Next Article in Journal
Sustainably Sourced Mesoporous Carbon Molecular Sieves as Immobilization Matrices for Enzymatic Biofuel Cell Applications
Next Article in Special Issue
Editorial: Special Issue Entitled “Development of g-C3N4-Based Photocatalysts: Environmental Purification and Energy Conversion”
Previous Article in Journal
Enhancing the Catalytic Performance of Platinum-Doped Lanthanum Hexaaluminate through Reduction Method Variation
Previous Article in Special Issue
Recent Advances in g-C3N4 Photocatalysts: A Review of Reaction Parameters, Structure Design and Exfoliation Methods
 
 
Search for Articles:
Title / Keyword
Author / Affiliation / Email
Journal
Article Type
 
 
Advanced Search
 
Section
Special Issue
Volume
Issue
Number
Page
 
Journals
Catalysts
Volume 13
Issue 11
10.3390/catal13111414
catalysts-logo
Submit to this Journal Review for this Journal Propose a Special Issue
► Article Menu

Article Menu

share Share announcement Help format_quote Cite question_answer Discuss in SciProfiles thumb_up
...
Endorse textsms
...
Comment
first_page
settings
Order Article Reprints
Font Type:
Arial Georgia Verdana
Font Size:
Aa Aa Aa
Line Spacing:
Column Width:
Background:
Review

Recent Innovative Progress of Metal Oxide Quantum-Dot-Integrated g-C3N4 (0D-2D) Synergistic Nanocomposites for Photocatalytic Applications

by
Tejaswi Tanaji Salunkhe
1,†,
Thirumala Rao Gurugubelli
2,†,
Bathula Babu
3,* and
Kisoo Yoo
3,*
1
Department of Chemical and Biological Engineering, Gachon University, Seongnam-si 13120, Republic of Korea
2
Department of Physics, School of Sciences, SR University, Warangal 506 371, India
3
School of Mechanical Engineering, Yeungnam University, Gyeongsan 38541, Republic of Korea
*
Authors to whom correspondence should be addressed.
†
These authors contributed equally to this work.
Catalysts 2023, 13(11), 1414; https://doi.org/10.3390/catal13111414
Submission received: 6 October 2023 / Revised: 29 October 2023 / Accepted: 1 November 2023 / Published: 3 November 2023
(This article belongs to the Special Issue Development of g-C3N4-Based Photocatalysts: Environmental Purification and Energy Conversion)
Browse Figures
Versions Notes

Abstract

:
Modern industrialization has unleashed unprecedented environmental challenges, primarily in the form of pollution. In response to these pressing issues, the quest for innovative and sustainable solutions has intensified. Photocatalysis, with its unique capabilities, has emerged as a potent technology to combat the adverse effects of industrialization on the environment. This review highlights recent advances in harnessing photocatalysis to address environmental pollution. Photocatalysis offers a multifaceted approach, utilizing solar energy for catalytic reactions and enabling efficient pollutant removal. Quantum dots and graphitic carbon nitride (g-C3N4) are essential elements in this science. In contrast to quantum dots, which have enormous potential due to their size-dependent bandgap tunability and effective charge carrier production, g-C3N4 has properties like chemical stability and a configurable bandgap that make it a versatile material for photocatalysis. In this review, we explore recent achievements in integrating metal oxide quantum dots with g-C3N4, forming nanocomposites with superior photocatalytic activity. These nanocomposites exhibit extended light absorption ranges and enhanced charge separation efficiency, positioning them at the forefront of diverse photocatalytic applications. In conclusion, this comprehensive review underscores the critical role of photocatalysis as a potent tool to counteract the adverse environmental effects of modern industrialization. By emphasizing recent advancements in g-C3N4 and quantum dots and highlighting the advantages of metal oxide quantum dots decorated/integrated with g-C3N4 nanocomposites, this work contributes to the evolving landscape of sustainable solutions for environmental remediation and pollution control. These innovations hold promise for a cleaner and more sustainable future.

Graphical Abstract

1. Introduction

The ongoing march of progress, for eons, has been marked by humanity’s relentless pursuit of industrialization. From the spinning jenny to the state-of-the-art factories dotting our landscapes, industrial processes have been the harbingers of prosperity, growth, and the advancement of our species [1]. Yet, this coin possesses a tarnished flip side. Our industrial accomplishments, while monumental, have brought with them undeniable environmental degradation. However, with its plethora of benefits, industrialization inadvertently ushered in a myriad of ecological challenges. Rapid urbanization and unchecked manufacturing processes spawned large-scale environmental pollution [2,3]. As industries mushroomed, so did the emissions, leading to the degradation of both air and water quality, affecting the very tenets of human health and environmental sustainability [4,5]. Among the myriad solutions that have been tabled to combat environmental degradation, one that stands out for its potential and innovation is photocatalysis [6]. Rooted in the confluence of physics and chemistry, photocatalysis offers an avenue where pollutants are degraded under the influence of light [7]. This process is not only environment-friendly but also sustainable. The advantages of photocatalysis are manifold. Aside from its ability to degrade organic pollutants, it exhibits the potential to harness solar energy efficiently, making it an eco-friendly solution to some of the pressing challenges of our times [8].
Historically, the world of photocatalysis has witnessed the introduction and application of numerous catalysts, each bringing its own set of benefits and challenges. From the pioneering work on TiO2 to the utilization of complex organic polymers, the field has never ceased to evolve [9,10]. Among these myriad materials, the realm of 2D and 3D materials has garnered significant interest [11,12]. Their unique morphologies, structural attributes, and ease of manipulation have made them frontrunners in the race to find the most efficient photocatalyst. In recent years, a material that has captured the imagination of researchers and scientists alike is graphitic carbon nitride, or g-C3N4 [13]. This two-dimensional material, with its layered structure reminiscent of graphene, has shown exceptional promise as a photocatalyst. The journey of g-C3N4 in the photocatalytic domain has been both evolutionary and revolutionary. Various precursors, ranging from urea to dicyandiamide, have been utilized in its synthesis, leading to variations in its properties and, consequently, its photocatalytic efficiency [14]. The synthesis of g-C3N4 is as intriguing as its properties. Various precursors, including melamine, dicyandiamide, and others, have been deployed to extract this material, with each method yielding slightly varied material properties, thereby influencing its overall photocatalytic performance [15].
Yet, even the most promising of materials present challenges. Issues with g-C3N4 include quick photogenerated electron–hole pair recombination, a narrow light absorption spectrum, and certain stability concerns, which have the potential to modestly shade the material’s otherwise brilliant prospects. An innovative approach to overcoming these challenges is the hybridization of g-C3N4 with other materials, especially quantum dots, culminating in the creation of superior nanocomposites [16]. Quantum dots, particularly metal oxide quantum dots, have properties–such as size-tunable band gaps and a high surface-to-volume ratio–that are extraordinarily beneficial for photocatalysis. Their amalgamation with g-C3N4 brings forth synergistic effects, where the strengths of one complement the weaknesses of the other [17]. To combat g-C3N4′s limitations and further enhance its capabilities, researchers looked towards nanotechnology, specifically quantum dots. These nanosized semiconducting particles, notable for their quantum mechanical properties, brought several benefits [18]. Their size-dependent tunable band gaps, high surface reactivity, and ability to be easily integrated with other materials made them ideal partners for g-C3N4 [19]. Several quantum dots such as metal oxides, metal sulfides, carbon quantum dots, graphene quantum dots, etc., are integrated with g-C3N4 for superior photocatalytic performance [20,21,22,23].
Quantum size effects become prominent when the size of the semiconductor particles is reduced to the nanometer scale, approaching the exciton Bohr radius, resulting in quantum confinement. This phenomenon significantly alters the materials’ electronic and optical properties, thereby influencing their photocatalytic behavior. For instance, as the particle size of these metal oxides decreases to the quantum scale, the bandgap can broaden due to the increased energy difference between the valence and conduction bands. This bandgap modification enhances light absorption efficiency and, subsequently, the photocatalytic performance under visible light, a feature not often observed in bulk counterparts. Specifically, in the realm of photocatalysis, nanosized TiO2 and ZnO have demonstrated improved charge carrier generation due to their quantum-dot-like behavior. For instance, studies have shown that TiO2 nanoparticles, with sizes reduced to the quantum realm (below 10 nm), exhibit a shift in their optical absorption toward the visible region, a direct consequence of the quantum size effect. Similarly, ZnO quantum dots (QDs) have been observed to display a higher photocatalytic activity compared to their bulk equivalents due to their enlarged bandgap and more efficient charge separation, critical for processes like degradation of pollutants.
Within the quantum dot realm, metal oxide (TiO2, SnO2, CuO, ZnO) and metal sulfide (CdS, SnS2, MoS2) quantum dots garnered significant attention [24,25,26]. Their inherent stability, coupled with favorable electronic properties, made them especially suited for photocatalytic applications [18,27,28]. Intense study has been conducted on the combination of g-C3N4 with quantum dots, also known as 2D-0D nanocomposites [20]. Significant milestones have been achieved, demonstrating enhanced photocatalytic activities, stability, and a broader range of light absorption [29]. This narrative, rich in scientific endeavors, merits a thorough review. It is imperative to collate, analyze, and critique the vast body of work that exists on this subject. For researchers delving deeper into this domain, there exists a myriad of opportunities [30]. The optimization of synthesis methods, exploring new combinations of quantum dots, and tuning the interfaces of these nanocomposites are just a few of the avenues that hold promise [31]. As this exciting chapter in photocatalysis continues to unfold, it remains a beacon of hope for a cleaner, more sustainable future. While this review intends to offer a comprehensive overview, it also serves as a clarion call to researchers worldwide. The field of g-C3N4 and quantum dot nanocomposites, though richly explored, is brimming with possibilities. Fresh perspectives, interdisciplinary collaborations, and novel methodologies can unearth nuances previously overlooked.
Impact of particle size on charge separation and catalytic kinetics:
Quantum Confinement Effect: as particle size reduces to the nanoscale, approaching the exciton Bohr radius, quantum confinement becomes prominent. This phenomenon significantly impacts the electronic properties of semiconductors, including the bandgap’s widening. For photocatalysts, this can enhance absorption in the visible light range, crucial for solar-driven applications.
Increased Surface Area: smaller particles imply a larger surface area relative to volume, increasing the number of active sites available for reactions. This also facilitates the separation of charge carriers, as electrons and holes have shorter distances to travel to reach the surface, reducing recombination rates and enhancing photocatalytic efficiency.
Enhanced Charge Carrier Dynamics: the high surface-to-volume ratio at the nanoscale influences the redox potential of the material surface, creating more favorable conditions for charge transfer to the reactants, further discouraging charge recombination.
Catalyst–Reactant Interaction: smaller particles allow for more intimate contact with reactants due to their increased surface area, enhancing interaction frequency and energy transfer efficacy, which are critical for reaction kinetics.
Diffusion and Reaction Rates: nanosized materials modify diffusion rates of reactants and products. The shortened diffusion paths in smaller particles accelerate reaction rates, making them more efficient catalysts.
Activation Energy: the quantum size effect can modify the activation energy required for certain reactions. Quantum dots, due to their discrete energy levels, can lower the activation energy barriers, thereby accelerating the reaction kinetics.

