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Polymers, Volume 16, Issue 3

2024 February-1 - 141 articles

Cover Story: Titanium dioxide is a highly attractive material due to its self-cleaning ability that can be utilized in solar panels as an anti-reflective coating and anti-bacterial surface. These surfaces self-clean by decomposing organic contaminants and washing them away under UV irradiation. With a high surface-to-volume ratio, the performances of the TiO2 coatings can be enhanced. In this study, highly porous TiO2 coatings that revealed excellent photocatalytic degradation performance and stability were synthesized by swelling-assisted sequential infiltration synthesis (SIS) of a block copolymer template. View this paper
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Articles (141)

  • Article
  • Open Access
14 Citations
2,904 Views
22 Pages

5 February 2024

In this study, the synthesis and characterization of grafted cellulose fiber with binary monomers mixture obtained using a KMnO4/citric acid redox initiator were investigated. Acrylonitrile (AN) was graft copolymerized with acrylic acid (AA) and styr...

  • Article
  • Open Access
10 Citations
2,435 Views
17 Pages

5 February 2024

This study addresses the challenges of modeling flexible connections in composite structures employing a polymeric adhesive layer. These types of connections provide a more uniform stress distribution compared to conventional rigid connectors. Howeve...

  • Review
  • Open Access
41 Citations
14,365 Views
34 Pages

Wastewater Treatment Using Membrane Bioreactor Technologies: Removal of Phenolic Contaminants from Oil and Coal Refineries and Pharmaceutical Industries

  • Mohd Jahir Khan,
  • Agung Wibowo,
  • Zoheb Karim,
  • Pattaraporn Posoknistakul,
  • Babasaheb M. Matsagar,
  • Kevin C.-W. Wu and
  • Chularat Sakdaronnarong

5 February 2024

Huge amounts of noxious chemicals from coal and petrochemical refineries and pharmaceutical industries are released into water bodies. These chemicals are highly toxic and cause adverse effects on both aquatic and terrestrial life. The removal of haz...

  • Review
  • Open Access
19 Citations
4,363 Views
18 Pages

Rheology of Highly Filled Polymer Compositions—Limits of Filling, Structure, and Transport Phenomena

  • Alexander Ya. Malkin,
  • Valery G. Kulichikhin,
  • Svetlana Yu. Khashirova,
  • Igor D. Simonov-Emelyanov and
  • Anton V. Mityukov

5 February 2024

The current state of the rheology of various polymeric and other materials containing a high concentration of spherical solid filler is considered. The physics of the critical points on the concentration scale are discussed in detail. These points de...

  • Review
  • Open Access
38 Citations
9,102 Views
32 Pages

Recent Developments in Polyurea Research for Enhanced Impact Penetration Resistance and Blast Mitigation

  • Yifan Wang,
  • Lailong Ding,
  • Jiayu Lin,
  • Xishun Qiu,
  • Chao Wu,
  • Changhao Liu,
  • Yicheng Tian,
  • Rui Zhang,
  • Weibo Huang and
  • Mingliang Ma

5 February 2024

Polyurea has gained significant attention in recent years as a functional polymer material, specifically regarding blast and impact protection. The molecular structure of polyurea is characterized by the rapid reaction between isocyanate and the term...

  • Article
  • Open Access
3 Citations
3,612 Views
17 Pages

5 February 2024

Epoxy resins find extensive utility across diverse applications owing to their exceptional adhesion capabilities and robust mechanical and thermal characteristics. However, the demanding reaction conditions, including extended reaction times and elev...

  • Article
  • Open Access
15 Citations
6,654 Views
16 Pages

5 February 2024

The Diels–Alder (D–A) reaction between furan and maleimide is a thermally reversible reaction that has become a vital chemical technique for designing polymer structures and functions. The kinetics of this reaction, particularly in polyme...

