1. Introduction
A quartz tuning fork (QTF) is an acoustic resonator widely used as a clock oscillator due to its stability and precision [
1]. The ease of production and low cost of quartz crystal pushed the mass production of QTFs by using standard photolithography and chemical etching [
2] or, more recently, with optical techniques consisting of direct cutting of the quartz crystal using ultrashort laser pulses [
3]. This allowed the realization of different geometries and sizes, suitable for different applications [
4,
5,
6]. Indeed, custom QTFs are employed in quartz-enhanced photo-acoustic spectroscopy (QEPAS) as acousto-electric transducers to detect the photo-acoustic signal generated by the absorption of modulated light from a gas sample [
7]. The principle of detection in QEPAS is based on the piezoelectric properties of a quartz crystal: acoustic waves photo-generated between the prongs hit and create oscillations at one of the in-plane resonance frequencies of the QTF (in order to operate the laser source in wavelength modulation); the mechanical stress generates a strain field; electric charges appear on the surface to be collected by electrodes and converted into a voltage or a current QEPAS signal [
8]. Its signal-to-noise ratio (SNR) is proportional to the squared root of the quality factor (
Q-factor) of the QTF resonance, defined as the ratio of the total input energy and the dissipated energy during one cycle. Furthermore, high
Q-factors imply low dissipation losses and narrow bandwidths (typically, a few Hz). These dissipation phenomena occurring while prongs are vibrating can be ascribed to: (i) air and acoustic damping, caused by interaction with surrounding air [
9,
10]; (ii) support losses due to the prong–support interaction [
11]; and (iii) thermoelastic damping, caused by stress field spatial inhomogeneity leading to temperature fluctuations [
12]. The main loss mechanisms depend upon the prong size and the resonance mode of the QTF. Another parameter affecting the QEPAS signal is the radiation-to-sound conversion efficiency of the gas, namely, the efficiency of the gas to convert the modulated absorbed light into sound, which is mainly determined by the non-radiative relaxation dynamics of the excited molecules [
13]. Lowering the modulation frequency, i.e., the QTF resonance frequency, is essential when dealing with slow relaxing molecules (with relaxation times of few microseconds) to allow a complete release of the absorbed energy during each oscillation period. Thus, QTFs with resonance frequencies lower than ~20 kHz and a quality factor as high as possible are an interesting choice for QEPAS detection. To follow these guidelines, a new geometry with T-shaped QTF prongs was introduced in [
14]. Compared with a rectangular shape, T-shaped prongs allow a lower resonance frequency without affecting the
Q-factor, as well as an increased stress field generated on the prong surface while the QTF is vibrating. The QTF is usually coupled with a pair of resonator tubes, allowing an enhancement of the QEPAS SNR [
15,
16]. The acoustic system composed of a QTF and a pair of resonator tubes is usually referred to as a spectrophone. In a spectrophone, an additional dissipation phenomenon can become limiting due to the interaction between the prong surface and the tubes’ transversal section squeezing damping. The influences of air pressure in the resonance properties of classic shape QTFs have been reported in the literature through analytical models, and a good agreement with experiments has been demonstrated [
17,
18,
19]. In [
14], a new geometry of QTF was introduced that may not be modelled in a similar manner.
This work aims to analyze the influence of air pressure on the resonance properties both of a bare T-shaped QTF, and of the same QTF when acoustically coupled with two resonator tubes. A theoretical model was developed to predict the influence of air pressure both on the frequency and quality factor of the fundamental resonance mode of the QTF. The model was validated with experimental results. Furthermore, the QTF was assembled in a spectrophone with two resonator tubes. The influence of resonator tubes on the spectrophone resonance properties was investigated and compared with those of the bare QTF. The same analysis was performed on the QTF tubes at two different distances.
4. Results
As an example, resonance curves (black datapoints) for the bare T-QTF at two representative pressures, 10 Torr and 760 Torr, are shown in
Figure 4a,b. The QTF signal is normalized and plotted as function of
.
Taking into account the results obtained in
Section 2.2, Equation (9) is used as fitting function in the form of:
where
B = 1/
Q2 and
x = 1 −
f2/
f02.