2. Synthesis Protocols of g-C3N4

g-C3N4, an emerging two-dimensional polymer, has captivated researchers’ interest primarily due to its remarkable physicochemical properties, making it a potential candidate for various applications, including photocatalysis [13]. Its unique electronic structure, environmental compatibility, and abundant natural precursors make g-C3N4 an attractive and eco-friendly material. In this comprehensive review, we delve into the synthesis protocols, precursor variations, morphology alterations, and their corresponding implications on photocatalytic performance. The synthesis of g-C3N4 generally revolves around thermally induced polymerization of nitrogen-rich precursors. The following are notable synthesis routes: (a) Direct Thermal Polymerization—in this method, nitrogen-rich organic precursors like melamine or urea are directly heated to temperatures between 500 and 600 °C, leading to polymerization and subsequent formation of g-C3N4 [32]. (b) Solvent-assisted Synthesis—by incorporating solvents, the crystallinity and porosity of g-C3N4 can be manipulated, enhancing its performance in specific applications. (c) Microwave-assisted Synthesis—this method harnesses the rapid heating capabilities of microwaves to achieve efficient and homogenous polymerization.
Several precursors for g-C3N4 synthesis, distinguished by their nitrogen content, can be employed for g-C3N4 synthesis: (a) Melamine—owing to its high nitrogen content, melamine is a widely preferred precursor. It affords good crystallinity and relatively more uncondensed amino groups, beneficial for certain applications [33]. (b) Urea—a more economical alternative, urea can be directly polymerized to yield g-C3N4. However, urea-derived g-C3N4 often displays inferior crystallinity [32]. (c) Dicyandiamide—it serves as an intermediate between melamine and urea in terms of the nitrogen content and resulting material properties [34]. The morphological attributes of g-C3N4 are significantly dictated by the thermal treatment it undergoes (Figure 1). Two parameters, the duration and ramping rate of the heating process, play pivotal roles: (a) Temperature Duration—extended heating times can refine the crystalline structure but might lead to an over-condensed framework, reducing activity in certain applications [32]. (b) Ramping Rate—a rapid ramping rate can cause abrupt polymerization, potentially resulting in non-uniform morphology. Gradual heating, on the other hand, allows a more ordered structure to be formed.
Over the years, researchers have reported a diverse array of g-C3N4 morphologies like nanosheets, nanorods, nanolayers, etc., due to their specific reasons [36]. Bulk g-C3N4 provides the primary structure obtained from direct thermal polymerization, characterized by its layered architecture. g-C3N4 nanosheets are thin, 2D planar structures that exhibit a higher surface area compared to the bulk counterpart. g-C3N4 nanorods are one-dimensional nanostructures offering directional pathways for charge transport. g-C3N4 nanolayers are ultrathin variants of nanosheets, further maximizing the surface area. g-C3N4 porous nanosheets introducing porosity can facilitate greater substance interaction and accessibility [37].
Several strategies exist to induce desired morphological changes in g-C3N4. (a) Exfoliation: mechanical or chemical means can be employed to delaminate bulk g-C3N4, producing nanosheets [38]. (b) Template Method: using sacrificial templates, g-C3N4 can be cast into specific morphologies, like rods or spheres, which are subsequently removed [39]. (c) Direct Synthesis: by manipulating synthesis conditions, such as precursor concentration or solvent choice, varied morphologies can be achieved [40]. The morphological modifications directly impact g-C3N4’s performance in photocatalysis. Enhanced surface area, improved light absorption, efficient charge separation, and facile substance accessibility are some of the benefits brought by morphology optimization. From its synthesis from diverse precursors to the myriad morphologies it can adopt, g-C3N4 offers an exciting playground for materials scientists and engineers. As our understanding of its structure–performance relationship deepens, fine-tuned g-C3N4 materials, specifically designed for target applications, can be anticipated. By marrying the principles of green chemistry with advanced characterization and simulation techniques, the next chapter in the g-C3N4 saga is set to be even more promising.
Role of advanced spectroscopic techniques:
Researchers must know the importance of understanding the underlying mechanisms responsible for the high photocatalytic activity of g-C3N4-QD nanocomposites.
Absorption and Bandgap Analysis: enhanced absorption in the visible-light region is a key indicator of improved photocatalytic activity. When quantum dots (QDs) are integrated with g-C3N4, a noticeable shift in the absorption edge towards longer wavelengths can be observed. This suggests a reduced bandgap, allowing the composite to harness a greater portion of the solar spectrum. A reduced bandgap often leads to increased electron–hole pair generation, thus driving photocatalytic reactions more efficiently [26].
Photoluminescence (PL) Spectroscopy: PL studies offer invaluable insights into the recombination rates of photoinduced electron–hole pairs. For an effective photocatalyst, the suppression of this recombination is crucial. Post integration of QDs with g-C3N4, a significant quenching or decrease in the PL intensity can be observed, signifying reduced recombination rates. This reduced recombination, as evidenced by the PL studies, supports the notion of heightened photocatalytic performance of the composite [19].
X-ray Photoelectron Spectroscopy (XPS): XPS is instrumental in probing the surface electronic states of materials. Upon forming a heterojunction between g-C3N4 and QDs, shifts in the XPS peak positions can be noticed, indicating a change in the electronic environment and suggesting charge transfer between the constituents. The altered intensities can hint at the difference in elemental composition, showcasing the successful integration of QDs onto g-C3N4. Such charge transfer is paramount for separating the photogenerated electron–hole pairs, thereby enhancing the photocatalytic efficiency [21].
Other Spectroscopic Techniques: Electron Paramagnetic Resonance (EPR) can be employed to detect photoinduced radical species, directly supporting the photocatalytic activity of the material. Additionally, techniques like Fourier-transform infrared spectroscopy (FTIR) can offer insights into the surface functional groups, ensuring the stability and integrity of the composite during photocatalytic reactions [24].

3. Metal Oxide QD-g-C3N4 Nanocomposites

Advantages of quantum dots over nanoparticles:
Size and Quantum Confinement: the primary distinction lies in the size. Quantum dots are typically smaller than nanoparticles and are in the range of 1–10 nanometers (approximately 10–50 atoms in diameter). At this scale, quantum effects significantly influence the material’s properties, leading to phenomena like quantum confinement in semiconductor QDs, which is not observed in larger nanoparticles. This results in unique optical, electronic, and catalytic properties for QDs.
Optical Properties: due to quantum confinement, QDs exhibit size-dependent tunable photoluminescence, allowing them to absorb and emit light over a wide spectrum. This property is crucial for various applications, including photocatalysis, and is not prominently observed in larger nanoparticles.
Surface Properties: the high surface-to-volume ratio of QDs leads to a significant proportion of atoms being at the surface, which profoundly impacts their chemical reactivity and catalytic activity. While nanoparticles also have a high surface-to-volume ratio, the quantum effects in QDs enhance these surface-related properties.
Energy Band Structures: the discrete energy levels in QDs, a consequence of quantum confinement, differ substantially from the continuous band structure of bulk materials or larger nanoparticles. This affects their interaction with light, charge carrier generation, and transfer—critical factors in photocatalytic processes.

