between Groups6117.13761019.5238.3890.002
Within Groups9358.42577121.538
Total15,475.56283
Table 15. Comparison table: significant differences between years.
Table 15. Comparison table: significant differences between years.
Years2017201820192020202120222023
2017-XXXXX
2018X-X
2019XX-XX
2020-XXX
2021XXX-XX
2022XXXX-X
2023XXXX-
-: Same year. ✓: There is a significant difference between the average PM10 concentration values.; X: There is not a significant difference between the average PM10 concentration values.
Table 16. Results of Expert Modeler in IBM® SPSS® Statistics 22.
Table 16. Results of Expert Modeler in IBM® SPSS® Statistics 22.
Model Description
Model Type
Model IDPM1010_values_after_COVID-19Model_1Simple Seasonal
Model Statistics
ModelModel Fit StatisticsLjung-Box Q(18)Number of Outliers
Stationary R-squaredR-squaredRMSEMAPEStatisticsDFSig.
PM10_values_after_COVID-19-Model_10.7320.4676.46112.78714.925160.5300
Exponential Smoothing Model Parameters
ModelEstimateSE t Sig.
PM10_values_after_ COVID-19-Model_1No TransformationAlpha (Level)0.1000.0771.2910.203
Delta (Season)4.673 × 10−50.1040.0001.000
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Güler, E.; Yerel Kandemir, S. Analysis of PM10 Substances via Intuitionistic Fuzzy Decision-Making and Statistical Evaluation. Sustainability 2024, 16, 7851. https://doi.org/10.3390/su16177851

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Güler E, Yerel Kandemir S. Analysis of PM10 Substances via Intuitionistic Fuzzy Decision-Making and Statistical Evaluation. Sustainability. 2024; 16(17):7851. https://doi.org/10.3390/su16177851

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Güler, Ezgi, and Süheyla Yerel Kandemir. 2024. "Analysis of PM10 Substances via Intuitionistic Fuzzy Decision-Making and Statistical Evaluation" Sustainability 16, no. 17: 7851. https://doi.org/10.3390/su16177851

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