Synthesis, Characterization, and Gas Adsorption Performance of Amine-Functionalized Styrene-Based Porous Polymers
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. Synthesis of Porous Polymer
2.2.1. Preparation of Hyper-Crosslinked Porous Polymer Sample (HCLPP)
2.2.2. Preparation of Dendrimer
2.2.3. Functionalization of HCLPP
2.3. Characterization
2.3.1. Properties of the HCLPPs
2.3.2. Characterization of Dendrimers
2.4. Gas Adsorption Measurement
3. Results and Discussion
3.1. Properties of HCLPPs
3.2. Gas Adsorption and Selectivity
Sample | SBET, (m2 g−1) | CO2, (μmol g−1) 1 bar, 273 K, 298 K | CO2/N2 Selectivity | Ref. | |
---|---|---|---|---|---|
HCP-3A | 179 | 932 | 9 | ||
HCP-6A | 299 | 1604 | 22 | ||
HCP-12A | 406 | 1987 | 273 K | 23 | [27] |
HCP-24A | 548 | 1715 | 20 | ||
HCP-12B | 488 | 1771 | 20 | ||
HCP-12C | 573 | 1846 | 15 | ||
HCP-0 | 425 | 1201 | 17 | ||
HCP-A | 777 | 1473 | 38 | ||
HCP-B | 768 | 1178 | 298 K | 25 | [28] |
HCP-C | 611 | 1258 | 15 | ||
HCP-D | 673 | 1359 | 15 | ||
P(DVB-VBC)-31 | 744 | 390 | 20 | ||
P(DVB-VBC)-31-EDA | 389 | 1150 | 152 | ||
P(DVB-VBC)-31-DETA | 376 | 1440 | 298 K | 223 | [32] |
P(DVB-VBC)-11 | 134 | 180 | - | ||
P(DVB-VBC)-11-EDA | 91 | 1150 | - | ||
P(DVB-VBC)-11-DETA | 48 | 750 | - | ||
HCLPP | 757 | 1010 | 28 | ||
HCLPP-EDA | 283 | 910 | 298 K | 81 | This work |
HCLPP-DETA | 277 | 820 | 71 | ||
HCLPP-DENDRIMER | 616 | 1100 | 29 |
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Data Availability Statement
Conflicts of Interest
References
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Sample | SBET a (m2 g−1) | Smeso b (m2 g−1) | Vtot c (mm3liq g−1) | Vmicro d (mm3liq g−1) |
---|---|---|---|---|
HCLPP | 757 | 310 | 408 | 226 |
HCLPP-EDA | 283 | 93 | 157 | 97 |
HCLPP-DETA | 277 | 132 | 159 | 76 |
HCLPP-DENDRIMER | 616 | 194 | 341 | 218 |
Sample | C (%) | Cl (%) | N (%) | S (%) | Si (%) |
---|---|---|---|---|---|
HCLPP | 97.79 | 0.42 | 1.74 | - | 0.05 |
HCLPP-EDA | 90.62 | 0.08 | 9.21 | - | 0.10 |
HCLPP-DETA | 90.55 | 0.05 | 9.32 | - | 0.07 |
HCLPP-DENDRIMER | 99.93 | 0.30 | 5.37 | 0.20 | 0.21 |
Sample | CO2 (μmol g−1) | CH4 (μmol g−1) | N2 (μmol g−1) | H2 (μmol g−1) | O2 (μmol g−1) |
---|---|---|---|---|---|
HCLPP | 1010 | 310 | 90 | 21 | 12 |
HCLPP-EDA | 910 | 130 | 33 | 15 | 47 |
HCLPP-DETA | 820 | 130 | 29 | 12 | 42 |
HCLPP-DENDRIMER | 1100 | 240 | 63 | 17 | 89 |
Sample | CO2 (μmol m2) | CH4 (μmol m2) | N2 (μmol m2) | H2 (μmol m2) | O2 (μmol m2) |
---|---|---|---|---|---|
HCLPP | 1.33 | 0.41 | 0.12 | 0.03 | 0.02 |
HCLPP-EDA | 3.22 | 0.46 | 0.12 | 0.05 | 0.17 |
HCLPP-DETA | 2.96 | 0.47 | 0.10 | 0.04 | 0.15 |
HCLPP-DENDRIMER | 1.79 | 0.39 | 0.10 | 0.03 | 0.14 |
Sample | CO2/CH4 (-) | CO2/N2 (-) | CO2/H2 (-) | O2/N2 (-) | CH4/N2 (-) |
---|---|---|---|---|---|
HCLPP | 5.8 | 27.6 | 74.2 | 0.1 | 4.7 |
HCLPP-EDA | 16.0 | 81.0 | 188.9 | 1.4 | 5.1 |
HCLPP-DETA | 12.8 | 71.4 | 172.6 | 1.5 | 5.6 |
HCLPP-DENDRIMER | 6.2 | 28.9 | 109.3 | 1.4 | 4.7 |
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Setnickova, K.; Jerabek, K.; Strasak, T.; Mullerova, M.; Jandova, V.; Soukup, K.; Petrickovic, R.; Tseng, H.-H.; Uchytil, P. Synthesis, Characterization, and Gas Adsorption Performance of Amine-Functionalized Styrene-Based Porous Polymers. Polymers 2023, 15, 13. https://doi.org/10.3390/polym15010013
Setnickova K, Jerabek K, Strasak T, Mullerova M, Jandova V, Soukup K, Petrickovic R, Tseng H-H, Uchytil P. Synthesis, Characterization, and Gas Adsorption Performance of Amine-Functionalized Styrene-Based Porous Polymers. Polymers. 2023; 15(1):13. https://doi.org/10.3390/polym15010013
Chicago/Turabian StyleSetnickova, Katerina, Karel Jerabek, Tomas Strasak, Monika Mullerova, Vera Jandova, Karel Soukup, Roman Petrickovic, Hui-Hsin Tseng, and Petr Uchytil. 2023. "Synthesis, Characterization, and Gas Adsorption Performance of Amine-Functionalized Styrene-Based Porous Polymers" Polymers 15, no. 1: 13. https://doi.org/10.3390/polym15010013