Catalytic Behaviors of Supported Cu, Ni, and Co Phosphide Catalysts for Deoxygenation of Oleic Acid
Abstract
:1. Introduction
2. Results and Discussion
2.1. Crystal Structures
2.2. Morphology and Surface Properties
2.3. Deoxygenation of Oleic Acid
3. Materials and Methods
3.1. Materials
3.2. Synthesis of Supported Metal Phosphide Catalysts
3.3. Characterization of Supported Metal Phosphide Catalysts
3.4. Deoxygenation of Oxygenated Hydrocarbon Compounds
4. Conclusions
Author Contributions
Funding
Conflicts of Interest
References
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Catalyst | Acid Site (mmol/g) a | SBET (m2/g) | Smicro (m2/g) | Total Pore Volume (cc/g) | Micropore Volume (cc/g) | Pore Diameter (nm) | Crystallite Size (nm) b |
---|---|---|---|---|---|---|---|
CoP/USY | 0.19 | 247 | 95 | 0.28 | 0.06 | 3.7 | 58.4 |
Ni2P/USY | 0.60 | 446 | 321 | 0.24 | 0.17 | 3.7 | 39.2 |
Cu3P/USY | 0.34 | 371 | 253 | 0.24 | 0.13 | 3.7 | 33.2 |
Cu3P/SiO2 | 0.04 | 38 | - | 0.50 | - | 27.2 | 33.2 |
Cu/γ-Al2O3 | 0.50 | 101 | - | 0.31 | - | 7.8 | 46.0 |
USY | 0.52 | 696 | 558 | 0.27 | 0.26 | 3.7 | - |
SiO2 | - | 471 | - | 0.99 | - | 6.9 | - |
γ-Al2O3 | 0.43 | 198 | - | 0.54 | - | 7.8 | - |
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Kochaputi, N.; Kongmark, C.; Khemthong, P.; Butburee, T.; Kuboon, S.; Worayingyong, A.; Faungnawakij, K. Catalytic Behaviors of Supported Cu, Ni, and Co Phosphide Catalysts for Deoxygenation of Oleic Acid. Catalysts 2019, 9, 715. https://doi.org/10.3390/catal9090715
Kochaputi N, Kongmark C, Khemthong P, Butburee T, Kuboon S, Worayingyong A, Faungnawakij K. Catalytic Behaviors of Supported Cu, Ni, and Co Phosphide Catalysts for Deoxygenation of Oleic Acid. Catalysts. 2019; 9(9):715. https://doi.org/10.3390/catal9090715
Chicago/Turabian StyleKochaputi, Nopparuj, Chanapa Kongmark, Pongtanawat Khemthong, Teera Butburee, Sanchai Kuboon, Attera Worayingyong, and Kajornsak Faungnawakij. 2019. "Catalytic Behaviors of Supported Cu, Ni, and Co Phosphide Catalysts for Deoxygenation of Oleic Acid" Catalysts 9, no. 9: 715. https://doi.org/10.3390/catal9090715