Innovative Methylcellulose-Polyvinyl Pyrrolidone-Based Solid Polymer Electrolytes Impregnated with Potassium Salt: Ion Conduction and Thermal Properties
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.1.1. Synthesis of MC/PVP Polymer Blend
2.1.2. Synthesis of MC/PVP/K2CO3 SPE
2.1.3. Synthesis of MC/PVP/K2CO3/EC SPE
2.1.4. EDLC Fabrication
2.2. Characterization of Electrolyte Samples
2.3. Electrochemical Studies of Solid Electrolytes
2.4. EDLC Characterization
Cyclic Voltammetry (CV)
3. Results and Discussion
3.1. Structural Analysis
3.1.1. FTIR Studies
3.1.2. XRD Analysis
3.2. Morphological Analysis
FESEM Analysis
3.3. DSC Analysis
3.4. Electrochemical Studies
3.4.1. EIS Studies
S/N | Sample | Film Thickness × 10−3 (cm) | Bulk Resistance (Ohm) | Ionic Conductivity (Scm−1) |
---|---|---|---|---|
a | ||||
1. | MP0 | 9.3 | 8.97 × 107 | 3.30 × 10−11 |
2. | MP10 | 9.5 | 5.31 × 107 | 5.71 × 10−11 |
3. | MP20 | 9.7 | 5.14 × 107 | 6.01 × 10−11 |
4. | MP30 | 9.9 | 3.33 × 107 | 9.45 × 10−11 |
5. | MP40 | 9.4 | 1.56 × 107 | 1.92 × 10−10 |
6. | MP50 | 9.2 | 2.98 × 106 | 9.83 × 10−10 |
b | ||||
1. | MPK5 | 2.33 | 4.46 × 104 | 1.66 × 10−7 |
2. | MPK10 | 1.77 | 2.84 × 104 | 1.98 × 10−7 |
3. | MPK15 | 2.16 | 2.13 × 104 | 3.23 × 10−7 |
4. | MPK20 | 2.21 | 4.83 × 103 | 1.46 × 10−6 |
5. | MPK25 | 2.11 | 4.46 × 104 | 1.51 × 10−7 |
c | ||||
1. | MPKE5 | 2.62 | 3.13 × 102 | 2.66 × 10−5 |
2. | MPKE10 | 2.91 | 4.94 × 101 | 1.87 × 10−4 |
3. | MPKE15 | 2.89 | 2.37 × 101 | 3.88 × 10−4 |
4. | MPKE20 | 2.74 | 6.90 × 101 | 1.26 × 10−4 |
5. | MPKE25 | 2.69 | 2.16 × 102 | 3.98 × 10−5 |
3.4.2. LSV Studies
3.4.3. TNM Measurement
3.5. Device Study
CV Analysis
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
- Putri, R.M.; Sundari, C.D.D.; Floweri, O.; Mayangsari, T.R.; Ivansyah, A.L.; Santosa, S.P.; Arcana, I.M.; Iskandar, F. PEO/PVA/LiOH Solid Polymer Electrolyte Prepared via Ultrasound-assisted Solution Cast Method. J. Non-Cryst. Solids 2021, 556, 120549. [Google Scholar] [CrossRef]
- Javed, K.; Oolo, M.; Savest, N.; Krumme, A. A review on graphene-based electrospun conductive nanofibers, supercapacitors, anodes, and cathodes for lithium-ion batteries. Crit. Rev. Solid State Mater. Sci. 2019, 44, 427–443. [Google Scholar] [CrossRef]
- Dannoun, E.M.; Aziz, S.B.; Brza, M.A.; Nofal, M.M.; Asnawi, A.S.; Yusof, Y.M.; Al-Zangana, S.; Hamsan, M.H.; Kadir, M.F.Z.; Woo, H.J. The Study of Plasticized Solid Polymer Blend Electrolytes Based on Natural Polymers and Their Application for Energy Storage EDLC Devices. Polymers 2020, 12, 2531. [Google Scholar] [CrossRef] [PubMed]
- Adam, A.A.; Ojur Dennis, J.; Al-Hadeethi, Y.; Mkawi, E.M.; Abubakar Abdulkadir, B.; Usman, F.; Mudassir Hassan, Y.; Wadi, I.A.; Sani, M. State of the Art and New Directions on Electrospun Lignin/Cellulose Nanofibers for Supercapacitor Application: A Systematic Literature Review. Polymers 2020, 12, 2884. [Google Scholar] [CrossRef]
- Mahalakshmi, M.; Selvanayagam, S.; Selvasekarapandian, S.; Chandra, M.V.L.; Sangeetha, P.; Manjuladevi, R. Magnesium ion-conducting solid polymer electrolyte based on cellulose acetate with magnesium nitrate (Mg(NO3)2·6H2O) for electrochemical studies. Ionics 2020, 26, 4553–4565. [Google Scholar] [CrossRef]
- Adam, A.A.; Soleimani, H.; Shukur, M.F.B.A.; Dennis, J.O.; Abdulkadir, B.A.; Hassan, Y.M.; Yusuf, J.Y.; Shamsuri, N.A.B. A new approach to understanding the interaction effect of salt and plasticizer on solid polymer electrolytes using statistical model and artificial intelligence algorithm. J. Non-Cryst. Solids 2022, 587, 121597. [Google Scholar] [CrossRef]
