Efficient Inorganic/Organic Acid Leaching for the Remediation of Protogenetic Lead-Contaminated Soil

In this study, inorganic acid and organic acid were used to leach and remediate superheavy, lead-contaminated protogenetic soil with a lead pollution level of 8043 mg∙kg⁻¹. Among the compounds studied, HCl and citric acid (CA) presented the best effects, respectively. Under the optimal experimental conditions, the remediation efficiency of 0.05 mol∙L⁻¹ CA reached 53.6%, while that of 0.2 mol∙L⁻¹ HCl was 70.3%. According to the lead morphology analysis, CA and HCl have certain removal ability to different fractions of lead. Among them, the removal rates of acid-soluble lead in soil by HCl and CA are 93% and 83%, and the soil mobility factor (M_F) value decreased from 34.4% to 7.74 % and 12.3%, respectively, indicating that the harm of lead in soil was greatly reduced. Meanwhile, the leaching mechanisms of CA and HCl were studied. The pH values of the soil after leaching with HCl and CA were 3.88 and 6.97, respectively, showing that HCl leaching has caused serious acidification of the soil, while the process of CA leaching is more mild. CA has a relatively high remediation efficiency at such a low concentration, especially for the highly active acid-soluble fraction lead when maintaining the neutrality of the leached soil. Hence, CA is more suitable for the remediation of lead-contaminated soil.