Sorption Recovery of Platinum Metals from Production Solutions of Sulfate-Chloride Leaching of Chromite Wastes
Abstract
:1. Introduction
2. Materials and Methods
3. Results and Discussion
4. Conclusions
Author Contributions
Funding
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Ionite | Type | Physical Structure | Functional Groups | SEC for Cl- mmol/g |
---|---|---|---|---|
AB-17-8 | strong base | G | QAB | 3.4 |
Purolite S 985 | weakly basic | MP | polyamines | 2.1 |
AH-31 | weakly basic | G | AA | 2.8 |
Ionite | Individual Sorption | Joint Sorption | ||||
---|---|---|---|---|---|---|
Quantitative Characteristics of Sorption | EC | D | R | EC | D | R |
platinum | ||||||
AH-31 | 0.010 | 213.16 | 81 | - | - | - |
AB-17-8 | 0.011 | 334.62 | 87 | 0.010 | 188.10 | 79 |
Purolite S 985 | 0.012 | 950.00 | 95 | 0.011 | 262.50 | 84 |
iridium | ||||||
AH-31 | 0.0078 | 78.21 | 61 | - | - | - |
AB-17-8 | 0.0086 | 101.52 | 67 | 0.007 | 57.14 | 54 |
Purolite S 985 | 0.0094 | 135.19 | 73 | 0.009 | 119.94 | 71 |
Ionite | Individual Sorption | Joint Sorption | ||||
---|---|---|---|---|---|---|
Thermodynamic Parameters of Sorption | K | R2 | ΔG, kJ/mol | K | R2 | ΔG, kJ/mol |
platinum | ||||||
AH-31 | 16.02 | 0.986 | −6.76 | - | - | - |
AB-17-8 | 20.4 | 0.9376 | −7.36 | 27.27 | 0.9934 | −8.05 |
Purolite S 985 | 153.84 | 0.9861 | −12.27 | 67.67 | 0.9788 | −10.27 |
iridium | ||||||
AH-31 | 47.95 | 0.9796 | −9.43 | - | - | - |
AB-17-8 | 53.66 | 0.9821 | −9.70 | 20.83 | 0.9979 | −7.40 |
Purolite S 985 | 66.90 | 0.9681 | −10.24 | 27.34 | 0.997 | −8.06 |
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Petrov, G.; Zotova, I.; Nikitina, T.; Fokina, S. Sorption Recovery of Platinum Metals from Production Solutions of Sulfate-Chloride Leaching of Chromite Wastes. Metals 2021, 11, 569. https://doi.org/10.3390/met11040569
Petrov G, Zotova I, Nikitina T, Fokina S. Sorption Recovery of Platinum Metals from Production Solutions of Sulfate-Chloride Leaching of Chromite Wastes. Metals. 2021; 11(4):569. https://doi.org/10.3390/met11040569
Chicago/Turabian StylePetrov, Georgiy, Irina Zotova, Tatiana Nikitina, and Svetlana Fokina. 2021. "Sorption Recovery of Platinum Metals from Production Solutions of Sulfate-Chloride Leaching of Chromite Wastes" Metals 11, no. 4: 569. https://doi.org/10.3390/met11040569