3.1. Wide-Bandgap Metal Oxide QD-g-C3N4 Nanocomposites

In recent half-decade research, TiO2 quantum dots (QDs) have solidified their position as stalwarts in the realm of nanotechnology, largely attributed to their exceptional photocatalytic proficiencies [41]. These quantum entities hold immense promise in efficiently absorbing solar energy, paving the way for their integration into an array of environmental and energy-focused applications. Properties intrinsic to TiO2 QDs set them apart in the vast quantum landscape. The quantum confinement effect empowers them with a modifiable bandgap, a boon for diversifying photocatalytic ventures. Their magnified surface-to-volume ratio augments their inherent reactivity, and their commendable photostability ensures longevity in demanding applications [42]. As for their real-world implications, these QDs shine in water purification, adeptly obliterating organic contaminants. Their prowess extends to hydrogen production, where they serve as linchpins in photoelectrochemical water splitting. Furthermore, their capabilities in air purification, specifically in annihilating noxious air pollutants, have been documented. In essence, the ongoing research narrative accentuates the transformative potential of TiO2 QDs, suggesting a luminous path ahead in environmental rejuvenation and sustainable energy paradigms. According to Wang et al., creating a p-TiO2 QDs@g-C3N4 p-n junction results in better photocatalytic performance than using pure g-C3N4. The improved performance is a result of the p-n heterojunction, strong interface interaction, and quantum-size impact [43]. Wang (2021) synthesized an F-doped TiO2 quantum dot/g-C3N4 nanosheet Z-scheme photocatalyst through chemical bonding, resulting in improved oxidizability, reducibility, and interfacial charge transfer ability [44]. Lee (2023) created a 0D/2D heterojunction nanocomposite with TiO2 quantum dots anchored on g-C3N4 nanosheets (Figure 2) that demonstrated accelerated solar-driven photocatalysis [45]. The integration of anatase/rutile homojunction quantum dots onto g-C3N4 nanosheets, which is intended to target the breakdown of antibiotics in saltwater matrices, was documented by Hu and colleagues. Their study delves into the combined mechanism of adsorption and photocatalysis, shedding light on its underlying intricacies. They further evaluated the ternary heterojunctions formed between anatase/rutile quantum dots (QDs) and g-C3N4, emphasizing their effectiveness in the removal of Oxytetracycline (OTC). Additionally, the research gauges the toxicity levels of the resultant intermediates detected post-process [24].
In recent years, the world of nanotechnology has seen an upswing in interest towards SnO2 quantum dots (QDs), primarily owing to their potent capabilities in photocatalysis [46]. These quantum dots excel in efficiently harnessing light, thereby driving effective charge separation and curbing recombination—traits indispensable for successful photocatalysis. Delving into their synthesis, several cutting-edge methods have emerged over the past half-decade. The hydrothermal method, which revolves around reacting tin salts in water under specific temperature and pressure conditions, remains a favored choice [47]. However, the sol-gel approach, where a precursor solution transitions from a gel-like consistency to the desired quantum dots upon drying and calcination, is also prevalent [46]. Not to be overshadowed, the microwave-assisted synthesis leverages the power of uniform and rapid microwave heating, often resulting in SnO2 QDs of superior crystallinity in a fraction of the conventional synthesis time [48]. What truly sets SnO2 QDs apart are their intrinsic properties. The quantum confinement effect grants researchers the liberty to tweak their bandgap, ensuring adaptability for a range of light-driven reactions. Their nanoscale stature bestows upon them a vast surface area, ideal for fostering enhanced reactant interactions. Furthermore, they stand out in the quantum dot family for their remarkable chemical and thermal stability. On the application front, these QDs have been instrumental in several arenas, from water splitting, where they play a role in converting water into hydrogen fuel using sunlight, to the degradation of persistent organic pollutants in water [49]. Another noteworthy application is their potential in reducing CO2, where they can transform atmospheric carbon dioxide into valuable fuels, presenting a promising avenue to combat escalating CO2 levels [50]. Recent studies and trends hint that the true potential of SnO2 QDs, especially when amalgamated with complementary materials, is yet to be fully unlocked, holding promises for advances in sustainable energy and environmental solutions.
SnO2 quantum dots (QDs) with graphitic carbon nitride (g-C3N4) can improve photocatalytic activity. In 2018, Babu found that when exposed to sunlight, the mixture of SnO2 QDs and g-C3N4 nanolayers displayed increased photocatalytic performance, effectively breaking down methyl orange. This increase in sunlight-driven photocatalytic activity is attributed to the cooperative interaction between the g-C3N4 nanolayers and SnO2 quantum dots. These results highlight the potential of g-C3N4 nanolayers and SnO2 QDs as powerful sunlight-responsive photocatalysts, particularly for the degradation of pollutants like methyl orange [27]. In 2019, Yousaf noted a marked increase in photocatalytic performance upon the embellishment of g-C3N4 with SnO2 QDs, which led to the successful decomposition of Rhodamine B. The relative proportion of SnO2 to g-C3N4 in these nanohybrids plays a pivotal role in determining their photocatalytic efficacy (Figure 3). Such findings highlight the potency of SnO2/g-C3N4 nanocomposites, particularly in the domain of degrading contaminants like Rhodamine B (RhB) in solutions [51]. In 2017, Ji pioneered the synthesis of a composite photocatalyst combining SnO2 with graphene-like g-C3N4. This composite exhibited superior visible-light-driven activities in degrading organic pollutants. Remarkably, its optimal photocatalytic efficiency under visible light exposure surpassed that of SnO2 and g-C3N4 by almost 9 and 2.5 times, respectively [52]. The synergy between SnO2 and graphene-like g-C3N4 is highlighted in this composite, which is represented as SnO2/graphene-like g-C3N4, underlining its potential in photocatalytic processes. Its process in the degradation of Rhodamine B (RhB) with visible light in particular provides encouraging insights into its functional possibilities. All of these results point to the possibility that SnO2 quantum dots and g-C3N4 work better together to accelerate photocatalytic breakdown of organic contaminants in water.
Zinc oxide (ZnO) quantum dots have shown significant promise for photocatalytic applications, driven by their unique physicochemical properties. ZnO quantum dots exhibit enhanced photocatalytic efficiency owing to their high surface area and quantum confinement effects [53]. Their ability to generate reactive oxygen species upon light irradiation makes them potent catalysts for degrading organic pollutants. Researchers have delved into surface modifications to improve the photocatalytic performance of ZnO quantum dots [54]. Techniques like doping, coating, or hybridizing with other materials have been shown to enhance their stability and photocatalytic activity. The advent of black ZnO quantum dots has opened up the possibility of utilizing visible light, significantly broadening the spectrum of light that can be used for photocatalytic applications. Innovations in the design of heterostructures with ZnO quantum dots have shown promise in promoting charge separation, which is crucial for efficient photocatalysis. ZnO quantum dots have found real-world applications in water treatment, air purification, and energy conversion, embodying the translation of academic research to practical solutions [55]. Studies have showcased the robustness of ZnO quantum dots in diverse environmental conditions, highlighting their potential for outdoor applications. The integration of ZnO quantum dots with other nanomaterials like graphitic carbon nitride has led to the creation of novel nanocomposites with superior photocatalytic properties [56]. Ren et al. created a composite by mixing graphitic carbon nitride (g-C3N4) and ZnO quantum dots (QDs) with the goal of enhancing the material’s photocatalytic properties. It was impressive to see how well the composite degraded Rhodamine B when exposed to visible light. A 96.8% degradation rate of Rhodamine B was attained under visible light within a 40 min window, which was a startling achievement. This heightened photocatalytic efficacy is believed to emanate from the synergistic interplay between ZnO QDs, GO, and g-C3N4. The separation of photogenerated electron–hole pairs was accelerated with this combination [57]. In conclusion, the ZnO QD/GO/g-C3N4 composite emerges as a potent contender for the remediation of organic pollutants in wastewater, presenting a workable solution for real-world wastewater treatment scenarios. This is due to its potent photocatalytic performance under visible light and its impressive durability. Investigating the visible-light-induced photocatalytic behavior of SnO2-ZnO quantum dots attached to g-C3N4 nanosheets was the goal of Vattikuti et al. The two main areas of concern were the degradation of contaminants and the creation of H2. They successfully anchored SnO2-ZnO quantum dots onto g-C3N4 nanosheets with their efforts. The resultant composite manifested heightened photocatalytic prowess when exposed to visible light, especially evident in its commendable degradation rates for contaminants like RhB and phenol. When the data were analyzed, it was discovered that the composite’s RhB degradation rate was 3.5 times greater than that of pure g-C3N4. Similar to this, phenol’s rate of degradation was 2.8 times more rapid than that of g-C3N4. Additionally, it was found that the composite’s capacity to produce H2 was astonishingly 4.6 times greater than that of pure g-C3N4. From these results, it is clear that the SnO2-ZnO quantum dots, when attached to g-C3N4 nanosheets, significantly improve photocatalytic activity when exposed to visible light. This composite not only excels at degrading pollutants but also evinces significant potential in H2 production. Such attributes earmark it as a viable solution for tasks ranging from environmental purification to fostering sustainable energy methodologies [58].

3.2. Bi-Based QD-g-C3N4 Nanocomposites

Bismuth-based quantum dots (QDs) have emerged as a captivating class of nanostructured semiconductors, drawing substantial interest because of their unique electronic, optical, and photocatalytic characteristics. Their size-dependent bandgaps offer specific tunability for photocatalytic reactions. BiVO4 QDs [59], for instance, display improved light absorption due to quantum confinement effects, and they are recognized for their proficiency in visible-light-driven water splitting and pollutant degradation (Figure 4). Bismuth oxide (Bi2O3) QDs exhibit enhanced optical attributes and charge transfer characteristics, positioning them as formidable catalysts for UV and visible light pollutant degradation [31,60]. Bi2WO6 QDs, with their increased electron–hole separation at the quantum level, stand out in degrading diverse organic pollutants under visible light [61]. While Bi2O4 QDs are relatively less explored, they have demonstrated potential with amplified light interaction at the nanoscale and offer efficient photocatalytic reactions. Lastly, Bi2MoO6 quantum dots, known for their extended photogenerated charge carrier lifetimes, are potential frontrunners for organic compound degradation and hydrogen evolution tasks [62]. In a nutshell, the nano-dimensionality of bismuth-based QDs accentuates their photocatalytic performance by amplifying light absorption, optimizing charge transfer, and minimizing recombination, making them versatile contenders for an array of photocatalytic applications. The scientists wanted to create a ternary heterostructure comprising C60, g-C3N4, and BiVO4 quantum dots as a photocatalyst. This was carried out to increase the photocatalytic activity when exposed to visible light. Under visible light irradiation, the synthesized ternary heterostructure shown improved photocatalytic activity. Compared to binary heterostructures and pure g-C3N4, the ternary heterostructure showed a greater photocatalytic degradation rate of Rhodamine B (RhB) [59]. The higher charge separation efficiency and expanded light absorption range were credited with the better photocatalytic performance. The potential mechanisms underlying the ternary heterostructure’s improved photocatalytic activity were discussed by the researchers. They emphasized how C60 and BiVO4 quantum dots worked together to promote charge separation and lessen recombination. The enhanced photocatalytic efficiency of the ternary heterostructure was also attributed to a wider light absorption range. In comparison to other structures, the ternary heterostructure of BiVO4 quantum dots/C60/g-C3N4 was effectively constructed and showed higher photocatalytic activity. The study offers suggestions for creating effective photocatalysts for a variety of uses, including environmental cleanup.
Liang et al. looked at how well Bi2O3 QDs/g-C3N4 performed as a photocatalyst for both organic and inorganic contaminants. Tetracycline (TC) and Cr (VI) were chosen as representative environmental pollutants to assess the effectiveness of the samples’ photocatalytic reduction and oxidation [60]. Under light illumination, the photocurrent density of the Bi2O3 QDs/g-C3N4 (ii) was noticeably higher than that of the g-C3N4, E-g-C3N4, and Bi2O3 QDs/g-C3N4, showing better charge transfer efficiency. Bi2O3 QDs/g-C3N4 had the shortest semicircular arc diameter, according to EIS Nyquist plots, indicating the lowest charge transfer resistance and quickest interfacial charge transport. Scavengers had an impact on the effectiveness of TC’s degradation, proving that certain radicals were involved in the process. Byproducts of TC were produced using photocatalytic mineralization processes, with some intermediates demonstrating decreased toxicity after photocatalytic degradation. Bi2O3 QDs/g-C3N4 underwent photoinduction to improve the separation and transfer of photogenerated charges. As model environmental pollutants, TC and Cr (VI) were used to assess the photocatalytic performance. For Bi2O3 QDs/g-C3N4, the results showed increased charge transfer effectiveness and quicker interfacial charge transport. The research showed that Bi2O3 QDs/g-C3N4 had the potential to be an efficient photocatalyst for the oxidation of both organic and inorganic contaminants. Its better photocatalytic performance was aided by its improved charge transfer efficiency and decreased charge transfer resistance. The research offers a potential method for creating highly scattered metal oxides on 2D lamella semiconductors, expanding the photocatalyst’s usefulness for removing a variety of environmental pollutants. Zeng et al. concentrated on the logical application of quantum dots (QDs) and graphitic carbon nitride (g-C3N4) semiconductors to increase their effectiveness as photocatalysts. The integration of g-C3N4 with QDs was intended to increase photogenerated electron transfer efficiency and produce significant photocatalytic activity. The researchers created brand-new Bi2WO6 QD/g-C3N4 nanocomposites with attapulgite (ATP) penetration [61]. The outcomes demonstrated that the ATP with a nanorod shape served as bridges to intercalate into the interlayers, thus enlarging the g-C3N4 inner space. With the use of an HPLC-MS system, the samples’ photocatalytic degradation activities were examined. Using a specified formula, the degrading effectiveness of MBT in the solution was determined. The MBT solution was broken down while being exposed to radiation to gauge the photocatalytic performance. We examined the rate of MBT degradation in several samples and investigated the photocatalytic degradation processes. The BCA5 sample exhibited favorable photoelectric characteristics, which indicated quick interfacial charge movement and low resistance for the production of charge carriers. As a potential strategy for future photocatalytic applications, the integration of g-C3N4 and QDs with the interpenetration of ATP led to improved photocatalytic performance. In order to create a 2D-0D g-C3N4/Bi2WO6-OV composite catalyst, Cheng et al. combined two-dimensional (2D) graphite carbon nitride (g-C3N4) nanosheets with oxygen-containing vacancy zero-dimensional (0D) Bi2WO6 (BWO-OV) quantum dots [31]. The goal was to improve the catalyst’s catalytic activity, increase the formation of photogenerated carriers, and improve light absorption. Utilizing Bi2WO6 with oxygen vacancies, which improved light absorption while simultaneously increasing the production of photogenerated carriers, was the novel method. The vacancy structure of Bi2WO6 and the heterojunction’s creation both contributed to the photogenerated carriers’ longer longevity. The composite of CN/BWO-OV-10 displayed the maximum intensity, indicating a greater capacity for NO degradation. The outcomes of the trapping tests revealed that superoxide radicals, holes, and electrons all contribute significantly to the photocatalytic reaction. Furthermore, hydroxyl is recognized as a less potent active free radical. By eliminating NO, the photocatalytic effectiveness was evaluated. The efficiency peaked at 61.2% when BWO-OV was 10% by mass of the total amount of CN. The CN/BWO composite demonstrated the superiority of CN/BWO-OV-10 with a rise in efficiency of 3.2%, achieving a degradation efficiency of 58%. At room temperature, the composite g-C3N4/Bi2WO6-OV structure removed nitric oxide (NO) at a rapid rate despite its low concentration. The composite catalyst’s efficiency was higher than that of g-C3N4 or BWO-OV and superior to that of g-C3N4/Bi2WO6 without oxygen vacancies. The best catalytic activity was demonstrated with the composite g-C3N4/Bi2WO6-OV-10, reaching up to 61.2%. The substance also demonstrated outstanding stability throughout several iterations of experimentation.
Ding and co. investigated Bi2MoO6 QDs/g-C3N4 with heterojunctions for their potential in the selective oxidation of aromatic alkanes into aldehydes under visible-light-driven catalysis [62]. The study offers fresh insights into the manufacturing of 0D/2D photocatalysts with heterojunctions for effective selective oxidation of C(sp3)-H bonds (Figure 5). It also presents a novel structure that improves the separation of charge carriers. Outstanding visible-light-driven catalytic performance was shown with the Bi2MoO6 QD/g-C3N4 heterojunction in the selective oxidation of aromatic alkanes into aldehydes. The heterojunction’s special structure, which facilitates the effective separation of charge carriers, is said to be responsible for the increased photocatalytic activity. Superior photocatalytic activity was demonstrated with the heterojunction of Bi2MoO6 QDs/g-C3N4, particularly in the selective oxidation of aromatic alkanes. The distinctive structure that enables greater charge carrier separation is responsible for this performance. Under visible light, the Bi2MoO6 QD/g-C3N4 heterojunction exhibits outstanding photocatalytic activity in the selective oxidation of aromatic alkanes to aldehydes. The distinctive structure, which improves charge carrier separation, is credited with the efficiency. The potential of 0D/2D photocatalysts with heterojunctions for the selective oxidation of C(sp3)-H bonds is crucial information provided in this study.