  • Article
  • Open Access
1,660 Views
15 Pages

5 February 2024

Crystalline poly-para-xylylene (parylene) has the potential for use as a protective membrane to delay the nucleation of explosives by separating the explosives and their decomposition products to decrease the explosive sensitivity. Here, molecular dy...

  • Article
  • Open Access
15 Citations
4,372 Views
12 Pages

5 February 2024

Thermogravimetric analysis (TGA) is crucial for describing polymer materials’ thermal behavior as a result of temperature changes. While available TGA data substantiated in the literature significantly focus attention on TGA performed at higher...

  • Article
  • Open Access
11 Citations
3,170 Views
15 Pages

4 February 2024

The performance of a viscoelastic damper is governed by the mechanical properties of the viscoelastic material, which are sensitive to prestrain. Among viscoelastic materials, carbon black (CB)-filled rubber vulcanizate is commonly used in structural...

  • Article
  • Open Access
10 Citations
2,824 Views
17 Pages

On Cyclic-Fatigue Crack Growth in Carbon-Fibre-Reinforced Epoxy–Polymer Composites

  • Silvain Michel,
  • Neal Murphy,
  • Anthony J. Kinloch and
  • Rhys Jones

4 February 2024

The growth of cracks between plies, i.e., delamination, in continuous fibre polymer matrix composites under cyclic-fatigue loading in operational aircraft structures has always been a very important factor, which has the potential to significantly de...

  • Article
  • Open Access
3 Citations
2,940 Views
19 Pages

4 February 2024

Poly(D,L-lactide-co-glycolide is a biodegradable copolymer that can release pharmaceuticals. These pharmaceuticals can provide local therapy and also avert the clinical issues that occur when a drug must be given continuously and/or automatically. Ho...

  • Article
  • Open Access
7 Citations
3,704 Views
12 Pages

Water-Based Generators with Cellulose Acetate: Uncovering the Mechanisms of Power Generation

  • Seung-Hwan Lee,
  • Hyun-Woo Lee,
  • So Hyun Baek,
  • Jeungjai Yun,
  • Yongbum Kwon,
  • Yoseb Song,
  • Bum Sung Kim,
  • Yong-Ho Choa and
  • Da-Woon Jeong

4 February 2024

Power generation technologies based on water movement and evaporation use water, which covers more than 70% of the Earth’s surface and can also generate power from moisture in the air. Studies are conducted to diversify materials to increase po...

  • Article
  • Open Access
12 Citations
4,888 Views
19 Pages

Thermally Conductive and Electrically Insulating Polymer-Based Composites Heat Sinks Fabricated by Fusion Deposition Modeling

  • Simone Bagatella,
  • Annacarla Cereti,
  • Francesco Manarini,
  • Marco Cavallaro,
  • Raffaella Suriano and
  • Marinella Levi

4 February 2024

This study explores the potential of novel boron nitride (BN) microplatelet composites with combined thermal conduction and electrical insulation properties. These composites are manufactured through Fusion Deposition Modeling (FDM), and their applic...

  • Article
  • Open Access
5 Citations
2,280 Views
18 Pages

4 February 2024

This study is focused on investigating the rheological and mechanical properties of highly oxidized graphite (GrO) incorporated into a poly (lactic acid) (PLA) matrix composite. Furthermore, the samples were annealed at 110 °C for 30 min to study...

  • Article
  • Open Access
4 Citations
2,593 Views
19 Pages

Exploring Functional Polymers in the Synthesis of Luminescent ZnO Quantum Dots for the Detection of Cr6+, Fe2+, and Cu2+

  • Leire San José,
  • Nastasiya Yuriychuk,
  • Olga García,
  • Mar López-González and
  • Isabel Quijada-Garrido

3 February 2024

The main aim of this work is to demonstrate that well-defined methacrylate-based copolymers with oligoethylene glycol side chains and functional groups such as thiol and glycidyl, obtained by photo-initiated reversible addition-fragmentation chain tr...