- Nadirah, B.N.; Ong, C.C.; Saheed, M.S.M.; Yusof, Y.M.; Shukur, M.F. Structural and conductivity studies of polyacrylonitrile/methylcellulose blend based electrolytes embedded with lithium iodide. Int. J. Hydrogen Energy 2020, 45, 19590–19600. [Google Scholar] [CrossRef]
- Xu, L.; Li, J.; Deng, W.; Li, L.; Zou, G.; Hou, H.; Huang, L.; Ji, X. Boosting the ionic conductivity of PEO electrolytes by waste eggshell-derived fillers for high-performance solid lithium/sodium batteries. Mater. Chem. Front. 2021, 5, 1315–1323. [Google Scholar] [CrossRef]
- Hassan, Y.M.; Guan, B.H.; Zaid, H.M.; Hamza, M.F.; Adil, M.; Adam, A.A.; Hastuti, K. Application of Magnetic and Dielectric Nanofluids for Electromagnetic-Assistance Enhanced Oil Recovery: A Review. Crystals 2021, 11, 106. [Google Scholar] [CrossRef]
- Hassan, Y.M.; Guan, B.H.; Chuan, L.K.; Zaid, H.M.; Hamza, M.F.; Adam, A.A.; Usman, F.; Oluwatobi, Y.A. Effect of annealing temperature on the rheological property of ZnO/SiO2 nanocomposites for Enhanced Oil Recovery. Mater. Today Proc. 2022, 48, 905–910. [Google Scholar] [CrossRef]
- Hassan, Y.M.; Guan, B.H.; Chuan, L.K.; Khandaker, M.U.; Sikiru, S.; Halilu, A.; Adam, A.A.; Abdulkadir, B.A.; Usman, F. Electromagnetically Modified Wettability and Interfacial Tension of Hybrid ZnO/SiO2 Nanofluids. Crystals 2022, 12, 169. [Google Scholar] [CrossRef]
- Hassan, Y.M.; Guan, B.H.; Chuan, L.K.; Halilu, A.; Adil, M.; Adam, A.A.; Abdulkadir, B.A. Interfacial tension and wettability of hybridized ZnOFe2O3/SiO2 based nanofluid under electromagnetic field inducement. J. Pet. Sci. Eng. 2022, 211, 110184. [Google Scholar] [CrossRef]
- Hassan, Y.M.; Guan, B.H.; Chuan, L.K.; Hamza, M.F.; Khandaker, M.U.; Sikiru, S.; Adam, A.A.; Abdul Sani, S.F.; Abdulkadir, B.A.; Ayub, S. The influence of ZnO/SiO2 nanocomposite concentration on rheology, interfacial tension, and wettability for enhanced oil recovery. Chem. Eng. Res. Des. 2022, 179, 452–461. [Google Scholar] [CrossRef]
- Hassan, Y.M.; Guan, B.H.; Chuan, L.K.; Hamza, M.F.; Adil, M.; Adam, A.A. The synergistic effect of Fe2O3/SiO2 nanoparticles concentration on rheology, wettability, and brine-oil interfacial tension. J. Pet. Sci. Eng. 2022, 210, 110059. [Google Scholar] [CrossRef]
- Mathela, S.; Sangwan, B.; Dhapola, P.S.; Singh, P.K.; Tomar, R. Ionic liquid incorporated poly (ethylene oxide) (PEO) doped with potassium iodide (KI) solid polymer electrolyte for energy device. Mater. Today Proc. 2022, 49, 3250–3253. [Google Scholar] [CrossRef]
- Hamsan, M.H.; Shukur, M.F.; Aziz, S.B.; Yusof, Y.M.; Kadir, M.F.Z. Influence of NH4Br as an ionic source on the structural/electrical properties of dextran-based biopolymer electrolytes and EDLC application. Bull. Mater. Sci. 2019, 43, 30. [Google Scholar] [CrossRef]
- Shuhaimi, N.E.A.; Teo, L.P.; Majid, S.R.; Arof, A.K. Transport studies of NH4NO3 doped methyl cellulose electrolyte. Synth. Met. 2010, 160, 1040–1044. [Google Scholar] [CrossRef]
- Asnawi, A.; Hamsan, M.; Kadir, M.; Aziz, S.; Yusof, Y.J.M.C.; Crystals, L. Investigation on electrochemical characteristics of maltodextrin–methyl cellulose electrolytes. Mol. Cryst. Liq. Cryst. 2020, 708, 63–91. [Google Scholar] [CrossRef]