3.3. Other Metal Oxide QD-g-C3N4 Nanocomposites

Sun et al. sought to create CeO2 quantum dots anchored on g-C3N4 (CeO2/g-C3N4) and examine the photocatalytic performance of the material [63]. The creation of CeO2 quantum dots anchored on g-C3N4—which are anticipated to have improved photocatalytic properties—represents the work’s originality (Figure 6). It is anticipated that the combination of these materials will enhance charge separation and increase the light absorption range. XRD, FTIR, SEM, TEM, XPS, and PL were used to characterize the synthesized CeO2/g-C3N4. The outcomes demonstrated a homogeneous distribution of CeO2 quantum dots on the g-C3N4 nanosheets. Better light absorption was discovered to be indicated with the bandgap of CeO2/g-C3N4 being narrower than that of pure g-C3N4. By observing the degradation of Rhodamine B (RhB) under visible light irradiation, the photocatalytic performance was assessed. Compared to pure g-C3N4, the CeO2/g-C3N4 demonstrated improved photocatalytic activity. The better charge separation and expanded light absorption range brought on with the presence of CeO2 quantum dots are credited with the improved performance. Rhodamine B degradation under visible light showed higher photocatalytic performance from the CeO2/g-C3N4 combination. This improved performance is a result of the cooperative action of g-C3N4 and CeO2 quantum dots, which improves charge separation and light absorption. Although the exact findings section was not directly extracted, it may be deduced from the information given that the researchers were successful in creating CeO2 quantum dots anchored on g-C3N4 with enhanced photocatalytic characteristics. Its improved Rhodamine B degradation under visible light made the composite material an attractive option for photocatalytic applications.
In order to create a novel photocatalyst, Zhu et al. combined g-C3N4 nanosheets and MoO3 quantum dots (QDs). This mixture was created with the goal of improving photocatalytic activity for the reduction in U(VI) under visible light. The addition of MoO3 QDs to g-C3N4 nanosheets is what makes this work novel [19]. Following their easy hydrothermal synthesis, the MoO3 QDs were loaded onto g-C3N4 nanosheets using a straightforward ultrasonic dispersion technique. This mixture was predicted to facilitate photogenerated electron–hole pair separation and improve photocatalytic activity. The MoO3 QD/g-C3N4 nanosheets showed remarkable photocatalytic performance for U(VI) reduction when exposed to visible light in their as-prepared state. It was discovered that MoO3 QDs should be loaded at a rate of 2%. The efficient separation of photogenerated electron–hole pairs and the expanded light absorption range were credited with the improved photocatalytic activity. Various characterization approaches were used to support the postulated photocatalytic mechanism. By measuring the concentration of U(VI) in aqueous solutions while they were exposed to visible light, the photocatalytic performance was assessed. The outcomes demonstrated that the photocatalytic reduction rate for U(VI) was greater in the MoO3 QD/g-C3N4 nanosheets than in pure g-C3N4. It can be concluded that g-C3N4 nanosheets in combination with MoO3 QDs present a viable method for improving the photocatalytic reduction in U(VI) under visible light. The proposed mechanism and the innovative photocatalyst design offer important new perspectives for this field’s future study. The detailed description of recent research on the photocatalytic abilities of nanocomposites based on metal oxide QD’s-g-C3N4 were provided in Table 1.
Zhao et al. set out to create phosphorus-doped g-C3N4/Co3O4 quantum dots in a single step using vitamin B12. They sought to increase the synthesized substance’s visible-light photocatalytic activity for the destruction of metronidazole (MTZ) [18]. The innovative aspect of the process is the one-step production of phosphorus-doped g-C3N4/Co3O4 quantum dots using vitamin B12. This technique is distinctive because it enhances the photocatalytic performance of g-C3N4 by combining the traits of both phosphorus doping and Co3O4 quantum dots. Several approaches were used to characterize the synthesized composites. The photodegradation of MTZ under visible light irradiation was used to assess the photocatalytic activities of the composites. The explanation for the increased photocatalytic activity was determined to be the synergistic interaction between the produced Co3O4 quantum dots and P-doped g-C3N4. This interaction improved photo-induced electron and hole separation efficiency, prevented their recombination, and reduced band gap energy. The generated Co3O4 quantum dots and P-doped g-C3N4 worked together to enhance the photocatalytic performance of the created material. As a result of this synergy, photoinduced electrons and holes were separated and transferred more effectively, which increased the photocatalytic degradation of MTZ. The study successfully demonstrated the synthesis of g-C3N4/Co3O4 quantum dots doped with phosphorus utilizing a one-step procedure and vitamin B12. The created substance demonstrated improved visible-light photocatalytic activity for the breakdown of MTZ. The fundamental causes of the enhanced photocatalytic performance were determined to be the synergistic interactions between the produced Co3O4 quantum dots and P-doped g-C3N4.
The heterojunctions formed between traditional QDs like CdS/CdSe and g-C3N4 have demonstrated effective charge separation due to their staggered band alignment, which minimizes recombination and enhances photocatalytic performance. We discussed how these strategies of interface engineering can be applied to metal oxide QDs to optimize their interactions with g-C3N4, focusing on creating synergistic band alignments that facilitate charge transfer and extend light absorption. In-depth analyses of the photocatalytic mechanisms in CdS/CdSe and Ag-In-Zn-S QDs combined with g-C3N4 have revealed critical factors such as quantum confinement effects, surface states, and the role of co-catalysts in improving photocatalytic activity. By integrating these insights, we will elaborate on how similar principles might govern the activity of metal oxide QDs, and how understanding these mechanisms can guide the optimization of their photocatalytic performance. Drawing parallels between the successes of these traditional QDs and our subject metal oxide QDs, we will discuss how strategies like precise size control, doping, or the introduction of defects, successful in traditional QDs, can be mirrored in metal oxides to modulate band structure, enhance light absorption, and improve charge carrier dynamics. While acknowledging the efficiency of traditional QDs, we also recognize concerns regarding their toxicity and environmental impact, particularly for Cd-based QDs. This contrast presents an opportunity to highlight the relative environmental friendliness of metal oxide QDs and the importance of pursuing these materials for sustainable photocatalysis.
Carbon quantum dots (CQDs) have emerged as a captivating class of carbon nanomaterials, characterized by their unique optical, electrical, and physicochemical properties. These properties, combined with their aqueous stability, low toxicity, high surface area, economic feasibility, and tunable photoluminescence behavior, make them promising candidates for photocatalytic applications. On the other hand, graphitic carbon nitride (g-C3N4) has gained attention as a stable carbon-based polymer with potential applications in various fields. The combination of CQDs and g-C3N4 offers a synergistic effect, enhancing the adsorptive and photocatalytic activity of the resulting nanocomposite. This is attributed to the broader visible-light absorption, increased specific surface area, and enhanced electron–hole pair migration and separation efficiency of the composite. Comparatively, while metal oxide quantum dots also present potential in photocatalytic applications, the CQDs and g-C3N4 combination stands out due to its non-toxic nature, economic feasibility, and enhanced photoluminescence properties. The interaction within this multicomponent photocatalyst promotes photocatalytic performance, making it a superior choice for wastewater treatment and other environmental applications. In essence, the amalgamation of CQDs and g-C3N4 presents a novel and efficient approach to address the challenges of wastewater treatment, emphasizing the importance of continued research in this domain [93].

4. Conclusions and Perspectives

Quantum dots (QDs) and graphitic carbon nitride (g-C3N4) together highlight a developing area of study with the potential to advance the photocatalytic frontier. Harnessing the unique electronic, optical, and photocatalytic properties intrinsic to QDs such as ZnO, SnO2, TiO2, CeO2, CO3O4, MoO3, BiVO4, Bi2O3, Bi2WO6, Bi2O4, and Bi2MoO6, when juxtaposed with the properties of g-C3N4, promises a synergy that could redefine the boundaries of photocatalysis. As we reflect on our discussions, let us draw some conclusions and speculate on future avenues.
Synergy of QDs with g-C3N4: quantum dots and g-C3N4 can be used to enhance light absorption, improve charge transfer, and reduce electron–hole recombination. This enhances their overall photocatalytic efficacy and paves the way for efficient light-driven reactions, particularly those aimed at energy conversion and environmental remediation.
Diverse Quantum Dot Landscape: each QD brings its unique characteristics. For instance, ZnO and TiO2 QDs have been heralded for their UV light-driven photocatalytic activities, while the bismuth-based QDs such as BiVO4, Bi2O3, and Bi2WO6 exhibit visible light-driven capabilities. The inherent bandgap variations, coupled with different photocorrosion resistances and surface chemistries, provide a diverse landscape for tailoring the desired photocatalytic response.
Enhanced Stability and Sustainability: one of the perennial challenges with photocatalysts is their stability and recyclability. g-C3N4’s structural robustness, when combined with the protective attributes of QDs, leads to prolonged catalyst life, thereby elevating the potential for sustainable and scalable applications.
Heterostructuring and Multifunctionality: in addition to enhancing the activity of the quantum dots, the addition of g-C3N4 also brings multifunctionality. The heterostructures formed can serve as platforms for multiple simultaneous reactions, like water splitting alongside organic pollutant degradation, creating avenues for multifaceted photocatalytic systems.

