New Low-Dimensional Hybrid Perovskitoids Based on Lead Bromide with Organic Cations from Charge-Transfer Complexes
Abstract
:1. Introduction
2. Materials and Methods
3. Results and Discussion
4. Conclusions
Author Contributions
Funding
Data Availability Statement
Conflicts of Interest
References
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Parameter | [AntrNH3][PbBr3](DMF) | [PyrNH3][Pb2Br6][DMFH](DMF)2 | [StyrNH3]2[PbBr4] |
---|---|---|---|
Formula unit | C36H42Br6N4O2Pb2 | C26H36Br6N4O3Pb2 | C30H32Br4N2Pb |
Formula weight | 1456.57 | 1346.43 | 947.40 |
T, K | 100 | 120 | 100 |
Crystal system | Orthorhombic | Monoclinic | Monoclinic |
Space group | P212121 | P21/n | Cc |
Z | 4 | 4 | 16 |
a, Å | 4.3768(2) | 7.5989(7) | 22.6541(4) |
b, Å | 20.9524(8) | 22.120(2) | 15.7611(3) |
c, Å | 44.9467(15) | 22.258(2) | 36.9741(7) |
β, ° | 90 | 92.060(2) | 95.2120(10) |
V, Å3 | 4121.8(3) | 3738.9(6) | 13147.1(4) |
Dcalc (g cm−1) | 2.347 | 2.392 | 1.915 |
Linear absorption, μ (cm−1) | 140.12 | 154.37 | 100.16 |
F(000) | 2704 | 2472 | 7168 |
2Θmax, ° | 54 | 52 | 54 |
Reflections measured | 85071 | 36079 | 200887 |
Independent reflections | 9012 | 7354 | 28716 |
Observed reflections [I > 2σ (I)] | 8637 | 5245 | 25396 |
Parameters | 456 | 376 | 1260 |
R1 | 0.0377 | 0.0399 | 0.0500 |
wR2 | 0.0843 | 0.0944 | 0.1341 |
GOOF | 1.138 | 1.042 | 1.039 |
Δρmax/Δρmin (e Å−3) | 1.620/−1.673 | 1.972/−1.598 | 3.283/−1.633 |
Parameter | [AntrNH3][PbBr3](DMF) | [PyrNH3][Pb2Br6][DMFH](DMF)2 | [StyrNH3]2[PbBr4] |
---|---|---|---|
Pb-Br, Å | 2.8480(10)—3.1916(10) [2.8402(11)—3.2532(13)] | 2.9250(9)—3.1786(10) [2.8569(9)—3.3482(10)] | 2.8717(19)—3.209(2) [2.841(2)—3.225(2), 2.8587(18)—3.232(3), 2.870(2)—3.192(2)] |
N…Br, Å | 3.289(11)—3.415(11) | 3.537(7) | 3.232(14)—3.701(13) |
NHBr, ° | 131.2(8)—150.0(7)° | 159.4(4) | 119(1)—172(1) |
N…O, Å | 2.767(14), 2.771(14) | 2.801(9), 2.835(9) | - |
NHO, ° | 168.8(7), 171.3(8) | 158.5(4), 163.1(5) | - |
O…O, Å | - | 2.42(1) | - |
OHO, ° | - | 166.0(5) | - |
S(Oh) | 0.122 [0.282] | 0.998 [1.138] | 0.866 [0.397, 0.885, 0.352] |
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Nikovskiy, I.A.; Isakovskaya, K.L.; Nelyubina, Y.V. New Low-Dimensional Hybrid Perovskitoids Based on Lead Bromide with Organic Cations from Charge-Transfer Complexes. Crystals 2021, 11, 1424. https://doi.org/10.3390/cryst11111424
Nikovskiy IA, Isakovskaya KL, Nelyubina YV. New Low-Dimensional Hybrid Perovskitoids Based on Lead Bromide with Organic Cations from Charge-Transfer Complexes. Crystals. 2021; 11(11):1424. https://doi.org/10.3390/cryst11111424
Chicago/Turabian StyleNikovskiy, Igor A., Kseniya L. Isakovskaya, and Yulia V. Nelyubina. 2021. "New Low-Dimensional Hybrid Perovskitoids Based on Lead Bromide with Organic Cations from Charge-Transfer Complexes" Crystals 11, no. 11: 1424. https://doi.org/10.3390/cryst11111424