- Abdullah, S.; Ahmad, A.S.; Latif, K.S.A.; Sobri, N.A.M.; Abdullah, N.; Hashim, N.; Yahya, N.M.; Mohamed, R.M. Characterization of Solid Polymer Electrolyte Membrane made of Methylcellulose and Ammonium Nitrate. J. Phys. Conf. Ser. 2020, 1532, 012017. [Google Scholar] [CrossRef]
- Ahmed, H.T.; Abdullah, O.G. Impedance and ionic transport properties of proton-conducting electrolytes based on polyethylene oxide/methylcellulose blend polymers. J. Sci. Adv. Mater. Devices 2020, 5, 125–133. [Google Scholar] [CrossRef]
- Shamsuri, N.A.; Zaine, S.N.A.; Yusof, Y.M.; Yahya, W.Z.N.; Shukur, M.F. Effect of ammonium thiocyanate on ionic conductivity and thermal properties of polyvinyl alcohol–methylcellulose–based polymer electrolytes. Ionics 2020, 26, 6083–6093. [Google Scholar] [CrossRef]
- Aziz, S.B.; Dannoun, E.; Hamsan, M.H.; Ghareeb, H.O.; Nofal, M.M.; Karim, W.O.; Asnawi, A.S.; Hadi, J.M.; Kadir, M. A Polymer Blend Electrolyte Based on CS with Enhanced Ion Transport and Electrochemical Properties for Electrical Double Layer Capacitor Applications. Polymers 2021, 13, 930. [Google Scholar] [CrossRef]
- Asnawi, A.S.F.M.; Hamsan, M.H.; Aziz, S.B.; Kadir, M.F.Z.; Matmin, J.; Yusof, Y.M. Impregnation of [Emim]Br ionic liquid as plasticizer in biopolymer electrolytes for EDLC application. Electrochim. Acta 2021, 375, 137923. [Google Scholar] [CrossRef]
- Hamsan, M.; Aziz, S.B.; Shukur, M.; Kadir, M.J.I. Protonic cell performance employing electrolytes based on plasticized methylcellulose-potato starch-NH4NO. Ionics 2019, 25, 559–572. [Google Scholar] [CrossRef]
- Fan, L.; Wang, M.; Zhang, Z.; Qin, G.; Hu, X.; Chen, Q. Preparation and Characterization of PVA Alkaline Solid Polymer Electrolyte with Addition of Bamboo Charcoal. Materials 2018, 11, 679. [Google Scholar] [CrossRef] [PubMed] [Green Version]
- Sunitha, V.; Kabbur, S.K.M.; Pavan, G.; Sandesh, N.; Suhas, M.; Lalithnarayan, C.; Laxman, N.; Radhakrishnan, S.J.I. Lithium ion conduction in PVA-based polymer electrolyte system modified with combination of nanofillers. Ionics 2020, 26, 823–829. [Google Scholar] [CrossRef]
- Saeed, M.A.M.; Abdullah, O.G. Effect of High Ammonium Salt Concentration and Temperature on the Structure, Morphology, and Ionic Conductivity of Proton-Conductor Solid Polymer Electrolytes Based PVA. Membranes 2020, 10, 262. [Google Scholar] [CrossRef] [PubMed]
- Liu, J.; Khanam, Z.; Muchakayala, R.; Song, S. Fabrication and characterization of Zn-ion-conducting solid polymer electrolyte films based on PVdF-HFP/Zn(Tf)2 complex system. J. Mater. Sci. Mater. Electron. 2020, 31, 6160–6173. [Google Scholar] [CrossRef]
- Sedlak, P.; Gajdos, A.; Macku, R.; Majzner, J.; Holcman, V.; Sedlakova, V.; Kubersky, P.J.S.R. The effect of thermal treatment on ac/dc conductivity and current fluctuations of PVDF/NMP/[EMIM][TFSI] solid polymer electrolyte. Sci. Rep. 2020, 10, 21140. [Google Scholar] [CrossRef]
- Han, L.; Wang, J.; Mu, X.; Wu, T.; Liao, C.; Wu, N.; Xing, W.; Song, L.; Kan, Y.; Hu, Y. Controllable magnetic field aligned sepiolite nanowires for high ionic conductivity and high safety PEO solid polymer electrolytes. J. Colloid Interface Sci. 2021, 585, 596–604. [Google Scholar] [CrossRef]
- Wen, J.; Zhao, Q.; Jiang, X.; Ji, G.; Wang, R.; Lu, G.; Long, J.; Hu, N.; Xu, C. Graphene Oxide Enabled Flexible PEO-Based Solid Polymer Electrolyte for All-Solid-State Lithium Metal Battery. ACS Appl. Energy Mater. 2021, 4, 3660–3669. [Google Scholar] [CrossRef]
