Emerging Applications of Versatile Polyaniline-Based Polymers in the Food Industry
Abstract
:1. Introduction
2. Applications of PANI in the Food Industry
2.1. Biodegradable Food Packaging
Matrix | Preparation | Results | Ref |
---|---|---|---|
Chitosan | In situ polymerisation |
| [78] |
| [79] | ||
WPI | Ex situ polymerisation |
| [80] |
Starch | Ex situ polymerisation |
| [6] |
Starch/ZnO NPs | Impregnation on ZnO NP |
| [85] |
CNF | In situ polymerisation |
| [81] |
Cellulose acetate | Ex situ polymerisation |
| [86] |
CNWs | In situ polymerisation |
| [82] |
PLA | Ex situ polymerisation |
| [29] |
| [83] |
2.2. Active Food Packaging
2.3. Intelligent Food Packaging
2.4. Food Safety Control
Contaminant | Device | Target | Food | Ref |
---|---|---|---|---|
Antibiotic | β-Lactamase immobilised on PANI-coated optical fibre | β-lactam antibiotics | Packaged milk, cow milk, buffalo milk | [147] |
SPME based on Cu/PANI/GO coupled with HPLC-UV | DOX, OXY, TET | Water, pasteurised bovine milk | [150] | |
MSPE based on RA/MMPANI/HM/CAS coupled with HPLC | DOX, OXY, TPM, PEN-G | Milk | [149] | |
PANI NW-based MIP deposited on a gold electrode | CHL | - | [148] | |
PANI/GO/QD-based MIP probe | LOM | Milk, chicken meat, egg | [167] | |
NSAID | SPE based on PANI NFM coupled with UPLC-MS/MS | IBU, NAP, DC, CPF, KTP, TLF, SA | Meat, egg | [152] |
CS/PANI/ZnAl-LDH | NAP | - | [154] | |
Au/PANI-based MIP membrane | IBU | - | [153] | |
SPME based on graphene/PANI coupled with IMS | MFA, IBU | - | [168] | |
Heavy metal ions | MSPE based on PANI-coated magnetic NPs coupled with FAAS | Co(II) | Soft drinks, spices, vegetables, water | [169] |
PAN/PANI membrane | Pb(II), Cr(VI) | Water | [163] | |
Electrochemically assisted SPE based on PANI NF/GO coupled with FAAS | Pb(II) | Juices (peach, orange, grape), water (tap, mineral) | [162] | |
MSPE based on SiO2-magnetic GO/PANI/PPy coupled with ICP-MS | Cr(III), Pb(II) | Water, rice, milk, wine | [156] | |
SPE based on nanostructured PANI coupled with FAAS | Cu(II), Pb(II) | Shrimp, crab, fish, apple, tomato, mushroom, potato, water | [170] |
2.5. Electronic Noses
3. Conclusions and Future Perspectives
Author Contributions
Funding
Institutional Review Board Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Composites | Antioxidant Properties | Antimicrobial Towards | Food | Ref |
---|---|---|---|---|
Chitosan/PANI | √ | - | - | [78] |
CS/PANI-ZnO NP | - | S. aureus E. coli | - | [85] |
PANI-(PMMA/CNC) | √ | B. cereus S. typhimurium | - | [106] |
Chitosan/PANI | - | A. niger E. coli | - | [79] |
PANI | - | S. aureus E.coli | - | [108] |
Cellulose/PANI | ||||
Chitosan-ZnO/PANI | - | S. aureus P. aeruginosa | - | [109] |
Dextrin/PANI | √ | - | - | [110] |
PCL/NF PANI | √ | S. aureus E. coli | - | [111] |
LLDPE/NR PANI | √ | S. aureus | Fish oil | [112] |
EC/PANI | √ | - | Fish oil | [113] |
PET/NR PANI | √ | - | - | [114] |
PLA/PANI/ZnO/CuO | √ | S. aureus E. coli | Orange juice | [107] |
Method | Label | Target | Food | Ref |
---|---|---|---|---|
Colourimetric | PANI-Pec | E. coli | Milk and butter | [130] |
Starch/PANI | NH3 | - | [6] | |
PANI/TPE | Spoilage gas | Red drum fish | [128] | |
PANI | TMA | Blue marlin fish | [126] | |
PANI | NH3 and DMA | Tilapia | [129] | |
PANI-Pec NP | E. coli | Tap water | [136] | |
PANI-PSS | TEA | - | [137] | |
PANI | NH3 | Milkfish | [138] | |
Resistometric | PLA/PANI/CuO/ZnO | Spoilage gas | Orange juice | [107] |
PANI/Ag NW/Silk | TMA | Pork | [132] | |
PTS-PANI | NH3, putrescine, and cadaverine | Beef, pork, fish, and chicken meat | [139] | |
TiO2-PANI/SFF | NH3 | Pork | [140] | |
PANI-PI | NH3 | Meat | [141] | |
Potentiometric | PANI NF/PET | pH | Milk & apple | [142] |
Conductometric | HEC/PANI | pH | Milk | [143] |
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Chia, M.-R.; Phang, S.-W.; Ahmad, I. Emerging Applications of Versatile Polyaniline-Based Polymers in the Food Industry. Polymers 2022, 14, 5168. https://doi.org/10.3390/polym14235168
Chia M-R, Phang S-W, Ahmad I. Emerging Applications of Versatile Polyaniline-Based Polymers in the Food Industry. Polymers. 2022; 14(23):5168. https://doi.org/10.3390/polym14235168
Chicago/Turabian StyleChia, Min-Rui, Sook-Wai Phang, and Ishak Ahmad. 2022. "Emerging Applications of Versatile Polyaniline-Based Polymers in the Food Industry" Polymers 14, no. 23: 5168. https://doi.org/10.3390/polym14235168