Preparation and Analysis of Complex Barrier Layer of Heterocyclic and Long-Chain Organosilane on Copper Alloy Surface
Abstract
:1. Introduction
2. Experimental Section
2.1. Materials and Reagents
2.2. Preparation of Complex Film on Copper Alloy Surface
2.3. Characterization
3. Results and Discussion
3.1. Electrodeposition of TES Monomer
3.2. FT-IR Spectra Analysis
3.3. Contact Angle
3.4. Surface Morphology
3.5. Cyclic Voltammetry Measurement for the Bare and Modified Copper Surface
3.6. Potentiodynamic Polarization
3.7. EIS
4. Conclusions
Acknowledgments
Author Contributions
Conflicts of Interest
References
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Sample | Anodic Peak I Potential (V) | Anodic Peak II Potential (V) | Oxidative Current Density (mA/cm2) | Area of CV Curves (10−4) |
---|---|---|---|---|
Blank | −0.39 | −0.18/−0.13 | 8.416 | 62.8 |
TES | −0.33 | −0.12 | 0.312 | 18.0 |
TES/OTES | −0.31 | −0.07 | 0.196 | 4.77 |
TES/HDTMS | −0.29 | −0.06 | 0.173 | 2.51 |
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Zhao, Q.; Tang, T.; Dang, P.; Zhang, Z.; Wang, F. Preparation and Analysis of Complex Barrier Layer of Heterocyclic and Long-Chain Organosilane on Copper Alloy Surface. Metals 2016, 6, 162. https://doi.org/10.3390/met6070162
Zhao Q, Tang T, Dang P, Zhang Z, Wang F. Preparation and Analysis of Complex Barrier Layer of Heterocyclic and Long-Chain Organosilane on Copper Alloy Surface. Metals. 2016; 6(7):162. https://doi.org/10.3390/met6070162
Chicago/Turabian StyleZhao, Qian, Tiantian Tang, Peilin Dang, Zhiyi Zhang, and Fang Wang. 2016. "Preparation and Analysis of Complex Barrier Layer of Heterocyclic and Long-Chain Organosilane on Copper Alloy Surface" Metals 6, no. 7: 162. https://doi.org/10.3390/met6070162