- Jothi, M.A.; Vanitha, D.; Nallamuthu, N.; Manikandan, A.; Bahadur, S.A. Investigations of lithium ion conducting polymer blend electrolytes using biodegradable cornstarch and PVP. Phys. B Condens. Matter 2020, 580, 411940. [Google Scholar] [CrossRef]
- Sangwan, B.; Mathela, S.; Dhapola, P.S.; Singh, P.K.; Tomar, R. Ionic liquid incorporated polyvinylpyrrolidone (PVP) doped with ammonium iodide (NH4I) doped solid polymer electrolyte for energy device. Mater. Today Proc. 2021, 49, 3306–3309. [Google Scholar] [CrossRef]
- Saeed, A.M.N.; Hezam, A.; Al-Gunaid, M.Q.A.; TE, S.; Siddaramaiah. Effect of ethylene carbonate on properties of PVP-CsAlO2-LiClO4 solid polymer electrolytes. Polym.-Plast. Technol. Mater. 2021, 60, 132–146. [Google Scholar] [CrossRef]
- Sreekanth, K.; Siddaiah, T.; Gopal, N.O.; Madhava Kumar, Y.; Ramu, C. Thermal, structural, optical and electrical conductivity studies of pure and Fe3+ ions doped PVP films for semoconducting polymer devices. Mater. Res. Innov. 2021, 25, 95–103. [Google Scholar] [CrossRef]
- Jothi, M.A.; Vanitha, D.; Bahadur, S.A.; Nallamuthu, N. Proton conducting polymer electrolyte based on cornstarch, PVP, and NH4Br for energy storage applications. Ionics 2021, 27, 225–237. [Google Scholar] [CrossRef]
- Sadiq, M.; Raza, M.M.H.; Murtaza, T.; Zulfequar, M.; Ali, J. Sodium Ion-Conducting Polyvinylpyrrolidone (PVP)/Polyvinyl Alcohol (PVA) Blend Electrolyte Films. J. Electron. Mater. 2021, 50, 403–418. [Google Scholar] [CrossRef]
- Nofal, M.M.; Hadi, J.M.; Aziz, S.B.; Brza, M.A.; Asnawi, A.; Dannoun, E.M.A.; Abdullah, A.M.; Kadir, M.F.Z. A Study of Methylcellulose Based Polymer Electrolyte Impregnated with Potassium Ion Conducting Carrier: Impedance, EEC Modeling, FTIR, Dielectric, and Device Characteristics. Materials 2021, 14, 4859. [Google Scholar] [CrossRef]
- Adam, A.A.; Ramamurthi, K.; Margoni, M.M. A Study on Low Cost-Highly Transparent and Conductive Molybdenum Doped Zinc Oxide Thin Films Deposited by Spray Pyrolysis Technique. Am. J. Mater. Res. 2018, 5, 40–45. [Google Scholar]
- Adam, A.A.; Musa, M.; Sani, M. Enhanced optical transmittance of spray deposited zinc oxide thin films for optoelectronic applications. Bayero J. Pure Appl. Sci. 2020, 12, 1–5. [Google Scholar] [CrossRef]
- Abdulkadir, B.A.; Dennis, J.O.; Shukur, M.F.B.A.; Nasef, M.M.E.; Usman, F. Preparation and characterization of gel polymer electrolyte based on PVA-K2CO. Polym.-Plast. Technol. Mater. 2020, 59, 1679–1697. [Google Scholar]
- Dhanasekaran, P.; Lokesh, K.; Ojha, P.K.; Sahu, A.K.; Bhat, S.D.; Kalpana, D. Electrochemical deposition of three-dimensional platinum nanoflowers for high-performance polymer electrolyte fuel cells. J. Colloid Interface Sci. 2020, 572, 198–206. [Google Scholar] [CrossRef]
- Khoon, L.T.; Fui, M.-L.W.; Hassan, N.H.; Su’ait, M.S.; Vedarajan, R.; Matsumi, N.; Bin Kassim, M.; Shyuan, L.K.; Ahmad, A. In situ sol–gel preparation of ZrO2 in nano-composite polymer electrolyte of PVDF-HFP/MG49 for lithium-ion polymer battery. J. Sol-Gel Sci. Technol. 2019, 90, 665–675. [Google Scholar] [CrossRef]
- Mallaiah, Y.; Jeedi, V.R.; Swarnalatha, R.; Raju, A.; Narender Reddy, S.; Sadananda Chary, A. Impact of polymer blending on ionic conduction mechanism and dielectric properties of sodium based PEO-PVdF solid polymer electrolyte systems. J. Phys. Chem. Solids 2021, 155, 110096. [Google Scholar] [CrossRef]