  • Article
  • Open Access
4 Citations
2,007 Views
14 Pages

Polybenzoxazine-Based Nitrogen-Containing Porous Carbon and Their Composites with NiCo Bimetallic Oxides for Supercapacitor Applications

  • Thirukumaran Periyasamy,
  • Shakila Parveen Asrafali,
  • Seong-Cheol Kim,
  • Deivasigamani Ranjith Kumar and
  • Jaewoong Lee

3 February 2024

Supercapacitors (SCs) are considered as emerging energy storage devices that bridge the gap between electrolytic capacitors and rechargeable batteries. However, due to their low energy density, their real-time usage is restricted. Hence, to enhance t...

  • Article
  • Open Access
8 Citations
5,531 Views
13 Pages

3 February 2024

Carbon nanotubes (CNTs), known for their exceptional mechanical, thermal, and electrical properties, are being explored as cement nanofillers in the construction field. However, due to the limited water dispersion of CNTs, polymer dispersing agents l...

  • Article
  • Open Access
5 Citations
2,809 Views
18 Pages

Nanostructured Poly-l-lactide and Polyglycerol Adipate Carriers for the Encapsulation of Usnic Acid: A Promising Approach for Hepatoprotection

  • Benedetta Brugnoli,
  • Greta Perna,
  • Sara Alfano,
  • Antonella Piozzi,
  • Luciano Galantini,
  • Eleni Axioti,
  • Vincenzo Taresco,
  • Alessia Mariano,
  • Anna Scotto d’Abusco and
  • Iolanda Francolini
  • + 1 author

3 February 2024

The present study investigates the utilization of nanoparticles based on poly-l-lactide (PLLA) and polyglycerol adipate (PGA), alone and blended, for the encapsulation of usnic acid (UA), a potent natural compound with various therapeutic properties...

  • Article
  • Open Access
1,749 Views
21 Pages

A Theoretical Investigation of the Polyaddition of an AB2+A2+B4 Monomer Mixture

  • Sergei V. Karpov,
  • Artem Iakunkov,
  • Dmitry A. Chernyaev,
  • Vladimir G. Kurbatov,
  • Georgiy V. Malkov and
  • Elmira R. Badamshina

3 February 2024

Hyperbranched polymers (HBPs) are widely applied nowadays as functional materials for biomedicine needs, nonlinear optics, organic semiconductors, etc. One of the effective and promising ways to synthesize HBPs is a polyaddition of AB2+A2+B4 monomers...

  • Article
  • Open Access
2 Citations
3,613 Views
15 Pages

2 February 2024

Melt expansion followed by compression has been utilized for high-speed filling. In general, this technology was developed for a machine level. Recently, mold-level technology has been tried. In this study, an expansion injection molding process was...

  • Article
  • Open Access
2 Citations
2,373 Views
17 Pages

2 February 2024

Bending is one of the dominant material deformation mechanisms that occurs during the forming process of unidirectional (UD) thermoplastic tapes. Experimental characterization of the bending behavior at processing temperatures is crucial to obtaining...

  • Review
  • Open Access
89 Citations
21,599 Views
28 Pages

Nanocellulose Composite Films in Food Packaging Materials: A Review

  • Yanting Xu,
  • Zhenzeng Wu,
  • Ao Li,
  • Nairong Chen,
  • Jiuping Rao and
  • Qinzhi Zeng

2 February 2024

Owing to the environmental pollution caused by petroleum-based packaging materials, there is an imminent need to develop novel food packaging materials. Nanocellulose, which is a one-dimensional structure, has excellent physical and chemical properti...

