Design of Novel Functional Conductive Structures and Preparation of High-Hole-Mobility Polymer Transistors by Green Synthesis Using Acceptor–Donor–Acceptor Strategies
Abstract
:1. Introduction
2. Materials and Methods
2.1. Synthesis Procedures for Small-Molecule Intermediates and Monomer
2.2. Synthesis Procedure for Conductive Polymers PTVDPP-BSz
2.3. Characterization Steps and Details of the Intermediates and Polymer
2.4. Device Preparation for Measuring Conductivity of Material
3. Results
3.1. Preparation Route and Molecular Composition Analysis of the Polymer PTVDPP-BSz
3.2. Theoretical Simulation Calculations
3.3. Photochemical Properties
3.4. Electrochemical Properties
3.5. PFET Device Performance
3.6. Microstructure and Morphological Analysis of PTVDPP-BSz Film
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Mn | Mw | Đ 2 | C 3 | H 3 | N 3 | |
---|---|---|---|---|---|---|
(kDa) | (kDa) | (%) | (%) | (%) | ||
PTVDPP-BSz | 22.82 | 49.43 | 2.16 | 73.29 | 8.56 | 5.67 |
repeating unit 1 | - | - | - | 73.51 | 8.87 | 5.36 |
Coating Speed (rpm) | Annealing Temperature (°C) | µmax 1 (cm2/(V s)) | µave 2 (cm2/(V s)) | Threshold Voltage (V) | On/Off Ratio |
---|---|---|---|---|---|
3000 | 150 | 0.34 | 0.32 | 4.90 | 7.63 × 103 |
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Ren, S.; Wang, S.; Chen, J.; Yi, Z. Design of Novel Functional Conductive Structures and Preparation of High-Hole-Mobility Polymer Transistors by Green Synthesis Using Acceptor–Donor–Acceptor Strategies. Polymers 2024, 16, 396. https://doi.org/10.3390/polym16030396
Ren S, Wang S, Chen J, Yi Z. Design of Novel Functional Conductive Structures and Preparation of High-Hole-Mobility Polymer Transistors by Green Synthesis Using Acceptor–Donor–Acceptor Strategies. Polymers. 2024; 16(3):396. https://doi.org/10.3390/polym16030396
Chicago/Turabian StyleRen, Shiwei, Sichun Wang, Jinyang Chen, and Zhengran Yi. 2024. "Design of Novel Functional Conductive Structures and Preparation of High-Hole-Mobility Polymer Transistors by Green Synthesis Using Acceptor–Donor–Acceptor Strategies" Polymers 16, no. 3: 396. https://doi.org/10.3390/polym16030396