- Ramesh, S.; Lu, S.-C.; Morris, E. Towards magnesium ion conducting poly(vinylidenefluoride-hexafluoropropylene)-based solid polymer electrolytes with great prospects: Ionic conductivity and dielectric behaviours. J. Taiwan Inst. Chem. Eng. 2012, 43, 806–812. [Google Scholar] [CrossRef]
- Abdulkadir, B.A.; Ojur Dennis, J.; Al-Hadeethi, Y.; Shukur, M.F.B.A.; Mkawi, E.M.; Al-Harbi, N.; Ibnaouf, K.H.; Aldaghri, O.; Usman, F.; Abbas Adam, A. Optimization of the Electrochemical Performance of a Composite Polymer Electrolyte Based on PVA-K2CO3-SiO2 Composite. Polymers 2020, 13, 92. [Google Scholar] [CrossRef]
- Hamsan, M.H.; Shukur, M.F.; Kadir, M.F.Z. The effect of NH4NO3 towards the conductivity enhancement and electrical behavior in methyl cellulose-starch blend based ionic conductors. Ionics 2016, 23, 1137–1154. [Google Scholar] [CrossRef]
- Kadir, M.F.Z.; Salleh, N.S.; Hamsan, M.H.; Aspanut, Z.; Majid, N.A.; Shukur, M.F. Biopolymeric electrolyte based on glycerolized methyl cellulose with NH4Br as proton source and potential application in EDLC. Ionics 2018, 24, 1651–1662. [Google Scholar] [CrossRef]
- Nofal, M.M.; Aziz, S.B.; Brza, M.A.; Abdullah, S.N.; Dannoun, E.M.A.; Hadi, J.M.; Murad, A.R.; Al-Saeedi, S.I.; Kadir, M.F.Z. Studies of Circuit Design, Structural, Relaxation and Potential Stability of Polymer Blend Electrolyte Membranes Based on PVA:MC Impregnated with NH4I Salt. Membranes 2022, 12, 284. [Google Scholar] [CrossRef]
- Abdullah, O.G.; Aziz, S.B.; Rasheed, M.A. Structural and optical characterization of PVA:KMnO4 based solid polymer electrolyte. Results Phys. 2016, 6, 1103–1108. [Google Scholar] [CrossRef] [Green Version]
- Salehan, S.S.; Nadirah, B.N.; Saheed, M.S.M.; Yahya, W.Z.N.; Shukur, M.F. Conductivity, structural and thermal properties of corn starch-lithium iodide nanocomposite polymer electrolyte incorporated with Al2O. J. Polym. Res. 2021, 28, 222. [Google Scholar] [CrossRef]
- Aziz, S.B.; Brza, M.; Mishra, K.; Hamsan, M.; Karim, W.O.; Abdullah, R.M.; Kadir, M.; Abdulwahid, R.T. Fabrication of high performance energy storage EDLC device from proton conducting methylcellulose: Dextran polymer blend electrolytes. J. Mater. Res. Technol. 2020, 9, 1137–1150. [Google Scholar] [CrossRef]
- Rahamathullah, R.; Khairul, W.M.; Isa, M.I.N. Contribution of stilbene-imine additives on the structural, ionic conductivity performance and theoretical evaluation on CMC-based biopolymer electrolytes. Carbohydr. Polym. 2020, 250, 116935. [Google Scholar] [CrossRef] [PubMed]
- Saadiah, M.A.; Nagao, Y.; Samsudin, A.S. Enhancement on protonation (H+) with incorporation of flexible ethylene carbonate in CMC–PVA–30 wt.% NH4NO3 film. Int. J. Hydrogen Energy 2021, 46, 17231–17245. [Google Scholar] [CrossRef]
- Abdulkadir, B.A.; Dennis, J.O.; Adam, A.A.; Al-Dhahebi, A.M.; Shukur, M.F. Novel electrospun separator-electrolyte based on PVA-K2CO3-SiO2-cellulose nanofiber for application in flexible energy storage devices. J. Appl. Polym. Sci. 2022, 139, 52308. [Google Scholar] [CrossRef]
- Alves, R.; Sentanin, F.; Sabadini, R.C.; Pawlicka, A.; Silva, M.M. Innovative electrolytes based on chitosan and thulium for solid state applications: Synthesis, structural, and thermal characterization. J. Electroanal. Chem. 2017, 788, 156–164. [Google Scholar] [CrossRef]
- Ait Hana, N.; Aride, J.; Haddad, M.; Benkhouja, K.; Sahraoui, B.; Taibi, M. Electrical and structural analysis of xPbO-(1-x)B2O3 (0.3 ≤ x ≤ 0.9) glasses. Mol. Cryst. Liq. Cryst. 2016, 627, 106–117. [Google Scholar] [CrossRef]
