Effect of Acid Properties of Fluorinated Beta and ZSM-5 Zeolites Used as Supports of Ni Catalysts for the Catalytic Hydrodeoxygenation of Guaiacol
Abstract
:1. Introduction
2. Results and Discussion
2.1. Characterization of the Catalytic Supports and the Catalysts
2.2. Catalytic Activity
3. Materials and Methods
3.1. Materials
3.2. Preparation of the Fluorinated Zeolites
3.3. Preparation of the Catalysts
3.4. Characterization Techniques
3.5. Catalytic Activity Tests
Author Contributions
Funding
Data Availability Statement
Conflicts of Interest
References
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Samples | Si/Al (XRF) | IR Bands (cm−1) a | Langmuir Surface Area (m2/g) b | Acidity (mmol H+/g) c | |
---|---|---|---|---|---|
υ1 | υ2 | ||||
Z | 20.0 | 1058 | 795 | 505 | 0.25 |
ZF | 20.5 | 1061 | 795 | 549 | 0.37 |
ZF0.2 | 21.6 | 1071 | 795 | 558 | 0.33 |
ZF0.05 | 20.3 | 1060 | 795 | 516 | 0.27 |
ZFR | 20.1 | 1059 | 798 | 457 | 0.39 |
ZFMwR | 20.1 | 1053 | 797 | 454 | 0.45 |
B | 12.5 | 1047 | 792 | 630 | 0.30 |
BF | 14.6 | 1064 | 795 | 731 | 0.51 |
BF0.2 | 15.2 | 1066 | 797 | 767 | 0.29 |
BF0.05 | 13.8 | 1050 | 793 | 724 | 0.48 |
HB | 13.2 | 1054 | 795 | 636 | 0.60 |
HBF | 14.1 | 1065 | 798 | 702 | 0.58 |
Samples | [NH4F] (M) | Treatment Temperature (°C) | Treatment Time (h) | Heating |
---|---|---|---|---|
ZF | 0.1 | RT | 42 | -- |
ZF0.2 | 0.2 | RT | 42 | -- |
ZF0.05 | 0.05 | RT | 42 | -- |
ZFR | 0.1 | 40 | 4 | Conventional refluxing |
ZFMwR | 0.1 | 40 | 4 | Microwave refluxing |
BF | 0.1 | RT | 42 | -- |
BF0.2 | 0.2 | RT | 42 | -- |
BF0.05 | 0.05 | RT | 42 | -- |
HBFa | 0.1 | RT | 42 | -- |
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Quintero-Arroyo, G.; Rueda, A.C.; Granados-Reyes, J.; Fals, J.; Cesteros, Y. Effect of Acid Properties of Fluorinated Beta and ZSM-5 Zeolites Used as Supports of Ni Catalysts for the Catalytic Hydrodeoxygenation of Guaiacol. Catalysts 2024, 14, 586. https://doi.org/10.3390/catal14090586
Quintero-Arroyo G, Rueda AC, Granados-Reyes J, Fals J, Cesteros Y. Effect of Acid Properties of Fluorinated Beta and ZSM-5 Zeolites Used as Supports of Ni Catalysts for the Catalytic Hydrodeoxygenation of Guaiacol. Catalysts. 2024; 14(9):586. https://doi.org/10.3390/catal14090586
Chicago/Turabian StyleQuintero-Arroyo, Gabriela, Angie C. Rueda, Judith Granados-Reyes, Jayson Fals, and Yolanda Cesteros. 2024. "Effect of Acid Properties of Fluorinated Beta and ZSM-5 Zeolites Used as Supports of Ni Catalysts for the Catalytic Hydrodeoxygenation of Guaiacol" Catalysts 14, no. 9: 586. https://doi.org/10.3390/catal14090586