  • Article
  • Open Access
13 Citations
2,959 Views
16 Pages

Nanocomposites Based on Thermoplastic Acrylic Resin with the Addition of Chemically Modified Multi-Walled Carbon Nanotubes

  • Szymon Demski,
  • Dariusz Brząkalski,
  • Maciej Gubernat,
  • Kamil Dydek,
  • Paweł Czaja,
  • Konrad Żochowski,
  • Paulina Kozera,
  • Zuzanna Krawczyk,
  • Bogna Sztorch and
  • Anna Boczkowska
  • + 3 authors

2 February 2024

The main goal of this work was an improvement in the mechanical and electrical properties of acrylic resin-based nanocomposites filled with chemically modified carbon nanotubes. For this purpose, the surface functionalization of multi-walled carbon n...

  • Article
  • Open Access
35 Citations
3,699 Views
16 Pages

2 February 2024

Graphene-based materials have been widely studied in the field of supercapacitors. However, their electrochemical properties and applications are still restricted by the susceptibility of graphene-based materials to curling and agglomeration during p...

  • Article
  • Open Access
6 Citations
2,481 Views
21 Pages

2 February 2024

Plastic deformation of low/high density polyethylene (LDPE/HDPE) was analyzed in this work using positron annihilation lifetime spectroscopy (PALS). It was shown that in undeformed LDPE, both the mean ortho-positronium lifetime (τ3) and its dispe...

  • Article
  • Open Access
9 Citations
2,385 Views
18 Pages

Toward Producing Biopolyethylene/Babassu Fiber Biocomposites with Improved Mechanical and Thermomechanical Properties

  • Eduardo da Silva Barbosa Ferreira,
  • Fabiano Santana da Silva,
  • Carlos Bruno Barreto Luna,
  • Anna Raffaela de Matos Costa,
  • Fernanda Menezes de Sousa,
  • Laura Hecker de Carvalho,
  • Renate Maria Ramos Wellen and
  • Edcleide Maria Araújo

2 February 2024

The development of polymeric biocomposites containing natural fibers has grown over the years due to the properties achieved and its eco-friendly nature. Thus, biocomposites involving a polymer from a renewable source (Biopolyethylene (BioPE)) and ba...

  • Article
  • Open Access
3 Citations
4,181 Views
13 Pages

Fabrication of Fish Scale-Based Gelatin Methacryloyl for 3D Bioprinting Application

  • Kitipong Pasanaphong,
  • Danai Pukasamsombut,
  • Sani Boonyagul,
  • Sukanya Pengpanich,
  • Tulyapruek Tawonsawatruk,
  • Danuphat Wilairatanarporn,
  • Kittisak Jantanasakulwong,
  • Pornchai Rachtanapun,
  • Ruedee Hemstapat and
  • Nuttapol Tanadchangsaeng
  • + 1 author

1 February 2024

Gelatin methacryloyl (GelMA) is an ideal bioink that is commonly used in bioprinting. GelMA is primarily acquired from mammalian sources; however, the required amount makes the market price extremely high. Since garbage overflow is currently a global...

  • Article
  • Open Access
11 Citations
2,656 Views
19 Pages

1 February 2024

Due to high filler loading, clean, commercial, thermoplastic, flame-retardant materials are mechanically unstable when insulating wires and cables. In this study, composite formulations of linear low-density polyethylene (LLDPE)/ethylene–vinyl...

  • Article
  • Open Access
9 Citations
3,213 Views
14 Pages

1 February 2024

Temperature-responsive separation membranes can significantly change their permeability and separation properties in response to changes in their surrounding temperature, improving efficiency and reducing membrane costs. This study focuses on the mod...

  • Article
  • Open Access
5 Citations
1,924 Views
14 Pages

1 February 2024

Polyelectrolyte–surfactant complexes (PESCs) have garnered significant attention due to their extensive range of biological and industrial applications. Most present applications are predominantly used in liquid or emulsion states, which limits...

  • Article
  • Open Access
8 Citations
2,939 Views
16 Pages

1 February 2024

Recent focus on cellulose nanomaterials, particularly biodegradable and biocompatible cellulose nanocrystals (CNCs), has prompted their use as emulsion stabilizers. CNCs, when combined with salt, demonstrate enhanced emulsion stabilization. This stud...