5. Future Perspectives

Tailored Photocatalytic Systems: given the plethora of QDs available, future research should focus on systematically tailoring QD-g-C3N4 combinations to target specific photocatalytic reactions. This tailoring could lead to breakthroughs in reaction efficiency and selectivity.
Deep Dive into Charge Dynamics: to optimize the QD-g-C3N4 interfaces further, a comprehensive understanding of charge dynamics, including the rates of charge transfer, recombination, and trapping, is crucial. Advanced spectroscopic and microscopic techniques could elucidate these intricacies.
Scale-up and Real-world Applications: the transition from lab-scale research to real-world applications requires addressing challenges related to catalyst scale-up, stability under fluctuating environmental conditions, and integration with existing industrial setups.
Holistic Environmental Impact: as we push the boundaries of photocatalysis, it is imperative to ensure the green synthesis of these QD-g-C3N4 systems, minimizing any adverse environmental footprints and maximizing their eco-friendly applications.
Z-Schemes and Ternary Nanocomposites: researchers have the opportunity to explore and construct Z-scheme-based systems using QDs and g-C3N4. Additionally, there is potential for designing ternary nanocomposites, such as metal oxide QD-g-C3N4-noble metals, metal oxide QD-g-C3N4-carbon-related materials, and more.
In closing, the fusion of quantum dots with g-C3N4 heralds a new era in photocatalysis. The potential breakthroughs discussed here are just the tip of the iceberg. As research intensifies, the full spectrum of possibilities will undoubtedly be unveiled, driving a cleaner, greener, and energy-efficient future.

Author Contributions

Conceptualization, methodology, validation, writing—original draft preparation, T.T.S.; formal analysis, resources, data curation, writing—original draft preparation, T.R.G.; writing—review and editing, supervision, B.B.; supervision, project administration, funding acquisition, K.Y. All authors have read and agreed to the published version of the manuscript.

Funding

This work was supported with a National Research Foundation of Korea (NRF) grant funded by the Korean government (MSIT) (No. 2021R1C1C1011089).

Data Availability Statement

Not applicable.

Conflicts of Interest

The authors declare that they have no conflict of interest regarding the publication of this article, financial and/or otherwise.