- Pandi, D.V.; Selvasekarapandian, S.; Bhuvaneswari, R.; Premalatha, M.; Monisha, S.; Arunkumar, D.; Junichi, K. Development and characterization of proton conducting polymer electrolyte based on PVA, amino acid glycine and NH4SCN. Solid State Ionics 2016, 298, 15–22. [Google Scholar] [CrossRef]
- Long, M.-C.; Xia, L.-T.; Lyu, T.-B.; Wang, T.; Huang, T.; Chen, L.; Wu, G.; Wang, X.-L.; Wang, Y.-Z. A green and facile way to prepare methylcellulose-based porous polymer electrolytes with high lithium-ion conductivity. Polymer 2019, 176, 256–263. [Google Scholar] [CrossRef]
- Nurhaziqah, A.M.S.; Afiqah, I.Q.; Aziz, M.F.H.A.; Aziz, N.A.N.; Hasiah, S. Optical, Structural and Electrical Studies of Biopolymer Electrolytes Based on Methylcellulose Doped with Ca(NO3). IOP Conf. Ser. Mater. Sci. Eng. 2018, 440, 012034. [Google Scholar] [CrossRef] [Green Version]
- Anilkumar, K.M.; Jinisha, B.; Manoj, M.; Jayalekshmi, S. Poly(ethylene oxide) (PEO)—Poly(vinyl pyrrolidone) (PVP) blend polymer based solid electrolyte membranes for developing solid state magnesium ion cells. Eur. Polym. J. 2017, 89, 249–262. [Google Scholar] [CrossRef]
- Zhang, L.; Wang, X.F.; Peng, Y.L.; Zhao, Y.; Qian, J.Y.; Ding, X. Effect of different ionic liquids acting as plasticizers on the multi-scale structures and physical properties of hydroxypropyl methylcellulose/monosodium phosphate photophobic film. Int. J. Biol. Macromol. 2021, 179, 466–474. [Google Scholar] [CrossRef]
- Genier, F.S.; Burdin, C.V.; Biria, S.; Hosein, I.D. A novel calcium-ion solid polymer electrolyte based on crosslinked poly(ethylene glycol) diacrylate. J. Power Sources 2019, 414, 302–307. [Google Scholar] [CrossRef]
- Kiruthika, S.; Malathi, M.; Selvasekarapandian, S.; Tamilarasan, K.; Maheshwari, T. Conducting biopolymer electrolyte based on pectin with magnesium chloride salt for magnesium battery application. Polym. Bull. 2020, 77, 6299–6317. [Google Scholar] [CrossRef]
- Mustapa, S.R.; Aung, M.M.; Rayung, M. Physico-Chemical, Thermal, and Electrochemical Analysis of Solid Polymer Electrolyte from Vegetable Oil-Based Polyurethane. Polymers 2021, 13, 132. [Google Scholar] [CrossRef]
- Dennis, J.O.; Adam, A.A.; Ali, M.K.M.; Soleimani, H.; Shukur, M.F.B.A.; Ibnaouf, K.H.; Aldaghri, O.; Eisa, M.H.; Ibrahem, M.A.; Bashir Abdulkadir, A.; et al. Substantial Proton Ion Conduction in Methylcellulose/Pectin/Ammonium Chloride Based Solid Nanocomposite Polymer Electrolytes: Effect of ZnO Nanofiller. Membranes 2022, 12, 706. [Google Scholar] [CrossRef]
- Tuan Naiwi, T.S.R.; Aung, M.M.; Ahmad, A.; Rayung, M.; Su’ait, M.S.; Yusof, N.A.; Wynn Lae, K.Z. Enhancement of Plasticizing Effect on Bio-Based Polyurethane Acrylate Solid Polymer Electrolyte and Its Properties. Polymers 2018, 10, 1142. [Google Scholar] [CrossRef] [Green Version]
- Feng, X.; Liu, Q.; Zheng, J.; Xu, Y.; Chen, W. Poly(ethylene oxide)-ethylene carbonate solid binary electrolyte with higher conductivity, lower operating temperature and fully impregnated separator for all solid-state lithium ion batteries. Compos. Commun. 2022, 29, 101026. [Google Scholar] [CrossRef]
- Asnawi, A.S.F.M.; Aziz, S.B.; Brevik, I.; Brza, M.A.; Yusof, Y.M.; Alshehri, S.M.; Ahamad, T.; Kadir, M.F.Z. The Study of Plasticized Sodium Ion Conducting Polymer Blend Electrolyte Membranes Based on Chitosan/Dextran Biopolymers: Ion Transport, Structural, Morphological and Potential Stability. Polymers 2021, 13, 383. [Google Scholar] [CrossRef]
