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Article

Boosting the Performance of Nano-Ni Catalysts by Palladium Doping in Flow Hydrogenation of Sulcatone

by
Ilona Goszewska
1,
Małgorzata Zienkiewicz-Machnik
1,
Wojciech Błachucki
2,
Adam Kubas
1,
Damian Giziński
1,3,
Krzysztof Matus
4,
Kostiantyn Nikiforow
1,
Dmytro Lisovytskiy
1,
Anna Śrębowata
1,
Jakub Szlachetko
2 and
Jacinto Sá
1,5,*
1
Institute of Physical Chemistry, Polish Academy of Sciences, 01-224 Warsaw, Poland
2
Institute of Nuclear Physics, Polish Academy of Sciences, Radzikowskiego 152, 31-342 Krakow, Poland
3
Institute of Materials Science and Engineering, Faculty of Advanced Technology and Chemistry, Military University of Technology, Kaliskiego 2 Str., 00-908 Warsaw, Poland
4
Materials Research Laboratory, Silesian University of Technology, 44-100 Gliwice, Poland
5
Department of Chemistry—Ångström Laboratory, Uppsala University, Box 532, 75120 Uppsala, Sweden
*
Author to whom correspondence should be addressed.
Catalysts 2020, 10(11), 1267; https://doi.org/10.3390/catal10111267
Submission received: 7 October 2020 / Revised: 27 October 2020 / Accepted: 29 October 2020 / Published: 2 November 2020
(This article belongs to the Special Issue Continuous-Flow Catalysis)
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Abstract

The effect of Pd doping on nano-Ni catalyst hydrogenation aptitude in sulcatone (6-methyl-5-hepten-2-one) hydrogenation was investigated. Obtained results demonstrated that the addition of non-catalytic amounts of Pd to the surface of parent Ni catalyst improves the activity to the extent that it surpassed the activity of 2.16 wt% Pd catalyst (model catalyst) at optimal reaction conditions in the flow hydrogenation of an unsaturated ketone. Pd doping improves hydrogen activation on the catalyst, which was found to be a rate-limiting step using kinetic isotopic measurements and theoretical calculations.
Keywords: chemoselective flow hydrogenation of unsaturated ketone; Pd-modified Ni nanocatalysts; increased activity; selectivity towards C=C bond saturation; kinetic isotopic studies chemoselective flow hydrogenation of unsaturated ketone; Pd-modified Ni nanocatalysts; increased activity; selectivity towards C=C bond saturation; kinetic isotopic studies
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MDPI and ACS Style

Goszewska, I.; Zienkiewicz-Machnik, M.; Błachucki, W.; Kubas, A.; Giziński, D.; Matus, K.; Nikiforow, K.; Lisovytskiy, D.; Śrębowata, A.; Szlachetko, J.; et al. Boosting the Performance of Nano-Ni Catalysts by Palladium Doping in Flow Hydrogenation of Sulcatone. Catalysts 2020, 10, 1267. https://doi.org/10.3390/catal10111267

AMA Style

Goszewska I, Zienkiewicz-Machnik M, Błachucki W, Kubas A, Giziński D, Matus K, Nikiforow K, Lisovytskiy D, Śrębowata A, Szlachetko J, et al. Boosting the Performance of Nano-Ni Catalysts by Palladium Doping in Flow Hydrogenation of Sulcatone. Catalysts. 2020; 10(11):1267. https://doi.org/10.3390/catal10111267

Chicago/Turabian Style

Goszewska, Ilona, Małgorzata Zienkiewicz-Machnik, Wojciech Błachucki, Adam Kubas, Damian Giziński, Krzysztof Matus, Kostiantyn Nikiforow, Dmytro Lisovytskiy, Anna Śrębowata, Jakub Szlachetko, and et al. 2020. "Boosting the Performance of Nano-Ni Catalysts by Palladium Doping in Flow Hydrogenation of Sulcatone" Catalysts 10, no. 11: 1267. https://doi.org/10.3390/catal10111267

APA Style

Goszewska, I., Zienkiewicz-Machnik, M., Błachucki, W., Kubas, A., Giziński, D., Matus, K., Nikiforow, K., Lisovytskiy, D., Śrębowata, A., Szlachetko, J., & Sá, J. (2020). Boosting the Performance of Nano-Ni Catalysts by Palladium Doping in Flow Hydrogenation of Sulcatone. Catalysts, 10(11), 1267. https://doi.org/10.3390/catal10111267

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