  • Article
  • Open Access
8 Citations
4,653 Views
18 Pages

1 February 2024

Antioxidants are essential to the polymer industry. The addition of antioxidants delays oxidation and material degradation during their processing and usage. Sustainable phenolic acids such as 4-hydroxybenzoic acid or 3,4-dihydroxybenzoic acid were s...

  • Article
  • Open Access
7 Citations
4,140 Views
18 Pages

Characterization of PPS Piston and Packing Ring Materials for High-Pressure Hydrogen Applications

  • Alexander Pöllinger,
  • Julia Maurer,
  • Thomas Koch,
  • Stefan Krenn,
  • Bernhard Plank,
  • Sabine Schwarz,
  • Michael Stöger-Pollach,
  • Eleni Siakkou,
  • Karolina Smrczkova and
  • Michael Schöbel

1 February 2024

The widespread adoption of renewable energy hinges on the efficient transportation of hydrogen. Reciprocating piston compressor technology in non-lubricated operation will play a key role, ensuring high flow rates and compression ratios. These system...

  • Article
  • Open Access
22 Citations
4,562 Views
15 Pages

Enhanced Biodegradation Rate of Poly(butylene adipate-co-terephthalate) Composites Using Reed Fiber

  • Jia Xu,
  • Kunpeng Feng,
  • Yuan Li,
  • Jixing Xie,
  • Yingsai Wang,
  • Zhiqiang Zhang and
  • Qing Hu

1 February 2024

To enhance the degradability of poly(butylene adipate-co-terephthalate) (PBAT), reed fiber (RF) was blended with PBAT to create composite materials. In this study, a fifteen day degradation experiment was conducted using four different enzyme solutio...

  • Review
  • Open Access
20 Citations
3,452 Views
15 Pages

Manipulating Microbial Cell Morphology for the Sustainable Production of Biopolymers

  • Vipin C. Kalia,
  • Sanjay K. S. Patel,
  • Kugalur K. Karthikeyan,
  • Marimuthu Jeya,
  • In-Won Kim and
  • Jung-Kul Lee

1 February 2024

The total rate of plastic production is anticipated to surpass 1.1 billion tons per year by 2050. Plastic waste is non-biodegradable and accumulates in natural ecosystems. In 2020, the total amount of plastic waste was estimated to be 367 million met...

  • Article
  • Open Access
22 Citations
5,096 Views
16 Pages

Innovative Electrospun Nanofiber Mats Based on Polylactic Acid Composited with Silver Nanoparticles for Medical Applications

  • Tongsai Jamnongkan,
  • Kawisara Sirichaicharoenkol,
  • Vanida Kongsomboon,
  • Janitsata Srinuan,
  • Natee Srisawat,
  • Autchara Pangon,
  • Rattanaphol Mongkholrattanasit,
  • Achiraya Tammasakchai and
  • Chih-Feng Huang

1 February 2024

Nanofibers are some of the most attractive materials that can modify functionalities for developing new kinds of specific applications and are mainly used as a biomedical material. Herein, we designed and prepared antibacterial nonwoven fiber mats of...

  • Article
  • Open Access
6 Citations
2,386 Views
21 Pages

Cr-Free Anticorrosive Primers for Marine Propeller Applications

  • Annie Wang,
  • Karnika De Silva,
  • Mark Jones and
  • Wei Gao

1 February 2024

Marine propellers work under severe service conditions, where they commonly suffer from mechanical, electrochemical, and biological corrosion damage. The major mechanical corrosion involves cavitation, erosion, and impingement corrosion. On the other...

  • Article
  • Open Access
9 Citations
2,652 Views
15 Pages

Effect of Irradiation Temperature and Atmosphere on Aging of Epoxy Resins for Superconducting Magnets

  • David Mate Parragh,
  • Christian Scheuerlein,
  • Noémie Martin,
  • Roland Piccin,
  • Federico Ravotti,
  • Giuseppe Pezzullo,
  • Torsten Koettig and
  • Dirk Lellinger

1 February 2024

The superconducting magnets of future particle accelerators will be exposed to high irradiation doses at cryogenic temperatures. To investigate the effect of irradiation temperature and atmosphere on the aging behavior, we have characterized the chan...