- Aziz, S.B.; Faraj, M.; Abdullah, O.G. Impedance spectroscopy as a novel approach to probe the phase transition and microstructures existing in CS: PEO based blend electrolytes. Sci. Rep. 2018, 8, 14308. [Google Scholar] [CrossRef] [Green Version]
- Abdulkadir, B.A.; Dennis, J.O.; Abd Shukur, M.F.B.; Nasef, M.M.E.; Usman, F.; Adam, A.A.; Adamu, U.A. Dielectric Study of Gel Polymer Electrolyte Based on PVA-K2CO3-SiO. IOP Conf.Ser. Mater. Sci. Eng. 2021, 1092, 012066. [Google Scholar] [CrossRef]
- Kamboj, V.; Arya, A.; Tanwar, S.; Kumar, V.; Sharma, A.L. Nanofiller-assisted Na+-conducting polymer nanocomposite for ultracapacitor: Structural, dielectric and electrochemical properties. J. Mater. Sci. 2021, 56, 6167–6187. [Google Scholar] [CrossRef]
- Dannoun, E.M.A.; Aziz, S.B.; Kadir, M.F.Z.; Brza, M.A.; Nofal, M.M.; Hadi, J.M.; Al-Saeedi, S.I.; Abdulwahid, R.T. The study of impedance, ion transport properties, EEC modeling, dielectric and electrochemical characteristics of plasticized proton conducting PVA based electrolytes. J. Mater. Res. Technol. 2022, 17, 1976–1985. [Google Scholar] [CrossRef]
- Abdulkareem, S.S. Structural, morphological and electrical properties of chitosan/methylcellulose blend polymer doped with different concentrations of NH4NO. Mater. Res. Express 2021, 8, 086301. [Google Scholar] [CrossRef]
- Aziz, S.B.; Brza, M.A.; Brevik, I.; Hafiz, M.H.; Asnawi, A.S.F.M.; Yusof, Y.M.; Abdulwahid, R.T.; Kadir, M.F.Z. Blending and Characteristics of Electrochemical Double-Layer Capacitor Device Assembled from Plasticized Proton Ion Conducting Chitosan:Dextran:NH4PF6 Polymer Electrolytes. Polymers 2020, 12, 2103. [Google Scholar] [CrossRef]
- Aziz, S.B.; Hamsan, M.; Abdullah, R.M.; Abdulwahid, R.T.; Brza, M.; Marif, A.S.; Kadir, M.J.I. Protonic EDLC cell based on chitosan (CS): Methylcellulose (MC) solid polymer blend electrolytes. Ionics 2020, 26, 1829–1840. [Google Scholar] [CrossRef]
- Nofal, M.M.; Aziz, S.B.; Hadi, J.M.; Abdulwahid, R.T.; Dannoun, E.M.A.; Marif, A.S.; Al-Zangana, S.; Zafar, Q.; Brza, M.A.; Kadir, M.F.Z. Synthesis of Porous Proton Ion Conducting Solid Polymer Blend Electrolytes Based on PVA: CS Polymers: Structural, Morphological and Electrochemical Properties. Materials 2020, 13, 4890. [Google Scholar] [CrossRef]
- Shamsuri, N.A.; Zaine, S.N.A.; Mohamed Yusof, Y.; Shukur, M.F. Ion conducting methylcellulose-polyvinyl alcohol blend based electrolytes incorporated with ammonium thiocyanate for electric double layer capacitor application. J. Appl. Polym. Sci. 2022, 139, 52076. [Google Scholar] [CrossRef]
- Aziz, S.B.; Nofal, M.M.; Abdulwahid, R.T.; Ghareeb, H.O.; Dannoun, E.M.A.; Abdullah, R.M.; Hamsan, M.H.; Kadir, M.F.Z. Plasticized Sodium-Ion Conducting PVA Based Polymer Electrolyte for Electrochemical Energy Storage—EEC Modeling, Transport Properties, and Charge-Discharge Characteristics. Polymers 2021, 13, 803. [Google Scholar] [CrossRef]
- Hadi, J.M.; Aziz, S.B.; Brza, M.A.; Kadir, M.F.Z.; Abdulwahid, R.T.; Ali Al-Asbahi, B.; Ahmed Ali Ahmed, A. Structural and energy storage behavior of ion conducting biopolymer blend electrolytes based on methylcellulose: Dextran polymers. Alex. Eng. J. 2022, 61, 9273–9285. [Google Scholar] [CrossRef]