The
f0 value corresponding to the peak is needed for the fitting procedure. Since its value is not modified by the stray capacitance thanks to the virtual ground imposed by the transimpedance amplifier, as is observed in
Figure 2a,
f0 firstly can be determined by imposing a Lorentzian fit. Then, Equation (10) can be used for a second iteration fit to estimate the
Q-factor. The best fit by using Equation (10), for the highest (760 Torr) and lowest (10 Torr) pressures at which the bare QTF was investigated, is also shown in
Figure 4a,b as solid red lines. From the preliminary Lorentzian fitting procedures, resonance frequencies
f0 are extracted and plotted as a function of the air pressure in
Figure 5 (datapoints) for the three configurations.
As expected from Equation (4),
f0 decreases linearly as pressure increases. The intercept values of linear fits, i.e., the resonance frequencies in vacuum, are different for three configurations. At first glance, this seems not to be in agreement with Equation (4). It is worth noticing that the Euler–Bernoulli equation with viscous drag force term in Equation (3) is valid only when the gas is supposed to be in the viscous regime. Lowering the pressure, the gas can enter the molecular region, where damping mechanisms are caused by independent collisions of non-interacting molecules with the vibrating QTF prong. As a result, at pressures <10 Torr, the additive mass cannot be supposed proportional to the air density and a deviation from the linearity can also be supposed for the QTF resonance frequency. With respect to the bare QTF, the coupling with a pair of resonator tubes causes a shift of spectrophone resonance frequency. Moreover, the frequency shift increases with the pressure, although it is almost constant at pressures lower than 200 Torr. This can be explained by considering that the tubes and the QTF interact with each other through the medium in SSH at higher pressures. Thus, at low pressure, the QTF–tubes coupling is reduced and the QTF can be considered almost isolated from the tubes. For any pressure values, the frequency shift is larger when
d = 100 µm with respect to
d = 200 µm. This can be explained observing that the QTF–tube distance also affects the resonator’s acoustic interaction, thus leading to a greater frequency shift for a shorter QTF–tube distance. From the linear fits, the intercept value represents the fundamental vibrational mode
f’0 in vacuum whereas the slope is related to the additive mass, as described in Equation (4). Indeed, as discussed in the previous section, the additive mass per unit of length
u =
u0·P is proportional to the gas pressure, where
u0 =
kM/
RΘ with
k in m
2 units.
u0 represents the additive mass per unit of length and pressure, and can be retrieved from the slope
m of the linear fit as
m =
u0·f0/(2
ρA) where
ρ = 2650 kg/m
3 and the prong section
A =
T2·w. The results are listed in
Table 2.
The bare T-QTF shows a slightly higher value of u0 with respect to the one obtained when it is coupled with tubes. This could be related to the fact that the presence of the tubes reduces the number of molecules surrounding the QTF which results in a decreasing of the inertia to the prong oscillation. The additional inertia of the vibrating prong due to the effect of the surrounding medium was modelled as an additive mass. Indeed, with respect to the bare QTF, the reductions in the additive mass results were 8% and 16% for QTF–tube distance d = 100 μm and d = 200 μm, respectively.
The quality factor values are extracted by fitting the resonance curves with Equation (10). The
Q-factor values (datapoints) are plotted as a function of the air pressure in
Figure 6, for the three investigated configurations.
The trends show a strong dependence on air pressure, especially at pressures lower than 20 Torr, suggesting that the dominant loss mechanism is air damping. Moreover, working at pressures lower than 100 Torr, the
Q-factor dramatically increases as pressure decreases, meaning that air pressure requires a higher efficient stabilization with respect to operating at pressures close to the atmospheric one. Negligible differences are observed when the QTF–tube distance is reduced from 200 µm to 100 µm: if the tube–QTF distance is reduced from 200 µm to 100 µm, the spectrophone
Q-factor is almost not affected. This “relaxes” the assembling procedure of the spectrophone, avoiding the requirement of a superfine placement of tubes. This can be explained by noting that the prong spacing (800 μm) is comparable with the tube ID (see
Table 1); thus, the effective interacting surface can be neglected. Indeed, while prongs are vibrating, they could lose energy via interaction with the tube walls (squeeze damping). If this additional loss mechanism is present, it should be influenced by: (i) the tube–QTF distance: the lower the distance, the higher the contribution; (ii) the air pressure: the higher the pressure, the higher the squeeze damping. Thus, in
Figure 6, a squeeze damping effect should result in a deviation at higher pressures of red circles (spectrophone with
d = 100 µm) towards lower values, with respect to blue triangles (spectrophone with
d = 200 µm). Conversely, red circles and blue triangles should overlap at lower pressures. Instead, both datasets are quite overlapped in the whole of the investigated pressure range, demonstrating that squeeze damping is negligible. In the whole pressure range, the coupling with tubes leads to a reduction in the spectrophone
Q-factor with respect to the bare QTF. This reduction increases as pressure increases and is almost zero at pressures lower than 100 Torr. This behavior can be explained by considering that the effect of the acoustic coupling of the high
Q-factor QTF with the low
Q-factor tubes, which leads to a QTF loss of energy, is reduced at low pressures, because of the reduced number of surrounding molecules. Indeed, at 10 Torr, the
Q-factor of the spectrophone (45,454) is comparable with the one measured for the bare QTF (45,221). As a result, the surrounding air strongly affects the acoustic coupling of both resonators, namely, the tube and the QTF. It is worth noticing that datapoints in
Figure 6 close to atmospheric pressure deviate from fitting with Equation (12). This is expected because Hosaka’s model in Equation (5) was rewritten with the assumption that air density is proportional to pressure. This is valid only if the ideal gas law is assumed. Approaching atmospheric pressure, the ideal gas law is no longer valid, requiring a replacement with the van der Waals equation (real gas law).