References

  1. Opoku, E.E.O.; Boachie, M.K. The environmental impact of industrialization and foreign direct investment. Energy Policy 2020, 137, 111178. [Google Scholar] [CrossRef]
  2. Tran, V.V.; Park, D.; Lee, Y.-C. Indoor Air Pollution, Related Human Diseases, and Recent Trends in the Control and Improvement of Indoor Air Quality. Int. J. Environ. Res. Public Health 2020, 17, 2927. [Google Scholar] [CrossRef] [PubMed]
  3. Antoci, A.; Galeotti, M.; Sordi, S. Environmental pollution as engine of industrialization. Commun. Nonlinear Sci. Numer. Simul. 2018, 58, 262–273. [Google Scholar] [CrossRef]
  4. Siddiqua, A.; Hahladakis, J.N.; Al-Attiya, W.A.K.A. An overview of the environmental pollution and health effects associated with waste landfilling and open dumping. Environ. Sci. Pollut. Res. 2022, 29, 58514–58536. [Google Scholar] [CrossRef]
  5. Manisalidis, I.; Stavropoulou, E.; Stavropoulos, A.; Bezirtzoglou, E. Environmental and Health Impacts of Air Pollution: A Review. Front. Public Health 2020, 8, 14. [Google Scholar] [CrossRef]
  6. He, J.; Kumar, A.; Khan, M.; Lo, I.M.C. Critical review of photocatalytic disinfection of bacteria: From noble metals- and carbon nanomaterials-TiO2 composites to challenges of water characteristics and strategic solutions. Sci. Total Environ. 2021, 758, 143953. [Google Scholar] [CrossRef]
  7. Wei, Z.; Liu, J.; Shangguan, W. A review on photocatalysis in antibiotic wastewater: Pollutant degradation and hydrogen production. Chin. J. Catal. 2020, 41, 1440–1450. [Google Scholar] [CrossRef]
  8. Zhang, F.; Wang, X.; Liu, H.; Liu, C.; Wan, Y.; Long, Y.; Cai, Z. Recent Advances and Applications of Semiconductor Photocatalytic Technology. Appl. Sci. 2019, 9, 2489. [Google Scholar] [CrossRef]
  9. Guo, Q.; Zhou, C.; Ma, Z.; Yang, X. Fundamentals of TiO2 Photocatalysis: Concepts, Mechanisms, and Challenges. Adv. Mater. 2019, 31, 1901997. [Google Scholar] [CrossRef]
  10. Wang, J.; Guo, R.-T.; Bi, Z.-X.; Chen, X.; Hu, X.; Pan, W.-G. A review on TiO2−x-based materials for photocatalytic CO2 reduction. Nanoscale 2022, 14, 11512–11528. [Google Scholar] [CrossRef]
  11. Zhao, Y.; Zhang, S.; Shi, R.; Waterhouse, G.I.N.; Tang, J.; Zhang, T. Two-dimensional photocatalyst design: A critical review of recent experimental and computational advances. Mater. Today 2020, 34, 78–91. [Google Scholar] [CrossRef]
  12. Li, X.; Xiong, J.; Gao, X.; Huang, J.; Feng, Z.; Chen, Z.; Zhu, Y. Recent advances in 3D g-C3N4 composite photocatalysts for photocatalytic water splitting, degradation of pollutants and CO2 reduction. J. Alloys Compd. 2019, 802, 196–209. [Google Scholar] [CrossRef]
  13. Luo, Y.; Zhu, Y.; Han, Y.; Ye, H.; Liu, R.; Lan, Y.; Xue, M.; Xie, X.; Yu, S.; Zhang, L.; et al. g-C3N4-based photocatalysts for organic pollutant removal: A critical review. Carbon Res. 2023, 2, 14. [Google Scholar] [CrossRef]
  14. Chen, L.; Maigbay, M.A.; Li, M.; Qiu, X. Synthesis and modification strategies of g-C3N4 nanosheets for photocatalytic applications. Adv. Powder Mater 2023, 100150, in press. [Google Scholar] [CrossRef]
  15. Zhu, W.; Yue, Y.; Wang, H.; Zhang, B.; Hou, R.; Xiao, J.; Huang, X.; Ishag, A.; Sun, Y. Recent advances on energy and environmental application of graphitic carbon nitride (g-C3N4)-based photocatalysts: A review. J. Environ. Chem. Eng. 2023, 11, 110164. [Google Scholar] [CrossRef]
  16. Babu, B.; Koutavarapu, R.; Shim, J.; Yoo, K. Enhanced visible-light-driven photoelectrochemical and photocatalytic performance of Au-SnO2 quantum dot-anchored g-C3N4 nanosheets. Sep. Purif. Technol. 2020, 240, 116652. [Google Scholar] [CrossRef]
  17. Jin, T.; Liu, C.B.; Chen, F.; Qian, J.C.; Qiu, Y.B.; Meng, X.R.; Chen, Z.G. Synthesis of g-C3N4/CQDs composite and its photocatalytic degradation property for Rhodamine B. Carbon Lett. 2022, 32, 1451–1462. [Google Scholar] [CrossRef]
  18. Zhao, Z.W.; Fan, J.Y.; Deng, X.Y.; Liu, J. One-step synthesis of phosphorus-doped g-C3N4/Co3O4 quantum dots from vitamin B12 with enhanced visible-light photocatalytic activity for metronidazole degradation. Chem. Eng. J. 2019, 360, 1517–1529. [Google Scholar] [CrossRef]
  19. Zhu, X.; Dong, Z.M.; Xu, J.D.; Lin, S.Y.; Liu, J.Y.; Cheng, Z.P.; Cao, X.H.; Wang, Y.Q.; Liu, Y.H.; Zhang, Z.B. Visible-light induced electron-transfer in MoO3 QDs/g-C3N4 nanosheets for efficient photocatalytic reduction of U(VI). J. Alloys Compd. 2022, 926, 10. [Google Scholar] [CrossRef]
  20. Guo, R.T.; Liu, X.Y.; Qin, H.; Ang, Z.Y.; Shi, X.; Pan, W.G.; Fu, Z.G.; Tang, J.Y.; Jia, P.Y.; Miao, Y.F.; et al. Photocatalytic reduction of CO2 into CO over nanostructure Bi2S3 quantum dots/g-C3N4 composites with Z-scheme mechanism. Appl. Surf. Sci 2020, 500, 144059. [Google Scholar] [CrossRef]
  21. Wang, J.M.; Yu, L.M.; Wang, Z.J.; Wei, W.; Wang, K.F.; Wei, X.H. Constructing 0D/2D Z-Scheme Heterojunction of CdS/g-C3N4 with Enhanced Photocatalytic Activity for H-2 Evolution. Catal. Lett. 2021, 151, 3550–3561. [Google Scholar] [CrossRef]
  22. Li, G.; Huang, J.M.; Wang, N.N.; Huang, J.L.; Zheng, Y.M.; Zhan, G.W.; Li, Q.B. Carbon quantum dots functionalized g-C3N4 nanosheets as enhanced visible-light photocatalysts for water splitting. Diam. Relat. Mat. 2021, 116, 9. [Google Scholar] [CrossRef]
  23. Huo, Y.; Ding, X.H.; Zhang, X.Y.; Ren, M.; Sang, L.B.; Wen, S.Y.; Song, D.Y.; Yang, Y.X. Graphene quantum dot implanted supramolecular carbon nitrides with robust photocatalytic activity against recalcitrant contaminants. Catal. Sci. Technol. 2022, 12, 3937–3946. [Google Scholar] [CrossRef]
  24. Hu, X.Y.; Yu, Y.T.; Chen, D.D.; Xu, W.C.; Fang, J.Z.; Liu, Z.; Li, R.Q.; Yao, L.; Qin, J.J.; Fang, Z.Q. Anatase/Rutile homojunction quantum dots anchored on g-C3N4 nanosheets for antibiotics degradation in seawater matrice via coupled adsorption-photocatalysis: Mechanism insight and toxicity evaluation. Chem. Eng. J. 2022, 432, 15. [Google Scholar] [CrossRef]
  25. Zhao, T.Y.; Xing, Z.P.; Xiu, Z.Y.; Li, Z.Z.; Yang, S.L.; Zhou, W. Oxygen-Doped MoS2 Nanospheres/CdS Quantum Dots/g-C3N4 Nanosheets Super-Architectures for Prolonged Charge Lifetime and Enhanced Visible-Light-Driven Photocatalytic Performance. ACS Appl. Mater. Interfaces 2019, 11, 7104–7111. [Google Scholar] [CrossRef]
  26. Wu, H.H.; Yu, S.Y.; Wang, Y.; Han, J.; Wang, L.; Song, N.; Dong, H.J.; Li, C.M. A facile one-step strategy to construct 0D/2D SnO2/g-C3N4 heterojunction photocatalyst for high-efficiency hydrogen production performance from water splitting. Int. J. Hydrogen Energy 2020, 45, 30142–30152. [Google Scholar] [CrossRef]
  27. Babu, B.; Cho, M.; Byon, C.; Shim, J. Sunlight-driven photocatalytic activity of SnO2 QDs-g-C3N4 nanolayers. Mater. Lett. 2018, 212, 327–331. [Google Scholar] [CrossRef]
  28. Li, N.X.; Liu, X.C.; Zhou, J.C.; Chen, W.S.; Liu, M.C. Encapsulating CuO quantum dots in MIL-125(Ti) coupled with g-C3N4 for efficient photocatalytic CO2 reduction. Chem. Eng. J. 2020, 399, 11. [Google Scholar] [CrossRef]
  29. Zou, Y.Z.; Xie, Y.; Yu, S.; Chen, L.; Cui, W.; Dong, F.; Zhou, Y. SnO2 quantum dots anchored on g-C3N4 for enhanced visible-light photocatalytic removal of NO and toxic NO2 inhibition. Appl. Surf. Sci. 2019, 496, 8. [Google Scholar] [CrossRef]
  30. Zhu, Z.; Tang, X.; Fan, W.Q.; Liu, Z.; Huo, P.W.; Wang, T.S.; Yan, Y.S.; Li, C.X. Studying of Co-doped g-C3N4 and modified with Fe3O4 quantum dots on removing tetracycline. J. Alloys Compd. 2019, 775, 248–258. [Google Scholar] [CrossRef]
  31. Cheng, C.; Chen, D.Y.; Li, N.J.; Li, H.; Xu, Q.F.; He, J.H.; Lu, J.M. Bi2WO6 quantum dots with oxygen vacancies combined with g-C3N4 for NO removal. J. Colloid Interface Sci. 2022, 609, 447–455. [Google Scholar] [CrossRef] [PubMed]
  32. Paul, D.R.; Sharma, R.; Nehra, S.P.; Sharma, A. Effect of calcination temperature, pH and catalyst loading on photodegradation efficiency of urea derived graphitic carbon nitride towards methylene blue dye solution. RSC Adv. 2019, 9, 15381–15391. [Google Scholar] [CrossRef] [PubMed]
  33. Surender, S.; Balakumar, S. Insight into the melamine-derived freeze-dried nanostructured g-C3N4 for expeditious photocatalytic degradation of dye pollutants. Diam. Relat. Mat. 2022, 128, 109269. [Google Scholar] [CrossRef]
  34. Raaja Rajeshwari, M.; Kokilavani, S.; Sudheer Khan, S. Recent developments in architecturing the g-C3N4 based nanostructured photocatalysts: Synthesis, modifications and applications in water treatment. Chemosphere 2022, 291, 132735. [Google Scholar] [CrossRef]
  35. Fernández-Catalá, J.; Greco, R.; Navlani-García, M.; Cao, W.; Berenguer-Murcia, Á.; Cazorla-Amorós, D. g-C3N4-Based Direct Z-Scheme Photocatalysts for Environmental Applications. Catalysts 2022, 12, 1137. [Google Scholar] [CrossRef]
  36. Hayat, A.; Sohail, M.; El Jery, A.; Al-Zaydi, K.M.; Alshammari, K.F.; Khan, J.; Ali, H.; Ajmal, Z.; Taha, T.A.; Ud Din, I.; et al. Different Dimensionalities, Morphological Advancements and Engineering of g-C3N4-Based Nanomaterials for Energy Conversion and Storage. Chem. Rec. 2023, 23, e202200171. [Google Scholar] [CrossRef]
  37. Linh, P.H.; Do Chung, P.; Van Khien, N.; Oanh, L.T.M.; Thu, V.T.; Bach, T.N.; Hang, L.T.; Hung, N.M.; Lam, V.D. A simple approach for controlling the morphology of g-C3N4 nanosheets with enhanced photocatalytic properties. Diam. Relat. Mat. 2021, 111, 108214. [Google Scholar] [CrossRef]
  38. Zhang, M.; Yang, Y.; An, X.; Zhao, J.; Bao, Y.; Hou, L.-A. Exfoliation method matters: The microstructure-dependent photoactivity of g-C3N4 nanosheets for water purification. J. Hazard. Mater. 2022, 424, 127424. [Google Scholar] [CrossRef]
  39. Chen, Y.; Yang, B.; Xie, W.; Zhao, X.; Wang, Z.; Su, X.; Yang, C. Combined soft templating with thermal exfoliation toward synthesis of porous g-C3N4 nanosheets for improved photocatalytic hydrogen evolution. J. Mater. Res. Technol. 2021, 13, 301–310. [Google Scholar] [CrossRef]
  40. Wu, X.; Gao, D.; Wang, P.; Yu, H.; Yu, J. NH4Cl-induced low-temperature formation of nitrogen-rich g-C3N4 nanosheets with improved photocatalytic hydrogen evolution. Carbon 2019, 153, 757–766. [Google Scholar] [CrossRef]
  41. Zhou, L.; Shen, Z.; Wang, S.; Gao, J.; Tang, L.; Li, J.; Dong, Y.; Wang, Z.; Lyu, J. Construction of quantum-scale catalytic regions on anatase TiO2 nanoparticles by loading TiO2 quantum dots for the photocatalytic degradation of VOCs. Ceram. Int. 2021, 47, 21090–21098. [Google Scholar] [CrossRef]
  42. Javed, S.; Islam, M.; Mujahid, M. Synthesis and characterization of TiO2 quantum dots by sol gel reflux condensation method. Ceram. Int. 2019, 45, 2676–2679. [Google Scholar] [CrossRef]
  43. Wang, S.; Wang, F.; Su, Z.; Wang, X.; Han, Y.; Zhang, L.; Xiang, J.; Du, W.; Tang, N. Controllable Fabrication of Heterogeneous p-TiO2 QDs@g-C3N4 p-n Junction for Efficient Photocatalysis. Catalysts 2019, 9, 439. [Google Scholar] [CrossRef]
  44. Wang, J.; Lin, W.; Hu, H.; Liu, C.; Cai, Q.; Zhou, S.; Kong, Y. Engineering Z-system hybrids of 0D/2D F-TiO2 quantum dots/g-C3N4 heterostructures through chemical bonds with enhanced visible-light photocatalytic performance. New J. Chem. 2021, 45, 3067–3078. [Google Scholar] [CrossRef]
  45. Lee, J.-H.; Jeong, S.-Y.; Son, Y.-D.; Lee, S.-W. Facile Fabrication of TiO2 Quantum Dots-Anchored g-C3N4 Nanosheets as 0D/2D Heterojunction Nanocomposite for Accelerating Solar-Driven Photocatalysis. Nanomaterials 2023, 13, 1565. [Google Scholar] [CrossRef]
  46. Kumari, K.; Ahmaruzzaman, M. SnO2 quantum dots (QDs): Synthesis and potential applications in energy storage and environmental remediation. Mater. Res. Bull. 2023, 168, 112446. [Google Scholar] [CrossRef]
  47. Yu, B.; Li, Y.; Wang, Y.; Li, H.; Zhang, R. Facile hydrothermal synthesis of SnO2 quantum dots with enhanced photocatalytic degradation activity: Role of surface modification with chloroacetic acid. J. Environ. Chem. Eng. 2021, 9, 105618. [Google Scholar] [CrossRef]
  48. Xu, Z.; Jiang, Y.; Li, Z.; Chen, C.; Kong, X.; Chen, Y.; Zhou, G.; Liu, J.-M.; Kempa, K.; Gao, J. Rapid Microwave-Assisted Synthesis of SnO2 Quantum Dots for Efficient Planar Perovskite Solar Cells. ACS Appl. Energy Mater. 2021, 4, 1887–1893. [Google Scholar] [CrossRef]
  49. Bathula, B.; Gurugubelli, T.R.; Yoo, J.; Yoo, K. Recent Progress in the Use of SnO2 Quantum Dots: From Synthesis to Photocatalytic Applications. Catalysts 2023, 13, 765. [Google Scholar] [CrossRef]
  50. Wu, Z.; Jing, H.; Zhao, Y.; Lu, K.; Liu, B.; Yu, J.; Xia, X.; Lei, W.; Hao, Q. Grain boundary and interface interaction Co-regulation promotes SnO2 quantum dots for efficient CO2 reduction. Chem. Eng. J. 2023, 451, 138477. [Google Scholar] [CrossRef]
  51. Yousaf, M.U.; Pervaiz, E.; Minallah, S.; Afzal, M.J.; Honghong, L.; Yang, M. Tin oxide quantum dots decorated graphitic carbon nitride for enhanced removal of organic components from water: Green process. Results Phys. 2019, 14, 102455. [Google Scholar] [CrossRef]
  52. Ji, H.; Fan, Y.; Yan, J.; Xu, Y.; She, X.; Gu, J.; Fei, T.; Xu, H.; Li, H. Construction of SnO2/graphene-like g-C3N4 with enhanced visible light photocatalytic activity. RSC Adv. 2017, 7, 36101–36111. [Google Scholar] [CrossRef]
  53. Mohamed, K.M.; Benitto, J.J.; Vijaya, J.J.; Bououdina, M. Recent Advances in ZnO-Based Nanostructures for the Photocatalytic Degradation of Hazardous, Non-Biodegradable Medicines. Crystals 2023, 13, 329. [Google Scholar] [CrossRef]
  54. Mohamed, W.A.A.; Handal, H.T.; Ibrahem, I.A.; Galal, H.R.; Mousa, H.A.; Labib, A.A. Recycling for solar photocatalytic activity of Dianix blue dye and real industrial wastewater treatment process by zinc oxide quantum dots synthesized by solvothermal method. J. Hazard. Mater. 2021, 404, 123962. [Google Scholar] [CrossRef]
  55. Mohamed, W.A.A.; Ibrahem, I.A.; El-Sayed, A.M.; Galal, H.R.; Handal, H.; Mousa, H.A.; Labib, A.A. Zinc oxide quantum dots for textile dyes and real industrial wastewater treatment: Solar photocatalytic activity, photoluminescence properties and recycling process. Adv. Powder Technol. 2020, 31, 2555–2565. [Google Scholar] [CrossRef]
  56. Ye, Q.; Xu, L.; Xia, Y.; Gang, R.; Xie, C. Zinc oxide quantum dots/graphitic carbon nitride nanosheets based visible-light photocatalyst for efficient tetracycline hydrochloride degradation. J. Porous Mat. 2022, 29, 571–581. [Google Scholar] [CrossRef]
  57. Ren, Z.; Ma, H.; Geng, J.; Liu, C.; Song, C.; Lv, Y. ZnO QDs/GO/g-C3N4 Preparation and Photocatalytic Properties of Composites. Micromachines 2023, 14, 1501. [Google Scholar] [CrossRef]
  58. Vattikuti, S.V.P.; Reddy, P.A.K.; Shim, J.; Byon, C. Visible-Light-Driven Photocatalytic Activity of SnO2–ZnO Quantum Dots Anchored on g-C3N4 Nanosheets for Photocatalytic Pollutant Degradation and H2 Production. ACS Omega 2018, 3, 7587–7602. [Google Scholar] [CrossRef]
