Surface-Enhanced Raman Spectroscopic Investigation of PAHs at a Fe3O4@GO@Ag@PDA Composite Substrates
Abstract
:1. Introduction
2. Experimental
2.1. Materials and Apparatus
2.2. Material Synthesis
2.2.1. Synthesis of Fe3O4 Nanoparticles
2.2.2. Synthesis of Fe3O4@PDA
2.2.3. Synthesis of Fe3O4@PDA@Ag
2.2.4. Synthesis of Fe3O4@PDA@Ag@GO
3. Results and Discussion
3.1. Characterization
3.1.1. UV-Visible Characterization
3.1.2. TEM Image of Fe3O4@PDA@Ag@GO
3.1.3. XRD Characterization
3.2. Detection of PAHs with SERS Substrate
3.2.1. Sample Preparation
3.2.2. Method for Detection
3.2.3. The Detection of Phenanthrene
- Effects of each component in Fe3O4@PDA@Ag@GO on SERS detection performance
- 2.
- The influence of the mixing ratio of SERS substrate and phenanthrene solution on SERS detection performance
- 3.
- Fe3O4@PDA@Ag@GO detection limit for phenanthrene
3.2.4. Limit of Detection for Pyrene
3.2.5. Detection Limit of Benzanthracene
4. Conclusions
Author Contributions
Funding
Data Availability Statement
Conflicts of Interest
References
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Reagent | Grade | Manufacturer |
---|---|---|
Ethylene glycol | analytical purity | Chengdu Colon Chemicals Co., Ltd. (Chengdu, China) |
Methanol | analytical purity | Chengdu Colon Chemicals Co., Ltd. (Chengdu, China) |
Anhydrous ethanol | analytical purity | Chengdu Colon Chemicals Co., Ltd. (Chengdu, China) |
Polyethylene glycol | analytical purity | Beijing Chemical Reagent Co., Ltd. (Beijing, China) |
Ferric chloride hexahydrate | analytical purity | Beijing Chemical Reagent Co., Ltd. (Beijing, China) |
Silver nitrate | analytical purity | Beijing Chemical Reagent Co., Ltd. (Beijing, China) |
Sodium citrate | analytical purity | Beijing Chemical Reagent Co., Ltd. (Beijing, China) |
Phenanthrene | analytical purity | McLean Biochemical Technology Co., Ltd. (Shanghai, China) |
Pyrene | analytical purity | McLean Biochemical Technology Co., Ltd. (Shanghai, China) |
Benzanthracene | analytical purity | McLean Biochemical Technology Co., Ltd. (Shanghai, China) |
Graphene oxide dispersion | 0.5 mg/mL | Beijing Chemical Reagent Co., Ltd. (Beijing, China) |
Hydrochloric acid-dopamine | analytical purity | McLean Biochemical Technology Co., Ltd. (Shanghai, China) |
Anhydrous sodium acetate | analytical purity | Beijing Chemical Reagent Co., Ltd. (Beijing, China) |
Apparatus Names | Manufacturers | Model Number |
---|---|---|
Electronic balances | METTLER TOLEDO, Zurich, Switzerland. | XP5003S |
Thermostatic magnetic agitator | Jintan Fuhua Electric Appliance Co., Ltd. | RCT B S25 |
TG16-WS high speed centrifuge | Hunan Xiangyi Laboratory Instrument Development Co., Ltd. | TG16-WS |
SB-5200DT Ultrasonic cleaner | Ningbo Xinzhi Biotechnology Co., Ltd. | SB-5200DT |
Metage Opal 2800 spectrometer | Metage Co., London, England | Metage Opal 2800 |
50mL Stainless steel reactor | Chengdu Cologne Chemicals Co., Ltd. | PDFE |
DZF vacuum oven | Beijing Yongguangming Medical Instrument Co., Ltd. | DZF |
Electric blower drying box | Chongqing Star Test Equipment Co., Ltd. | CS101-2EB |
Spectrophotometer | Shanghai Meipuda Instrument Co., Ltd. | UV-1600PC |
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Liu, J.; Cui, W.; Sang, S.; Guan, L.; Gu, K.; Wang, Y.; Wang, J. Surface-Enhanced Raman Spectroscopic Investigation of PAHs at a Fe3O4@GO@Ag@PDA Composite Substrates. Micromachines 2022, 13, 1253. https://doi.org/10.3390/mi13081253
Liu J, Cui W, Sang S, Guan L, Gu K, Wang Y, Wang J. Surface-Enhanced Raman Spectroscopic Investigation of PAHs at a Fe3O4@GO@Ag@PDA Composite Substrates. Micromachines. 2022; 13(8):1253. https://doi.org/10.3390/mi13081253
Chicago/Turabian StyleLiu, Junyu, Wencan Cui, Shihua Sang, Liang Guan, Kecheng Gu, Yinyin Wang, and Jian Wang. 2022. "Surface-Enhanced Raman Spectroscopic Investigation of PAHs at a Fe3O4@GO@Ag@PDA Composite Substrates" Micromachines 13, no. 8: 1253. https://doi.org/10.3390/mi13081253