As the dissipation mechanisms described in
Section 2.1 are independent of each other, the overall quality factor can be written as:
where 1/
Q0 = 1/
QTED + 1
/Qsup. Using Equation (5) for
Qair,
Q(
P) can be rewritten as:
where:
With this formulation, parameter
C takes into account all the pressure-independent loss mechanisms. Equation (12) was used to fit the experimental data and the results are shown as solid lines in
Figure 6. The obtained fit curves were used to evaluate the difference Δ
Q between the
Q-factors of the bare QTF and the spectrophone with
d = 200 μm, as a function of the air pressure. The result is shown in
Figure 7.
Starting from low pressures, ΔQ quickly increases until it reaches a maximum at around 200 Torr. At p > 200 Torr, we can assume that the influence of air on the interaction between tubes and QTF is saturated, leading to an almost flat trend with a slight decrease towards the atmospheric pressure. A reduction of 24% in the Q-factor of the spectrophone with respect to the bare QTF is observed at atmospheric pressure.
5. Conclusions
In this work, we studied the resonance properties of a T-shaped QTF and how they are affected by acoustic coupling with a pair of resonator tubes in a spectrophone. This study was performed by analyzing the pressure-dependence of the resonance frequency and the
Q-factor, both for the bare QTF and the spectrophone. A theoretical model was proposed and validated by experimental results. The analysis showed that dependence of the resonance properties on air pressure is well described by the proposed model in the approximation of ideal gas law. This study allowed the authors to experimentally verify how, when the QTF is vibrating in air, the effect of the surrounding medium (modelled as an additive mass for the QTF itself) affects resonance frequency, whereas energy dissipation in air reduces
Q-factor. Moreover, additive mass is a difficult parameter to be modeled for simple geometries. This work allowed the authors to evaluate it experimentally. A reduction in the additive mass was observed for a spectrophone, when compared to the bare QTF. This means that tubes cause a shielding effect between QTF and air, leading to a reduction in the air effect on vibrating prongs. Comparing bare QTF results with those obtained with a spectrophone, it was observed that at low pressures, the quality factor of a spectrophone weakly deviates from that of the bare QTF (see
Figure 6). At higher pressures, the acoustic coupling is stronger, leading to an increase in resonance frequency and a decrease in quality factor. No squeeze damping was observed when the resonator tubes were placed at a distance greater than 100 μm from the QTF.
The theoretical model developed in this work can be useful for QEPAS sensing to predict working pressure, which is usually determined experimentally and can vary from gas to gas. Indeed, the QEPAS signal strongly depends on gas pressure because both the spectrophone
Q-factor and the radiation-to-sound conversion efficiency (involving the acoustic wave generation within the gas) depends on gas pressure [
6]. Although the dependence of the radiation-to-sound conversion efficiency on gas pressure has been well modelled [
6], a theoretical description predicting the
Q-factor behavior as a function of the pressure studied in this work is the fundamental step to converge for a combined theoretical model aimed at predicting the best operating pressure for QEPAS, avoiding a time-consuming experimental investigation.
Moreover, a bare QTF has recently been used as a photodetector in tunable diode laser spectroscopy (TDLAS) setup [
25], showing that the photo-induced electrical signal scales linearly with the QTF accumulation time, which is proportional to its quality factor. Thus, the
Q-factor vs. pressure trend is the necessary step to predict the enhancement factor of the photo-induced signal as a function of pressure.