Cross-Linked Chitosan/Multi-Walled Carbon Nanotubes Composite as Ecofriendly Biocatalyst for Synthesis of Some Novel Benzil Bis-Thiazoles
Abstract
:1. Introduction
2. Results and Discussion
2.1. Preparation of CLCS and CLCS/MWCNTs Composite
2.2. FTIR Spectra of CLCS and CLCS/MWCNTs Composite
2.3. Scanning Electron Microscopy (SEM) of CLCS and CLCS/MWCNTs Composite
2.4. X-ray Diffraction of CLCS and CLCS/MWCNTs Composite
2.5. Thermal Stability of CLCS and CLCS/MWCNTs Composite
2.6. Synthesis of Benzil Bis-Thiazoles
3. Experimental Section
3.1. Measurements
3.2. Methods
3.2.1. Preparation of CLCS
3.2.2. Preparation of CLCS/MWCNTs Composite
3.2.3. Synthesis of Benzil Bis-Thiazole Derivatives 5a–g and 9a–e
3.2.4. Alternative Synthesis of 5a
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Temperature (°C) | Weight Loss (%) | ||
---|---|---|---|
Chitosan | CLCS | CLCS/MWCNTs | |
50 | 2.24 | 0.48 | 0.72 |
100 | 6.36 | 1.92 | 3.62 |
150 | 8.61 | 4.79 | 6.75 |
200 | 8.98 | 7.42 | 8.44 |
250 | 10.47 | 10.05 | 11.33 |
260 | 11.22 | 11.72 | 12.54 |
270 | 13.09 | 15.55 | 14.47 |
280 | 15.33 | 22.26 | 17.60 |
290 | 19.08 | 29.20 | 21.95 |
300 | 25.06 | 34.94 | 27.48 |
310 | 34.04 | 37.81 | 32.55 |
320 | 40.76 | 39.97 | 35.68 |
330 | 43.76 | 41.64 | 37.86 |
340 | 46.01 | 43.07 | 39.79 |
350 | 47.87 | 44.51 | 41.23 |
400 | 53.86 | 48.93 | 46.53 |
450 | 59.09 | 53.20 | 50.15 |
500 | 65.46 | 57.95 | 53.29 |
Compound no. | TEA | CLCS | CLCS/MWCNTs | |||
---|---|---|---|---|---|---|
Time (Min) | (%) Yield | Time (min) | (%) Yield | Time (min) | (%) Yield | |
5a | 50 | 77 | 41 | 79 | 20 | 85 |
5b | 50 | 74 | 43 | 80 | 23 | 86 |
5c | 56 | 78 | 46 | 79 | 25 | 86 |
5d | 53 | 72 | 43 | 80 | 28 | 84 |
5e | 52 | 72 | 36 | 81 | 19 | 87 |
5f | 60 | 78 | 38 | 83 | 25 | 85 |
5g | 55 | 73 | 38 | 82 | 22 | 87 |
Compound no. | TEA | CLCS | CLCS/MWCNTs | |||
---|---|---|---|---|---|---|
Time (min) | (%) Yield | Time (min) | (%) Yield | Time (min) | (%) Yield | |
9a | 53 | 72 | 39 | 77 | 22 | 86 |
9b | 48 | 70 | 40 | 78 | 20 | 83 |
9c | 53 | 72 | 44 | 80 | 23 | 84 |
9d | 47 | 74 | 41 | 82 | 24 | 85 |
9e | 55 | 74 | 38 | 80 | 21 | 83 |
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Alshabanah, L.A.; Gomha, S.M.; Al-Mutabagani, L.A.; Abolibda, T.Z.; El-Ghany, N.A.A.; El-Enany, W.A.M.A.; El-Ziaty, A.K.; Ali, R.S.; Mohamed, N.A. Cross-Linked Chitosan/Multi-Walled Carbon Nanotubes Composite as Ecofriendly Biocatalyst for Synthesis of Some Novel Benzil Bis-Thiazoles. Polymers 2021, 13, 1728. https://doi.org/10.3390/polym13111728
Alshabanah LA, Gomha SM, Al-Mutabagani LA, Abolibda TZ, El-Ghany NAA, El-Enany WAMA, El-Ziaty AK, Ali RS, Mohamed NA. Cross-Linked Chitosan/Multi-Walled Carbon Nanotubes Composite as Ecofriendly Biocatalyst for Synthesis of Some Novel Benzil Bis-Thiazoles. Polymers. 2021; 13(11):1728. https://doi.org/10.3390/polym13111728
Chicago/Turabian StyleAlshabanah, Latifah A., Sobhi M. Gomha, Laila A. Al-Mutabagani, Tariq Z. Abolibda, Nahed A. Abd El-Ghany, Waleed A. M. A. El-Enany, Ahmed K. El-Ziaty, Rania S. Ali, and Nadia A. Mohamed. 2021. "Cross-Linked Chitosan/Multi-Walled Carbon Nanotubes Composite as Ecofriendly Biocatalyst for Synthesis of Some Novel Benzil Bis-Thiazoles" Polymers 13, no. 11: 1728. https://doi.org/10.3390/polym13111728