  • Review
  • Open Access
6 Citations
3,731 Views
19 Pages

1 February 2024

The development of catalysts has significantly advanced the progress of polyolefin materials. In particular, group 4 (Ti, Zr, Hf) non-metallocene catalysts ligated with [N,N] bidentate ligand(s) have garnered increasing attention in the field of olef...

  • Article
  • Open Access
12 Citations
3,478 Views
15 Pages

1 February 2024

Liposomes show promise for anti-cancer drug delivery and tumor-targeted therapy. However, complex tumor microenvironments and the performance limitations of traditional liposomes restrict clinical translation. Hyaluronic acid (HA)-modified nanoliposo...

  • Article
  • Open Access
7 Citations
2,106 Views
17 Pages

31 January 2024

Excessive settlement of the subgrade seriously reduces the service quality of slab tracks and threatens trains’ running safety. While the utilization of foamed polyurethane is recognized as an effective solution, previous research on its expans...

  • Article
  • Open Access
22 Citations
4,161 Views
30 Pages

An Insight into the Characteristics of 3D Printed Polymer Materials for Orthoses Applications: Experimental Study

  • Syed Hammad Mian,
  • Emad Abouel Nasr,
  • Khaja Moiduddin,
  • Mustafa Saleh and
  • Hisham Alkhalefah

31 January 2024

Knee orthoses assist patients with impaired gait through the amendment of knee abnormalities, restoration of mobility, alleviation of pain, shielding, and immobilization. The inevitable issues with laborious traditional plaster molding procedures for...

  • Article
  • Open Access
5 Citations
2,183 Views
14 Pages

31 January 2024

Chiral nematic materials have been attracting attention in fields of advanced functional applications due to their unique iridescent colors and tunable helical structure. A precisely decreased pitch is of importance for construction and applications...

  • Article
  • Open Access
2 Citations
2,590 Views
20 Pages

31 January 2024

Reducing the CO2 emissions of plastic parts is crucial in terms of sustainable product and process designs. Approaches include the use of recycled materials and reducing the energy demands of processes through more efficient technologies. In this con...

  • Article
  • Open Access
11 Citations
2,114 Views
18 Pages

31 January 2024

In order to study the modification mechanisms of a warm-mixing agent and high dosage on rubber-powder-modified asphalt, as well as the influence of salt freeze–thaw cycling on the mechanism of warm-mixed high-dosage-rubber-powder-modified aspha...

  • Article
  • Open Access
6 Citations
2,399 Views
16 Pages

31 January 2024

Cellulose derivatives have attracted attention as environmentally friendly materials that can exhibit a cholesteric liquid crystal (CLC) phase with visible light reflection. Previous reports have shown that the chemical structures and the degrees of...

  • Article
  • Open Access
6 Citations
4,587 Views
22 Pages

31 January 2024

The investigation of interconnection technologies is crucial for advancing semiconductor packaging technology. This study delved into the various methods of achieving electrical interconnections, focusing on the sintering process and composition of t...

  • Article
  • Open Access
6 Citations
2,342 Views
12 Pages

31 January 2024

The design of novel acceptor molecular structures based on classical building blocks is regarded as one of the efficient ways to explore the application of organic conjugated materials in conductivity and electronics. Here, a novel acceptor moiety, t...

  • Article
  • Open Access
8 Citations
2,090 Views
16 Pages

31 January 2024

Clean fracturing fluid has the characteristics of being environmentally friendly and causing little damage to reservoirs. Meanwhile, its backflow gel-breaking fluids (GBFs) can be reutilized as an oil displacement agent. This paper systematically eva...

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Polymers - ISSN 2073-4360