  59. Wang, J.B.; Liu, C.; Yang, S.; Lin, X.; Shi, W.L. Fabrication of a ternary heterostructure BiVO4 quantum dots/C-60/g-C3N4 photocatalyst with enhanced photocatalytic activity. J. Phys. Chem. Solids 2020, 136, 7. [Google Scholar] [CrossRef]
  60. Liang, Y.; Xu, W.; Fang, J.; Liu, Z.; Chen, D.; Pan, T.; Yu, Y.; Fang, Z. Highly dispersed bismuth oxide quantum dots/graphite carbon nitride nanosheets heterojunctions for visible light photocatalytic redox degradation of environmental pollutants. Appl. Catal. B 2021, 295, 120279. [Google Scholar] [CrossRef]
  61. Zeng, Y.; Yin, Q.; Liu, Z.; Dong, H. Attapulgite-interpenetrated g-C3N4/Bi2WO6 quantum-dots Z-scheme heterojunction for 2-mercaptobenzothiazole degradation with mechanism insight. Chem. Eng. J. 2022, 435, 134918. [Google Scholar] [CrossRef]
  62. Ding, F.; Chen, P.; Liu, F.; Chen, L.; Guo, J.-K.; Shen, S.; Zhang, Q.; Meng, L.-H.; Au, C.-T.; Yin, S.-F. Bi2MoO6/g-C3N4 of 0D/2D heterostructure as efficient photocatalyst for selective oxidation of aromatic alkanes. Appl. Surf. Sci. 2019, 490, 102–108. [Google Scholar] [CrossRef]
  63. Sun, Y.; Yuan, X.; Wang, Y.; Zhang, W.; Li, Y.; Zhang, Z.; Su, J.; Zhang, J.; Hu, S. CeO2 quantum dots anchored g-C3N4: Synthesis, characterization and photocatalytic performance. Appl. Surf. Sci. 2022, 576, 151901. [Google Scholar] [CrossRef]
  64. Qin, Y.Y.; Li, H.; Lu, J.; Ma, C.C.; Liu, X.L.; Meng, M.J.; Yan, Y.S. Fabrication of magnetic quantum dots modified Z-scheme Bi2O4/g-C3N4 photocatalysts with superior hydroxyl radical productivity for the degradation of rhodamine B. Appl. Surf. Sci. 2019, 493, 458–469. [Google Scholar] [CrossRef]
  65. Sun, C.; Yang, J.; Zhu, Y.; Xu, M.; Cui, Y.; Liu, L.; Ren, W.; Zhao, H.; Liang, B. Synthesis of 0D SnO2 nanoparticles/2D g-C3N4 nanosheets heterojunction: Improved charge transfer and separation for visible-light photocatalytic performance. J. Alloys Compd. 2021, 871, 159561. [Google Scholar] [CrossRef]
  66. Mohammad, A.; Khan, M.E.; Karim, M.R.; Cho, M.H. Synergistically effective and highly visible light responsive SnO2-g-C3N4 nanostructures for improved photocatalytic and photoelectrochemical performance. Appl. Surf. Sci. 2019, 495, 143432. [Google Scholar] [CrossRef]
  67. Van Pham, V.; Mai, D.-Q.; Bui, D.-P.; Van Man, T.; Zhu, B.; Zhang, L.; Sangkaworn, J.; Tantirungrotechai, J.; Reutrakul, V.; Cao, T.M. Emerging 2D/0D g-C3N4/SnO2 S-scheme photocatalyst: New generation architectural structure of heterojunctions toward visible-light-driven NO degradation. Environ. Pollut. 2021, 286, 117510. [Google Scholar] [CrossRef]
  68. Wang, X.; He, Y.; Xu, L.; Xia, Y.; Gang, R. SnO2 particles as efficient photocatalysts for organic dye degradation grown in-situ on g-C3N4 nanosheets by microwave-assisted hydrothermal method. Mater. Sci. Semicond. Process. 2021, 121, 105298. [Google Scholar] [CrossRef]
  69. Zhang, B.; He, X.; Yu, C.; Liu, G.; Ma, D.; Cui, C.; Yan, Q.; Zhang, Y.; Zhang, G.; Ma, J.; et al. Degradation of tetracycline hydrochloride by ultrafine TiO2 nanoparticles modified g-C3N4 heterojunction photocatalyst: Influencing factors, products and mechanism insight. Chin. Chem. Lett. 2022, 33, 1337–1342. [Google Scholar] [CrossRef]
  70. Ni, S.; Fu, Z.; Li, L.; Ma, M.; Liu, Y. Step-scheme heterojunction g-C3N4/TiO2 for efficient photocatalytic degradation of tetracycline hydrochloride under UV light. Colloids Surf. A Physicochem. Eng. Asp. 2022, 649, 129475. [Google Scholar] [CrossRef]
  71. Guo, F.; Sun, H.; Huang, X.; Shi, W.; Yan, C. Fabrication of TiO2/high-crystalline g-C3N4 composite with enhanced visible-light photocatalytic performance for tetracycline degradation. J. Chem. Technol. Biotechnol. 2020, 95, 2684–2693. [Google Scholar] [CrossRef]
  72. Gündoğmuş, P.; Park, J.; Öztürk, A. Preparation and photocatalytic activity of g-C3N4/TiO2 heterojunctions under solar light illumination. Ceram. Int. 2020, 46, 21431–21438. [Google Scholar] [CrossRef]
  73. Li, Y.; Zhang, Q.; Lu, Y.; Song, Z.; Wang, C.; Li, D.; Tang, X.; Zhou, X. Surface hydroxylation of TiO2/g-C3N4 photocatalyst for photo-Fenton degradation of tetracycline. Ceram. Int. 2022, 48, 1306–1313. [Google Scholar] [CrossRef]
  74. Jung, H.; Pham, T.-T.; Shin, E.W. Effect of g-C3N4 precursors on the morphological structures of g-C3N4/ZnO composite photocatalysts. J. Alloys Compd. 2019, 788, 1084–1092. [Google Scholar] [CrossRef]
  75. Ngullie, R.C.; Alaswad, S.O.; Bhuvaneswari, K.; Shanmugam, P.; Pazhanivel, T.; Arunachalam, P. Synthesis and Characterization of Efficient ZnO/g-C3N4 Nanocomposites Photocatalyst for Photocatalytic Degradation of Methylene Blue. Coatings 2020, 10, 500. [Google Scholar] [CrossRef]
  76. Tan, X.; Wang, X.; Hang, H.; Zhang, D.; Zhang, N.; Xiao, Z.; Tao, H. Self-assembly method assisted synthesis of g-C3N4/ZnO heterostructure nanocomposites with enhanced photocatalytic performance. Opt. Mater. 2019, 96, 109266. [Google Scholar] [CrossRef]
  77. Naseri, A.; Samadi, M.; Pourjavadi, A.; Ramakrishna, S.; Moshfegh, A.Z. Enhanced photocatalytic activity of ZnO/g-C3N4 nanofibers constituting carbonaceous species under simulated sunlight for organic dye removal. Ceram. Int. 2021, 47, 26185–26196. [Google Scholar] [CrossRef]
  78. Mathialagan, A.; Manavalan, M.; Venkatachalam, K.; Mohammad, F.; Oh, W.C.; Sagadevan, S. Fabrication and physicochemical characterization of g-C3N4/ZnO composite with enhanced photocatalytic activity under visible light. Opt. Mater. 2020, 100, 109643. [Google Scholar] [CrossRef]
  79. Xu, X.; Huang, T.; Xu, Y.; Hu, H.; Liao, S.; Hu, X.; Chen, D.; Zhang, M. Highly dispersed CeO2–x nanoparticles with rich oxygen vacancies enhance photocatalytic performance of g-C3N4 toward methyl orange degradation under visible light irradiation. J. Rare Earths 2022, 40, 1255–1263. [Google Scholar] [CrossRef]
  80. Subashini, A.; Varun Prasath, P.; Sagadevan, S.; Anita Lett, J.; Fatimah, I.; Mohammad, F.; Al-Lohedan, H.A.; Alshahateet, S.F.; Chun Oh, W. Enhanced photocatalytic degradation efficiency of graphitic carbon nitride-loaded CeO2 nanoparticles. Chem. Phys. Lett. 2021, 769, 138441. [Google Scholar] [CrossRef]
  81. Barathi, D.; Rajalakshmi, N.; Ranjith, R.; Sangeetha, R.; Meyvel, S. Controllable synthesis of CeO2/g-C3N4 hybrid catalysts and its structural, optical and visible light photocatalytic activity. Diam. Relat. Mat. 2021, 111, 108161. [Google Scholar] [CrossRef]
  82. Kaur, M.; Singh, S.; Mehta, S.K.; Kansal, S.K.; Umar, A.; Ibrahim, A.A.; Baskoutas, S. CeO2 quantum dots decorated g-C3N4 nanosheets: A potential scaffold for fluorescence sensing of heavy metals and visible-light driven photocatalyst. J. Alloys Compd. 2023, 960, 170637. [Google Scholar] [CrossRef]
  83. Wei, X.; Wang, X.; Pu, Y.; Liu, A.; Chen, C.; Zou, W.; Zheng, Y.; Huang, J.; Zhang, Y.; Yang, Y.; et al. Facile ball-milling synthesis of CeO2/g-C3N4 Z-scheme heterojunction for synergistic adsorption and photodegradation of methylene blue: Characteristics, kinetics, models, and mechanisms. Chem. Eng. J. 2021, 420, 127719. [Google Scholar] [CrossRef]
  84. Rathi, V.; Panneerselvam, A.; Sathiyapriya, R. A novel hydrothermal induced BiVO4/g-C3N4 heterojunctions visible-light photocatalyst for effective elimination of aqueous organic pollutants. Vacuum 2020, 180, 109458. [Google Scholar] [CrossRef]
  85. Xu, X.; Zhang, J.; Tao, F.; Dong, Y.; Wang, L.; Hong, T. Facile construction of Z-scheme g-C3N4/BiVO4 heterojunctions for boosting visible-light photocatalytic activity. Mater. Sci. Eng. B 2022, 279, 115676. [Google Scholar] [CrossRef]
  86. Reddy, C.V.; Nagar, A.; Shetti, N.P.; Reddy, I.N.; Basu, S.; Shim, J.; Kakarla, R.R. Novel g-C3N4/BiVO4 heterostructured nanohybrids for high efficiency photocatalytic degradation of toxic chemical pollutants. Chemosphere 2023, 322, 138146. [Google Scholar] [CrossRef] [PubMed]
  87. Mao, J.; Hong, B.; Wei, J.; Xu, J.; Han, Y.; Jin, H.; Jin, D.; Peng, X.; Li, J.; Yang, Y.; et al. Enhanced Ciprofloxacin Photodegradation of Visible-Light-Driven Z-Scheme g-C3N4/Bi2WO6 Nanocomposites and Interface Effect. ChemistrySelect 2019, 4, 13716–13723. [Google Scholar] [CrossRef]
  88. Yasmeen, H.; Zada, A.; Li, W.; Xu, M.; Liu, S. Suitable energy platform of Bi2WO6 significantly improves visible-light degradation activity of g-C3N4 for highly toxic diuron pollutant. Mater. Sci. Semicond. Process. 2019, 102, 104598. [Google Scholar] [CrossRef]
  89. Lian, X.; Xue, W.; Dong, S.; Liu, E.; Li, H.; Xu, K. Construction of S-scheme Bi2WO6/g-C3N4 heterostructure nanosheets with enhanced visible-light photocatalytic degradation for ammonium dinitramide. J. Hazard. Mater. 2021, 412, 125217. [Google Scholar] [CrossRef]
  90. Yang, Q.; An, J.; Xu, Z.; Liang, S.; Wang, H. Performance and mechanism of atrazine degradation using Co3O4/g-C3N4 hybrid photocatalyst with peroxymonosulfate under visible light irradiation. Colloids Surf. A Physicochem. Eng. Asp. 2021, 614, 126161. [Google Scholar] [CrossRef]
  91. Liu, L.; Huang, J.; Yu, H.; Wan, J.; Liu, L.; Yi, K.; Zhang, W.; Zhang, C. Construction of MoO3 nanopaticles/g-C3N4 nanosheets 0D/2D heterojuntion photocatalysts for enhanced photocatalytic degradation of antibiotic pollutant. Chemosphere 2021, 282, 131049. [Google Scholar] [CrossRef] [PubMed]
  92. Xue, S.; Wu, C.; Pu, S.; Hou, Y.; Tong, T.; Yang, G.; Qin, Z.; Wang, Z.; Bao, J. Direct Z-Scheme charge transfer in heterostructured MoO3/g-C3N4 photocatalysts and the generation of active radicals in photocatalytic dye degradations. Environ. Pollut. 2019, 250, 338–345. [Google Scholar] [CrossRef] [PubMed]
  93. Liu, Y.; Huang, H.; Cao, W.; Mao, B.; Liu, Y.; Kang, Z. Advances in carbon dots: From the perspective of traditional quantum dots. Mat. Chem. Front. 2020, 4, 1586–1613. [Google Scholar] [CrossRef]
Catalysts 13 01414 g001
Figure 1. (A,B) Synthesis of g-C3N4 from different precursors and temperature conditions [35].
Figure 1. (A,B) Synthesis of g-C3N4 from different precursors and temperature conditions [35].
Catalysts 13 01414 g001
Catalysts 13 01414 g002
Figure 2. Synthetic process for fabricating TiO2 QDs@g-C3N4 nanocomposite [45].
Figure 2. Synthetic process for fabricating TiO2 QDs@g-C3N4 nanocomposite [45].
Catalysts 13 01414 g002
Catalysts 13 01414 g003
Figure 3. (a–f) Photocatalytic application of SnO2 QD/g-C3N4 nanocomposite [51].
Figure 3. (a–f) Photocatalytic application of SnO2 QD/g-C3N4 nanocomposite [51].
Catalysts 13 01414 g003
Catalysts 13 01414 g004
Figure 4. Schematic diagram of the synthesis process for Bi2O3 QD/g-C3N4 nanocomposite [60]. Copyright 2021, Elsevier.
Figure 4. Schematic diagram of the synthesis process for Bi2O3 QD/g-C3N4 nanocomposite [60]. Copyright 2021, Elsevier.
Catalysts 13 01414 g004
Catalysts 13 01414 g005
Figure 5. (a,b) TEM and (c–e) HRTEM images of Bi2MoO6 QD/g-C3N4 nanocomposite [62]. Copyright 2019, Elsevier.
Figure 5. (a,b) TEM and (c–e) HRTEM images of Bi2MoO6 QD/g-C3N4 nanocomposite [62]. Copyright 2019, Elsevier.
Catalysts 13 01414 g005
Catalysts 13 01414 g006
Figure 6. The photocatalytic RhB degradation mechanism over CeO2 QD-modified g-C3N4 nanocomposite [63]. Copyright 2022, Elsevier.
Figure 6. The photocatalytic RhB degradation mechanism over CeO2 QD-modified g-C3N4 nanocomposite [63]. Copyright 2022, Elsevier.
Catalysts 13 01414 g006
Table 1. Detailed description of recent research on the photocatalytic abilities of nanocomposites based on metal oxide QDs-g-C3N4.
Table 1. Detailed description of recent research on the photocatalytic abilities of nanocomposites based on metal oxide QDs-g-C3N4.
PhotocatalystPollutantDosageLight SourceEfficiencyRef.
SnO2 QDs/g-C3N4RhB50 mg/LVisible light95% in 60 min[51]
TiO2 QDs/g-C3N4RhB10 mg/LVisible light99% in 75 min[44]
TiO2 QDs/g-C3N4Phenol10 mg/LVisible light98% in 100 min[44]
TiO2 QDs/g-C3N4Cr (VI)20 mg/LVisible light99% in 60 min[44]
TiO2 QDs/g-C3N4MO10 mg/LSolar light98% in 120 min[20]
CeO2 QDs/g-C3N4RhB10 mg/LVisible light80% in 180 min[63]
CeO2 QDs/g-C3N4MO10 mg/LVisible light82% in 180 min[63]
CeO2 QDs/g-C3N4MB10 mg/LVisible light74% in 180 min[63]
BiVO4 QDs-g-C3N4RhB10 mg/LVisible light81% in 90 min[59]
Bi2O3 QDs/g-C3N4TC10 mg/LVisible light83% in 120 min[60]
Bi2O3 QDs/g-C3N4Cr (VI)10 mg/LVisible light88% in 60 min[60]
Bi2O4 QDs/g-C3N4RhB10 mg/LVisible light78% in 160 min[64]
Bi2WO6 QDs/g-C3N4MBT20 mg/LVisible light99% in 80 min[61]
MoO3 QDs/g-C3N4U (VI)50 mg/LVisible light96% in 150 min[19]
Co3O4 QDs-g-C3N4MTZ10 mg/LVisible light77% in 180 min[18]
Bi2WO6 QDs/g-C3N4NO0.5 ppmVisible light61%[31]
SnO2 QDs/g-C3N4NO600 ppbVisible light32%[29]
SnO2 NPs/g-C3N4RhB10 ppmVisible light97% in 50 min[65]
SnO2 NPs/g-C3N4MB10 ppmVisible light99% in 90 min[66]
SnO2 NPs/g-C3N4CR10 ppmVisible light96% in 90 min[66]
SnO2 NPs/g-C3N4NO500 ppbVisible light40%[67]
SnO2 NPs/g-C3N4RhB10 ppmSolar light86% in 240 min[68]
TiO2 NPs/g-C3N4TC20 ppmVisible light99% in 120 min[69]
TiO2 NPs/g-C3N4TC20 ppmUV light96% in 90 min[70]
TiO2 NPs/g-C3N4TC20 ppmVisible light90% in 120 min[71]
TiO2 NPs/g-C3N4MB20 ppmSolar light80% in 180 min[72]
TiO2 NPs/g-C3N4TC100 ppmVisible light80% in 100 min[73]
ZnO NPs/g-C3N4MB10 ppmVisible light98% in 150 min[74]
ZnO NPs/g-C3N4MB50 ppmVisible light98% in 180 min[75]
ZnO NPs/g-C3N4MB10 ppmVisible light60% in 120 min[76]
ZnO NPs/g-C3N4MB10 ppmVisible light92% in 120 min[77]
ZnO NPs/g-C3N4CR10 ppmVisible light70% in 45 min[78]
CeO2 NPs/g-C3N4MO10 ppmVisible light96% in 100 min[79]
CeO2 NPs/g-C3N4RhB10 ppmVisible light96% in 60 min[80]
CeO2 NPs/g-C3N4Cr20 ppmVisible light96% in 100 min[81]
CeO2 QDs/g-C3N4TC10 ppmVisible light78% in 160 min[82]
CeO2 NPs/g-C3N4MB10 ppmVisible light70% in 180 min[83]
BiVO4 NPs/g-C3N44-CP20 ppmVisible light95% in 100 min[84]
BiVO4 NPs/g-C3N4MO20 ppmVisible light82% in 60 min[85]
BiVO4 NPs/g-C3N4MB10 ppmVisible light88% in 120 min[86]
BiVO4 NPs/g-C3N4TC10 ppmVisible light89% in 120 min[86]
Bi2WO6 NPs/g-C3N4CIP15 ppmVisible light98% in 120 min[87]
Bi2WO6 NPs/g-C3N4Diuron20 ppmVisible light75% in 120 min[88]
Bi2WO6 NPs/g-C3N4ADN10 ppmVisible light98% in 80 min[89]
Co3O4 NPs/g-C3N4Atrazine-Visible light78% in 35 min[90]
MoO3 NPs/g-C3N4TC10 ppm Visible light86% in 100 min[91]
MoO3 NPs/g-C3N4RhB10 ppmVisible light99% in 25 min[92]
Disclaimer/Publisher’s Note: The statements, opinions and data contained in all publications are solely those of the individual author(s) and contributor(s) and not of MDPI and/or the editor(s). MDPI and/or the editor(s) disclaim responsibility for any injury to people or property resulting from any ideas, methods, instructions or products referred to in the content.