- Regu, T.; Ambika, C.; Karuppasamy, K.; Rajan, H.; Vikraman, D.; Jeon, J.-H.; Kim, H.-S.; Raj, T.A.B. Proton transport and dielectric properties of high molecular weight polyvinylpyrrolidone (PVP K90) based solid polymer electrolytes for portable electrochemical devices. J Mater Sci: Mater Electron. 2019, 30, 11735–11747. [Google Scholar]
- Ambika, C.; Karuppasamy, K.; Vikraman, D.; Lee, J.Y.; Regu, T.; Ajith Bosco Raj, T.; Prasanna, K.; Kim, H.-S. Effect of dimethyl carbonate (DMC) on the electrochemical and cycling properties of solid polymer electrolytes (PVP-MSA) and its application for proton batteries. Solid State Ionics 2018, 321, 106–114. [Google Scholar] [CrossRef]
- Aziz, S.B.; Brevik, I.; Hamsan, M.H.; Brza, M.A.; Nofal, M.M.; Abdullah, A.M.; Rostam, S.; Al-Zangana, S.; Muzakir, S.K.; Kadir, M.F.Z. Compatible solid polymer electrolyte based on methyl cellulose for energy storage application: Structural, electrical, and electrochemical properties. Polymers 2020, 12, 2257. [Google Scholar] [CrossRef]
- Vahini, M.; Muthuvinayagam, M. Synthesis and electrochemical studies on sodium ion conducting PVP based solid polymer electrolytes. J. Mater. Sci. Mater. Electron. 2019, 30, 5609–5619. [Google Scholar] [CrossRef]
- Kumar, M.S.; Rao, M.C. Effect of Al2O3 on structural and dielectric properties of PVP-CH3COONa based solid polymer electrolyte films for energy storage devices. Heliyon 2019, 5, e02727. [Google Scholar] [CrossRef] [Green Version]
Polymer-Salt Complex | RT Ionic Conductivity (Scm−1) | Potential Window (V) | Ion Transference Number | Ref. |
---|---|---|---|---|
CS/DX/NH4PF6/glycerol | 3.0 × 10−4 | 1.5 | 0.96 | [75] |
CS/MC/NH4NO3/glycerol | 1.31 × 10−4 | 1.87 | 0.93 | [22] |
CS/MC/NH4I | 1.93 × 10−4 | 2.10 | 0.93 | [76] |
MC/PC/K3PO4/glycerol | 3.0 × 10−4 | 4.19 | - | [6] |
MC/PC/NH4Cl/ZnO | 3.13 × 10−4 | 4.55 | - | [66] |
DX/CS/NafT/glycerol | 6.10 × 10−5 | 2.55 | 0.99 | [69] |
PVA/CS/NH4SCN | 1.36 × 10−5 | 2.25 | 0.72 | [77] |
MC/PVP/K2CO3/EC | 3.88 × 10−4 | 5.02 | 0.949 | This work |
Scan Rate (mVs−1) | Specific Capacitance (Fg−1) |
---|---|
5 | 54.936 |
10 | 45.849 |
20 | 36.065 |
40 | 26.797 |
80 | 18.936 |
100 | 16.600 |
200 | 10.897 |
500 | 5.923 |
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Adam, A.A.; Ali, M.K.M.; Dennis, J.O.; Soleimani, H.; Shukur, M.F.B.A.; Ibnaouf, K.H.; Aldaghri, O.A.; Ibrahem, M.A.; Abdel All, N.F.M.; Bashir Abdulkadir, A. Innovative Methylcellulose-Polyvinyl Pyrrolidone-Based Solid Polymer Electrolytes Impregnated with Potassium Salt: Ion Conduction and Thermal Properties. Polymers 2022, 14, 3055. https://doi.org/10.3390/polym14153055
Adam AA, Ali MKM, Dennis JO, Soleimani H, Shukur MFBA, Ibnaouf KH, Aldaghri OA, Ibrahem MA, Abdel All NFM, Bashir Abdulkadir A. Innovative Methylcellulose-Polyvinyl Pyrrolidone-Based Solid Polymer Electrolytes Impregnated with Potassium Salt: Ion Conduction and Thermal Properties. Polymers. 2022; 14(15):3055. https://doi.org/10.3390/polym14153055
Chicago/Turabian StyleAdam, Abdullahi Abbas, Mohammed Khalil Mohammed Ali, John Ojur Dennis, Hassan Soleimani, Muhammad Fadhlullah Bin Abd. Shukur, Khalid Hassan Ibnaouf, Osamah A. Aldaghri, Moez A. Ibrahem, Naglaa F. M. Abdel All, and Abubakar Bashir Abdulkadir. 2022. "Innovative Methylcellulose-Polyvinyl Pyrrolidone-Based Solid Polymer Electrolytes Impregnated with Potassium Salt: Ion Conduction and Thermal Properties" Polymers 14, no. 15: 3055. https://doi.org/10.3390/polym14153055