Share and Cite

MDPI and ACS Style

Salunkhe, T.T.; Gurugubelli, T.R.; Babu, B.; Yoo, K. Recent Innovative Progress of Metal Oxide Quantum-Dot-Integrated g-C3N4 (0D-2D) Synergistic Nanocomposites for Photocatalytic Applications. Catalysts 2023, 13, 1414. https://doi.org/10.3390/catal13111414

AMA Style

Salunkhe TT, Gurugubelli TR, Babu B, Yoo K. Recent Innovative Progress of Metal Oxide Quantum-Dot-Integrated g-C3N4 (0D-2D) Synergistic Nanocomposites for Photocatalytic Applications. Catalysts. 2023; 13(11):1414. https://doi.org/10.3390/catal13111414

Chicago/Turabian Style

Salunkhe, Tejaswi Tanaji, Thirumala Rao Gurugubelli, Bathula Babu, and Kisoo Yoo. 2023. "Recent Innovative Progress of Metal Oxide Quantum-Dot-Integrated g-C3N4 (0D-2D) Synergistic Nanocomposites for Photocatalytic Applications" Catalysts 13, no. 11: 1414. https://doi.org/10.3390/catal13111414

Note that from the first issue of 2016, this journal uses article numbers instead of page numbers. See further details here.

Article Metrics

Back to TopTop